| MSDS | : | CARBON DIOXIDE, REFRIGERATED LIQUID | | CAS | : | 124-38-9 | | NAME | : | carbon dioxide
supdat:of the dermal surface or deep tissue freezing.
other prec:not attempt to repair, adjust/in any other way modify
ing 3:malfunction/other type of operations problem w/vessel, cont closest
ing 4:this prod is also delivered to users in transportable cryogenic
ing 5:be used in well vent areas & i/a/w mfr's & your supplier's
ing 6:upright position. specialized hand trucks are needed for their
ing 7:sys should be used w/these cyl. protect cyl against physical dmg.
ing 8:area away from sources of heat/direct sunlight. do not allow areas
ing 9:use check valve/trap in cyl discharge line to pvnt haz backflow.
ing 10:secured to pvnt falling/being knocked over. use only dot/asme
ing 11:when connecting cyl to lower press piping/sys. close valve after
ing 12:refilled except by/with consent of liq carbonic. for more info
ing 13:p-1, sb-2, g-6, g-6.1, and g-6.3. all are assoc w/hndlg gases,
eye prot:full length faceshield (fp n).
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LIQUID CARBONIC INDUSTRIES -- CARBON DIOXIDE, REFRIGERATED LIQUID
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Material Safety Data Sheet
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NIIN: 01-326-8978
MSDS Num: CBQXF
MSDS NAME: CARBON DIOXIDE, REFRIGERATED LIQUID
Responsible Party
Name: LIQUID CARBONIC INDUSTRIES
Address: 810 JORIE BLVD
City: OAKBROOK IL 60521-2216
Info Phone: 708-572-7500
Emergency Phone Number: 504-673-8831;800-424-9300(CHEMTREC)
Published: Y
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Contractor Summary
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Name: LIQUID CARBONIC INDUSTRIES CORP
Address: 810 JORIE BLVD
City: HINSDALE IL 60521-2216
Phone: 708-572-7000
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Item Description Information
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Item Manager: N35
Item Name: EXTINGUISHER,FIRE
Unit of Issue: EA
UI Container Qty: 1
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Ingredients
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Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE
% Wt: >99.5
OSHA PEL: 5000 PPM
ACGIH TLV: 5000 PPM/30000 STEL
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Name: SUPDAT:OF THE DERMAL SURFACE OR DEEP TISSUE FREEZING.
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Name: OTHER PREC:NOT ATTEMPT TO REPAIR, ADJUST/IN ANY OTHER WAY MODIFY
OPERATION OF THESE VESSELS. IF THERE IS
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Name: ING 3:MALFUNCTION/OTHER TYPE OF OPERATIONS PROBLEM W/VESSEL, CONT CLOSEST
SUPPLIER LOCATION IMMED. CYLINDERS:
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Name: ING 4:THIS PROD IS ALSO DELIVERED TO USERS IN TRANSPORTABLE CRYOGENIC
CNTNRS (LIQ CYL). THESE CYLS SHOULD ALWAYS
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Name: ING 5:BE USED IN WELL VENT AREAS & I/A/W MFR'S & YOUR SUPPLIER'S
INSTRUCTIONS. THEY MUST ALWAYS BE KEPT IN
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Name: ING 6:UPRIGHT POSITION. SPECIALIZED HAND TRUCKS ARE NEEDED FOR THEIR
MOVEMENT. A "FIRST IN-FIRST OUT" INVENTORY
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Name: ING 7:SYS SHOULD BE USED W/THESE CYL. PROTECT CYL AGAINST PHYSICAL DMG.
STORE IN COOL, DRY, WELL-VENTILATED
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Name: ING 8:AREA AWAY FROM SOURCES OF HEAT/DIRECT SUNLIGHT. DO NOT ALLOW AREAS
WHERE CYLS ARE STORED TO EXCEED 125F.
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Name: ING 9:USE CHECK VALVE/TRAP IN CYL DISCHARGE LINE TO PVNT HAZ BACKFLOW.
CYL SHOULD BE STORED UPRIGHT & FIRMLY
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Name: ING 10:SECURED TO PVNT FALLING/BEING KNOCKED OVER. USE ONLY DOT/ASME
CODED CNTNRS. USE PRESS REDUCING REGULATOR
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Name: ING 11:WHEN CONNECTING CYL TO LOWER PRESS PIPING/SYS. CLOSE VALVE AFTER
EACH USE & WHEN EMPTY. CYL MAY NOT BE
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Name: ING 12:REFILLED EXCEPT BY/WITH CONSENT OF LIQ CARBONIC. FOR MORE INFO
REFER TO CGA PAMPHLETS & SFTY BULLETINS
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Name: ING 13:P-1, SB-2, G-6, G-6.1, AND G-6.3. ALL ARE ASSOC W/HNDLG GASES,
HNDLG CARBON DIOXIDE/OXYG DEFICIENT ATMOSPHERES.
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Name: EYE PROT:FULL LENGTH FACESHIELD (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHALATION:AT 2-3% CONCENTRATION SYMPTOMS OF SIMPLE
ASPHYXIA OCCUR; 3-5% CAUSES INCREASED RESPIRATION & HEADACHE; UP TO 15 %
CAUSES HEADACHE, NAUSEA, VOMITING & UNCONSCIOUSNESS. HIGHER CONCENTRA
TIONS CAUSE RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA & DEATH. CO*2
IS MOST IMPORTANT CEREBRAL (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:VASODILATOR KNOWN. SKIN:PROLONGED
CONTACT W/CARBON DIOXIDE "SNOW" (SOLID) COULD RSLT IN CRYOGENIC
"BURN"/FROSTBITE. PERSONS IN ILL HEALTH WHERE SUCH ILLNESS WOULD BE
AGGRAVATED BY EXPOSURE TO LIQUID CARBON DIOXIDE SHOULD NOT BE ALLOWED TO
WORK WITH OR HANDLE THIS PRODUCT.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). EYES:IMMEDIATELY FLUSH W/POTABLE
WATER FOR MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD (FP N).
INHAL:CONSCIOUS PERSONS SHOULD BE ASSISTED TO UNCONTAMD AREA & INHA LE
FRESH AIR. IF UNCONSCIOUS, PROVIDE ASSISTED RESPIRATION & SUPPLEMENTAL
OXYG. FURTHER TREATMENT SHOULD BE AVAIL FOR RESCUE PERS. SKIN:(FROSTBITE)
FLUSH AFFECTED AREAS W/LUKEWARM WATER. DO (SUPDAT)
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Handling and Disposal
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Spill Release Procedures: LIQUID CARBON DIOXIDE WILL NOT SPILL, BUT FORMS SOLID
"SNOW" AT PRESSURES BELOW 67 PSIG. LEAKS SHOULD BE VENTED TO THE ATMOSPHERE
"OUTSIDE" IN A SAFE AREA.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: BULK SYS:CARBON DIOXIDE, REFRIGERATED LIQ IS
DELIVERED TO CUSTOMER INTO STATIONARY, INSULATED VESSELS @ CUSTOMER'S
LOCATION.
Other Precautions: THESE STATIONARY VESSELS MAY HAVE MECH REFRIGERATION COILS
W/IN VAP SPACE IN ORDER TO MAINTAIN PRESS IN VESSEL/TEMP OF LIQ IN VESSEL.
STATIONARY CUSTOMER SITE VESSELS SHOULD BE OPERATED I/A/W MFR'S & YOUR
SUPPLIER'S INSTRUCTIONS. DO
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Fire and Explosion Hazard Information
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Extinguishing Media: NONFLAMMABLE GAS. CARBON DIOXIDE IS USED AS AN
EXTINGUISHING MEDIA.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP N).
IF CYL ARE INVOLVED IN FIRE, SAFELY RELOCATE/KEEP COOL W/WATER SPRAY. DO NOT
SPRAY WATER DIRECTLY ON (SUPDAT)
Unusual Fire/Explosion Hazard: NONE.
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Control Measures
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Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: LOCAL EXHAUST:TO PVNT ACCUMULATION ABOVE TWA. MECHANICAL
(GENERAL):STEL/PEL.
Protective Gloves: LOOSE FITTING, INSULATED.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGG &
Other Protective Equipment: SAFETY SHOES; PORTABLE CO*2 ANALYZER. ANSI APPRVD
EMERGENCY EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: SUBLIMATION PT:-109F,-78C. SPEC GRAV:1.014 @ 2F
(H*2O=1). APPEAR/ODOR:PARTICLES (SNOW) WHEN DISCHARGED FROM CYL/VESSEL. FIRE
FIGHT PROC:SFTY RELIEF DEVISES. MATLS TO AVOID:MAGNESIUM) & THEIR
HYDRIDES. FIRST AID PROC:NOT USE HOT WATER. A PHYS SHOULD SEE PATIENT
PROMPTLY IF CRYOGENIC "BURN" HAS RSLTD IN BLISTERING
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Physical/Chemical Properties
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HCC: G3
B.P. Text: SUPDAT
Vapor Pres: 856 PSIA
Vapor Density: 1.65 @ 70F
Spec Gravity: SUPDAT
Solubility in Water: SOLUBLE.
Appearance and Odor: COLORLES GAS W/SLIGHT PUNGENT ODOR. LIQ CONVERTS TO WHITE
CRYSTALLINE (SUPDAT)
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: REACTS W/ALKALINE MATLS TO FORM CARBONATES & BICARBONATES.
CAN BE EXPLO W/REACTIVE METALS (SODIUM, POTASSIUM, (SUPDAT)
Hazardous Decomposition Products: CARBON MONOXIDE AT HIGH TEMPERATURES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: CARBON DIOXIDE, REFRIGERATED LIQUID
Company: LIQUID CARBONIC INDUSTRIES CORP
Street: 810 JORIE BLVD
City: HINSDALE IL
Zipcode: 60521-2216
Health Emergency Phone: 504-673-8831;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 11/29/1995
Status Code: C
Label Date: 11/29/1995
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHALATION:AT 2-3% CONCENTRATION SYMPTOMS OF
SIMPLE ASPHYXIA OCCUR; 3-5% CAUSES INCREASED RESPIRATION & HEADACHE; UP
TO 15 % CAUSES HEADACHE, NAUSEA, VOMITING & UNCONSCIOUSNESS. HIGHER
CONCENTRA TIONS CAUSE RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA &
DEATH. CO*2 IS MOST IMPORTANT CEREBRAL VASODILATOR KNOWN. SKIN:PROLONGED
CONTACT WITH CARBON DIOXIDE "SNOW" (SOLID) COULD RESULT IN CRYOGE NIC "BURN"
OR FROSTBITE. PERSONS IN ILL HEALTH WHERE SUCH ILLNESS WOULD BE AGGRAVATED BY
EXPOSURE TO LIQUID CARBON DIOXIDE SHOULD NOT BE ALLOWED TO WORK WITH OR
HANDLE THIS PRODUCT. CHRONIC:NONE LISTE D BY MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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