LCI (LUCIER CHEMICAL INDUSTRIE -- SODIUM FLUORIDE
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Material Safety Data Sheet
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NIIN: 00-059-9069
MSDS Num: CDFYY
MSDS NAME: SODIUM FLUORIDE
Responsible Party
Name: LCI (LUCIER CHEMICAL INDUSTRIES) LTD
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Info Phone: 904-241-1200
Emergency Phone Number: 904-241-1200
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Item Description Information
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Item Manager: S9G
Item Name: SODIUM FLUORIDE,TECHNICAL
Specification Number: 06768-AWWA B-701
Type/Grade/Class: NONE
Unit of Issue: BG
Quantitative Expression: 00000000100LB
UI Container Qty: 0
Type of Container: UN 5M2 BAG
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Ingredients
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Cas: 7681-49-4
RTECS #: WB0350000
Name: SODIUM FLUORIDE (CERCLA)
Percent by Wt: 97.7
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 2.5 PPM (F)
ACGIH TLV: 2.5 MG (F/)M3; 9596
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL, RAT) 180 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHALATION OFDUSTORMIST MAY CAUSE
SEVEREMUCOUSMEMBRANEIRRITATION & BURNS. EFFECTS MAY BOT BE IMMEDIATELY
APPARENT, ESPECIALLY WITH DILUTE SOLUTION. FIRST AID PROCEDURES SHOULD BE
FOLLOWED EVEN IN CASES OF SUSPECTED CONTACT. CHRONIC:CAUSES SEVERE SKIN
IRRITATION. INGESTION OR INHALATION MAY BE HARMFUL & POSSIBLY
FATALDEPENDING ON SEVERITY & LENGTH OF OVEREXPOSURE.MAY CAUSE FLUOROSIS.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: PRODUCT MAY BE ABSORBED THROUGH THE SKIN
AND PRODUCE SIGNS OF FLUOROSIS, SUCH AS WEIGHT LOSS, BRITTLENESS OF BONES,
ANEMIA,WEAKNESSANDSTIFFNESS OFJOINTS.INTERNAL BLEEDING MAY DEVELOP.
Medical Cond Aggravated By Exposure: ANY SKIN, RESPIRATORY ORMUCOUS MEMBRANE
CONDITIONS.
First Aid: INHALATION-REMOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE. IF
BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION.KEEP PERSON WARM &
AT REST. GET MEDICAL AID AS SOON AS POSSIBLE. EYE-IMMEDIATELY FLU SH EYES
WITH LARGE AMOUNTS OF WATER. GETMEDICAL AID AS SOON AS POSSIBLE (EYE
SPECIALIST). SKIN-PROMPTLY WASH SKIN USING SOAP & MILD DETERGENT &
WATER. IF SOAKS THROUGH CLOTHING, REMOVE PROMPTLY & WASH SKIN USING SOAP
OR MILD DETERGENT & WATER. GIVE MEDICALAIDAS SOON AS POSSIBLE FOR ALL
BURNS. INGESTION-HAVE THE PERSON DRINK AS MUCH WATER AS POSSIBLE. DO NOT
INDUCE VOMITING. GIVE SEVERAL GLASSES OF MILK. CONTACT PHYSICIAN
IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: EMPLOYEES SHOULD BE TRAINED IN SAFETY PROCEDURES FOR
HANDLING THIS PRODUCT. WEAR NIOSH APPROVED PROTECTIVE CLOTHING &
BREATHING APPARATUS. ISOLATE PRODUCT SPILL AREA. CAREFULLY SHOVEL MATERIAL
& PLACE IN CLEAN DRY CONTAINER & COVER. REMOVECONTAINER FROM SPILL
SITE & DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE & LOCAL
REGULATIONS. CHEMTREC CAN BE CONTACTED FOR 24-HOUR EMERGENCY ASSISTANCE.
Waste Disposal Methods: USED OR UNUSED PRODUCT SHOULDBE TESTED TO DETERMINE
HAZARD STATUS AND COMPLY WITH FEDERAL, STATE AND LOCAL DISPOSAL OR DISCHARGE
LAWS. REPORTABLE QUANTITY (RQ): 1000 POUNDS.
Handling And Storage Precautions: STORE IN A COOL, DRY, PLACE AWAY FROM ACIDS.
USE ONLY WITH ADEQUATE VENTILATION, DUST MASK OR SELF-CONTAINED BREATHING
APPARATUS. PROTECTIVE CLOTHING SHOULD ALWAYS BE WORN. AVOID CONTACT WITH
EYES, SK IN & CLOTHING. KEEPING BAG OR CONTAINERCLOSED WHEN NOT IN USE.
AVOID BREATHING DUST OR MIST.
Other Precautions: IF CHEMICAL SHOULD BECOME HEATED, AS IN A FIRE, IT WILL
DECOMPOSES, RELEASING HIGHLY TOXIC HYDROGEN FLUORIDE GAS.
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Fire and Explosion Hazard Information
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Extinguishing Media: THIS CHEMICAL IS NOT FLAMMABLE, BUT FOR FIRES IN AREA
WHERE THIS CHEMICAL IS STORED, FOAM, DRY CHEMICALS OR CO2 MAY BE USED.
Fire Fighting Procedures: ALTHOUGH THIS CHEMICAL IS NOT FLAMMABLE, WHEN
FLAMMABLE, WHEN HEATED TO EXTREME TEMPERATURES SUCH AS FIRE, IT WILL RELEASE
HYDROGEN FLOURIDE GAS.
Unusual Fire/Explosion Hazard: FIREFIGHTERS SHOULD AVOID ALL BODILY CONTACT,
WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS.
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Control Measures
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Respiratory Protection: USE NIOSH APPROVED SINGLE USE DUST RESPIRATOR. SELF
CONTAINED BREATHING APPARATUS MAY BE REQUIRED WHEN DEALING WITH SPILLS OR
WHEN HEATED TO DECOMPOSITION.
Ventilation: ADEQUATE VENTILATION TO MAINTAIN FLUORIDE CONCENTRATIONS BELOW
APPLICABLE STANDARDS.
Protective Gloves: IMPERVIOUS GLOVES SHOULD BE WORN.
Eye Protection: SPLASH- PROOF GOGGLES SHOULD BE WORN
Other Protective Equipment: IMPERVIOUS CLOTHING SHOULD BE WORN TO PREVENT
REPEATED OR PROLONGED SKIN CONTACT (OVERALLS, BOOTS, ETC). PROTECT OPEN
WOUNDS. HEATING TO DECOMPOSITION REQUIRES FULL BODY PROTECTIVE CLOTHING.
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Physical/Chemical Properties
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HCC: T4
NRC/State LIC No: NOT RELEVANT
Boiling Point: =1704.C, 3099.2F
M.P/F.P Text: 980-1040C
Decomp Text: UNKNOWN
Spec Gravity: 2.726 18C
Viscosity: NOT RELEVANT
Solubility in Water: 4G/100G H20 0C
Appearance and Odor: WHITE CRYSTALLINE POWDER - ODORLESS
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT
Materials To Avoid: CONTACT WITH STRONG ACIDS; WILL PRODUCE HYDROGEN FLOURIDE.
AVOID EXTREME TEMPERATURES, SUCH AS FIRES. THEY WILL CAUSE DECOMPOSITION AND
FORMULATION OF NITROGEN OXIDES, HYDROFLUORIC ACID AND FLUORINE.
Hazardous Decomposition Products: EXTREME TEMPERATURES, SUCH AS FIRES, WILL
CAUSE DECOMPOSITION AND FORMULATION OF NITROGEN OXIDES AND FLUORINE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: OSHA PERMISSIBLE EXPOSURE LIMIT(PEL): TWA 2.5 MG/M3
(AS F).
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Ecological Information
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MSDS Transport Information
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Transport Information: HAZARD CLASS: 6.1. PLACARDING REQUIREMENTS: KEEP
AWAYFROM FOOD. EPA HAZARDOUS SUBSTANCE: YES. REPORTABLE QUANTITY: 1000LBS.
DOT PROPER SHIPPING NAME: SODIUM FLUORIDE,SOLID. UN/NA IDENTIFICATION: UN
1690. STANDARD TRANSPORTATION COMMODITYCODE: 49441 50.
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Regulatory Information
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Sara Title III Information: NO
Federal Regulatory Information: CERCLA: YES. TSCA: YES.
State Regulatory Information: NEW JERSEY "RIGHT TO KNOW" LAWS: YES.
MASSACHUSETTES " RIGHT TO KNOW" LAWS: YES.
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Other Information
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Transportation Information
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Trans ID NO: 45219
MSDS NAME: SODIUM FLUORIDE
MSDS Prepared Date: 02/01/1993
Review Date: 03/19/1999
Radioactivity: NOT RELEVANT
Net Unit Weight: 100 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: BG
Container QTY: 0
Type Of Container: UN 5M2 BAG
Additional Data: DOT PROPER SHIPPING NAME, UN ID NUMBER, HAZARD CLASS PER MSDS.
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Detail DOT Information
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DOT PSN Code: NFI
DOT Proper Shipping Name: SODIUM FLUORIDE
Hazard Class: 6.1
UN ID Num: UN1690
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Special Provision: T8
Packaging Exception: 153
Non Bulk Pack: 213
Bulk Pack: 240
Max Qty Pass: 100 KG
Max Qty Cargo: 200 KG
Vessel Stow Req: A
Water/Ship/Other Req: 26
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Detail IMO Information
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IMO PSN Code: NRR
IMO Proper Shipping Name: SODIUM FLUORIDE, SOLID
IMDG Page Number: 6258
UN Number: 1690
UN Hazard Class: 6.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 6.1-04
MED First Aid Guide NUM: 750
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Detail IATA Information
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IATA PSN Code: WQB
IATA UN ID Num: 1690
IATA Proper Shipping Name: SODIUM FLUORIDE
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 619
Max Quant Pass: 100KG
Max Quant Cargo: 200KG
Packaging Note Cargo: 619
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Detail AFI Information
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AFI PSN Code: WQB
AFI Proper Shipping Name: SODIUM FLUORIDE
AFI Hazard Class: 6.1
AFI UN ID NUM: UN1690
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A10.6
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HAZCOM Label
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MSDS NAME: SODIUM FLUORIDE
Company: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Street: 415 PABLO AVE N
PO Box: 49000
City: JACKSONVILLE BEACH FL
Zipcode: 32240-9000
Health Emergency Phone: 904-241-1200
Label Required IND: Y
Date Of Label Review: 09/28/1999
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 02/24/1997
Year Procured: 1997
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- TOXIC. MAY CAUSE EYE BURNS. MAY BE ABOSRBED THROUGH SKIN. INGESTION
MAY BE FATAL. INHALATION MAY CAUSE SEVERE IRRITATION OF MUCOUS MEMBRANES
& BURNS. CHRONIC- CAUSES FLUOROSIS, INTERNAL BLEEDING, ANEMIA. STORE
AWAY FROM ACIDS. SWEEP UP SPILL & PLACE IN A SUITABLE CONTAINER FOR
DISPOSAL. FIRST AID- GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALE D:REMOVE TO
FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:IF
CONSCIOUS, DRINK MILK (CALCIUM) OR LARGE AMOUNT OF WA TER. GET MEDICAL
ATTENTION IMMEDIATELY.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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