LOS ANGELES CHEMICAL CO -- CALCIUM HYPOCHLORITE GRANULAR,97 D 5207
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Material Safety Data Sheet
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NIIN: 00-255-0471
MSDS Num: CFYDB
MSDS NAME: CALCIUM HYPOCHLORITE GRANULAR,97 D 5207
Responsible Party
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE STREET
Box: 1987
City: SOUTH GATE CA 90280-2534
Info Phone: 213-583-4761 / FAX 213-773-0909
Emergency Phone Number: 213-583-4761/562-9500
Preparer's Name: UNKNOWN
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280
Phone: 213-562-9500
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Item Description Information
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Item Manager: S9G
Item Name: CALCIUM HYPOCHLORITE,TECHNICAL
Specification Number: OC114
Type/Grade/Class: NONE
Unit of Issue: BT
Quantitative Expression: 00000000006OZ
UI Container Qty: 0
Type of Container: IP.1 OR IP.2
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Ingredients
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Cas: 7778-54-3
RTECS #: NH3485000
Name: CALCIUM HYPOCHLORITE (CERCLA)
% Wt: 65 - 75
Other REC Limits: 3 MG/M3 (CEILING)MFR
OSHA PEL: 0.5 PPM (CL)
ACGIH TLV: 0.5PPM/1STEL(CL)9596
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 7647-14-5
RTECS #: VZ4725000
Name: SODIUM CHLORIDE
% Wt: 10 - 20
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Cas: 10137-74-3
RTECS #: FN9800000
Name: CALCIUM CHLORATE
% Wt: 0 - 5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Cas: 10043-52-4
RTECS #: EV9800000
Name: CALCIUM CHLORIDE
% Wt: 0 - 5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Cas: 1305-62-0
RTECS #: EW2800000
Name: CALCIUM HYDROXIDE
% Wt: 0 - 4
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 5 MG/M3; 9596
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Cas: 471-34-1
RTECS #: FF9335000
Name: CALCIUM CARBONATE
% Wt: 0 - 4
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: 0 - 5.5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT RELEVANT
ACGIH TLV: NOT RELEVANT
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL, RAT) IS 850 MG/KG (RTECS).
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- DUST IRRITATES RESPIRATORY TRACT & MAY CAUSE BURNS. CORROSIVE TO
EYES/SKIN. MAY CAUSE SEVERE IRRITATION AND/OR BURNS. IF SWALLOWED, CAUSES
IRRI TATION AND/OR BURNS OF ENTIRE GASTROINTESTINAL TRACT. CHRONIC- LUNG
DAMAGE, TISSUE DESTRUCTION, CORNEAL DAMAGE.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: SEVERE IRRITATION, PAIN, ULCERATION,
TEARING, BLINDNESS, SHORTNESS OF BREATH, COUGH, SORE THROAT, NASAL CONGESTION
Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING SKIN DISORDERS
OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THE SUBSTANCE.
First Aid: GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH AIR.
PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. CALL PHYSICIAN. SKIN:FLUSH WITH PLEN TY OF WATER.
ORAL:IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER. DO NOT INDUCE VOMITING. GET
MEDICAL ATTENTION OR TAKE VICTIM TO AN HOSPITAL EMERGENCY IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: WEAR RESPIRATOR APPROVED FOR DUST/CHLORINE. VENTILATE
AREA. SWEEP UP AND MINIMIZE CONTAMINATION WITH ORGANIC MATERIALS. PLACE IN AN
APPROPRIATE CONTAINER FOR DISPOSAL. WASH AREA WITH WATER. DO NOT FLU SH TO
SEWER. COMPLY WITH HAZWOPER (29 CFR 1910.120
Neutralizing Agent: WEAK OR DILUTE ACID AND REDUCING AGENTS
Waste Disposal Methods: DISPOSAL OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS. REPORTABLE QUANTITY: 10 LBS.
Handling And Storage Precautions: STORE IN COOL, DRY, VENTILATED AREA AWAY FROM
INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. KEEP OUT OF REACH OF
CHILDREN.
Other Precautions: DO NOT TAKE INTERNALLY. AVOID CONTACT WITH EYES,
SKIN/CLOTHING. AVOID BREATHING DUST. CAUSES SEVERE IRRITATION AND BURNS. WASH
THOROUGHLY AFTER HANDLING. DO NOT STORE ABOVE 52C/125F.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Lower Limits: NOT RELEVANT
Upper Limits: NOT RELEVANT
Extinguishing Media: WATER SPRAY ONLY. NOT COMBUSTIBLE, BUT MAY IGNITE
COMBUSTIBLES. USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures: WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. DO NOT USE DRY EXTINGUISHER CONTAINING
AMMONIUM COMPOUNDS.
Unusual Fire/Explosion Hazard: WILL EVOLVE CHLORINE GAS AT ELEVATED
TEMPERATURES.
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Control Measures
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Respiratory Protection: NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS
EXIST. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A NIOSH-APPROVED DUST AND
CHLORINE RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS.
Ventilation: USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST AND CHLORINE
LEVELS.
Protective Gloves: NEOPRENE, PVC, RUBBER
Eye Protection: DUST-RESISTANT SAFETY GOGGLES
Other Protective Equipment: PROTECTIVE CLOTHING, EYE-WASH FACILITIES, SAFETY
SHOWER.
Work Hygienic Practices: OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING.
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Physical/Chemical Properties
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HCC: D1
NRC/State LIC No: NOT RELEVANT
M.P/F.P Text: UNKNOWN
Decomp Text: >351F,>177C
Spec Gravity: UNKNOWN
PH: 11.5
Viscosity: NOT RELEVANT
Evaporation Rate & Reference: NOT RELEVANT
Solubility in Water: 18% @ 25C/77F
Appearance and Odor: WHITE, FREE FLOWING GRANULES OR TABLETS FORM WITH
CHLORINE-LIKE ODOR
Corrosion Rate: UNKNOWN
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: TEMPERATURES ABOVE 125F/52C, HIGH HUMIDITY
Materials To Avoid: ACIDS, COMBUSTIBLES, ORGANICS, NITROGEN CONTAINING
COMPOUNDS, FLAMMABLE MATERIALS, DRY FIRE EXTINGUISHER (AMMONIUM CMPD)
Hazardous Decomposition Products: CHLORINE GAS
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 61678
MSDS NAME: CALCIUM HYPOCHLORITE GRANULAR,97 D 5207
MSDS Prepared Date: 02/09/1996
Review Date: 07/13/1998
Radioactivity: NOT RELEVANT
Net Unit Weight: 6 OZ
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: BT
Container QTY: 0
Type Of Container: IP.1 OR IP.2
Additional Data: HAZARD LABEL: OXIDIZER PER MSDS. REPORTABLE QUANTITY: 10 LBS,
PER MSDS. LTD QTY. EXEMPT FROM LABELLI NG AND PLACARDING UNLESS SHIPPED BY
AIR (49 CFR 173.152).
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Detail DOT Information
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DOT PSN Code: CQT
DOT Proper Shipping Name: CALCIUM HYPOCHLORITE, HYDRATED OR CALCIUM
HYPOCHLORITE, HYDRATED MIXTURES,
DOT PSN Modifier: WITH NOT LESS THAN 5.5 PER CENT BUT NOT MORE THAN 10 PER CENT
WATER.
Hazard Class: 5.1
UN ID Num: UN2880
DOT Packaging Group: II
Label: OXIDIZER
Packaging Exception: 152
Non Bulk Pack: 212
Bulk Pack: 240
Max Qty Pass: 5 KG
Max Qty Cargo: 25 KG
Vessel Stow Req: A
Water/Ship/Other Req: 50,56,58,69,106
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Detail IMO Information
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IMO PSN Code: DKN
IMO Proper Shipping Name: CALCIUM HYPOCHLORITE, HYDRATED MIXTURE
IMO PSN Modifier: ,WITH NOT LESS THAN 5.5% BUT NOT MORE THAN 10% WATER
IMDG Page Number: 5138
UN Number: 2880
UN Hazard Class: 5.1
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 5.1-06
MED First Aid Guide NUM: 741
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Detail IATA Information
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IATA PSN Code: EZD
IATA UN ID Num: 2880
IATA Proper Shipping Name: CALCIUM HYPOCHLORITE, HYDRATED MIXTURE
IATA PSN Modifier: WITH NOT LESS THAN 5.5% BUT NOT MORE THAN 10% WATER
IATA UN Class: 5.1
IATA Label: OXIDIZER
UN Packing Group: II
Packing Note Passenger: 508
Max Quant Pass: 5KG
Max Quant Cargo: 25KG
Packaging Note Cargo: 511
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Detail AFI Information
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AFI PSN Code: EZD
AFI Proper Shipping Name: CALCIUM HYPOCHLORITE HYDRATED, OR CALCIUM
HYPOCHLORITE, HYDRATED MIXTURES
AFI PSN Modifier: ,WITH NOT LESS THAN 5.5 BUT NOT MORE THAN 10% WATER
AFI Hazard Class: 5.1
AFI UN ID NUM: UN2880
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A9.8
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HAZCOM Label
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MSDS NAME: CALCIUM HYPOCHLORITE GRANULAR,97 D 5207
Company: LOS ANGELES CHEMICAL CO
Street: 4545 ARDINE ST
PO Box: 1987
City: SOUTH GATE CA
Zipcode: 90280
Health Emergency Phone: 213-583-4761/562-9500
Label Required IND: Y
Date Of Label Review: 02/09/1998
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 02/09/1998
Year Procured: 1997
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- DUST IRRITATES & MAY CAUSE BURNS. CORROSIVE TO EYES/SKIN. MAY
CAUSE SEVERE IRRITATION & BURNS. IF SWALLOWED, CAUSES IRRITATION &
BURNS OF GI TR ACT. CHRONIC- LUNG DAMAGE, TISSUE DESTRUCTION. STORE AWAY FROM
INCOMPATIBLES. SWEEP UP SPILL. PLACE IN AN APPROPRIATE CONTAINER FOR
DISPOSAL. FIRST AID- GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:M OVE TO
FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH WATER
FOR 15 MINUTES. HOLD EYELIDS OPEN. CALL PHYSICIAN. SKIN:FLUSH WITH PLENTY OF
WATER. ORAL:IF CONSCIOUS, DRINK LARGE AMO UNT OF WATER. DO NOT INDUCE
VOMITING. CALL DOCTOR.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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