CARBOLINE CO -- THINNER #33
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Material Safety Data Sheet
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NIIN: 00-998-2834
MSDS Num: CGDTD
MSDS NAME: THINNER #33
Responsible Party
Name: CARBOLINE CO
Address: 350 HANLEY IND CT
City: ST LOUIS MO 63144
Info Phone: 314-644-1000
Emergency Phone Number: 412-681-6669;800-424-9300(CHEMTREC)
Proprietary Ind: Y
Published: Y
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Contractor Summary
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Name: CARBOLINE CO
Address: 350 S HANLEY INDUSTRIAL CT
City: ST. LOUIS MO 63144-1599
Phone: 314-644-1000
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Item Description Information
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENT 1
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: INHAL: HARMFUL IF INHALED; MAY AFFECT BRAIN OR NERVOUS
SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE NOSE & THROAT
IRRITATION. EYE CONTACT: MAY CAUSE IRRITATION. SKIN CONTACT: MAY CAUSE IRRI
TATION. CHRONIC: ANIMAL STUDIES HAVE CLEARLY SHOWN DOSE-RELATED ADVERSE
EFFECTS ON THE CNS, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS, VOL 65, PG 149,
1996:GROUP 2B.
Signs And Symptions Of Overexposure: HLTH HAZ: HEMATOPOIETIC TISSUES, BLOOD,
KIDNEYS & LIVER ASSOCIATED W/THE ADMINISTRATION OF 2-BUTOXYETHANOL
(EXTRACTED FROM DHHS (NIOSH) PUB NO 90-118) (FP N). NOTICE: REPORTS HAVE
ASSOCIATED REPEATED & PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS
W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Medical Cond Aggravated By Exposure: IF YOU HAVE A CONDITION THAT COULD BE
AGGRAVATED BY EXPOSURE TO DUST OR ORGANIC VAPORS SEE MD PRIOR TO USE.
First Aid: WHEN EXPOSED ALWAYS GET MEDICAL ATTENTION. EYES: FLUSH WITH WATER
FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED
CLOTHING AND CLEAN BEFORE REUSE. INHALATION: REMOVE TO FR ESH AIR. PROVIDE
OXYGEN IF BREATHING ISDIFFICULT. USE ARTIFICIAL RESPIRATION IF NOT BREATHING.
GET MEDICAL ATTENTION. INGEST: DO NOT INDUCE VOMITING!! ALWAYS GET MEDICAL
ATTENTION.
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Handling and Disposal
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Spill Release Procedures: ELIMINATE ALL IGNIT SOURCES. HANDLING EQUIP MUST BE
GROUNDED TO PVNT SPARKING. EVACUATE AREA OF UNPROTECTED PERS. WEAR APPROP
PERSONAL PROTECTION CLTHG & EQUIP. FOLLOW SAFE HANDLING & USE
GUIDELINES. CONTAIN & SOAK UP RESIDUAL W/ABSORB (CLAY (SUPDAT)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME &
STRONG OXIDIZING AGENTS. KEEP CONTAINERS CLOSED. STORE IN COOL, DRY PLACE
W/ADEQUATE VENTILATION.
Other Precautions: IF POURING OR TRANSFERRING MATERIALS, GROUND ALL COUNTAINERS
& TOOLS. DO NOT WELD, HEAT, CUT OR DRILL ON FULL OR EMPTY CONTAINERS. FOR
INDUSTRIAL USE ONLY.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: 89.0F,31.7C
Lower Limits: 0.9%
Upper Limits: 13.8%
Extinguishing Media: DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROTECTIVE EQUIP (FP
N). EVACUATE HAZARD AREA OF UNPROTECTED PERSONNEL. COOL SURROUNDING CNTNRS
W/WATER IN CASE OF FIRE EXPOSURE.
Unusual Fire/Explosion Hazard: VAPS ARE HVR/AIR & WILL ACCUM. VAPS WILL
FORM EXPLOS CONCS W/AIR. VAPS TRAVEL LONG DISTS & WILL FLASHBACK. USE
MECH VENT WHEN NEC TO KEEP PERCENT VAP (SUPDAT)
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Control Measures
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Respiratory Protection: USE ONLY W/VENTILATION TO KEEP LEVELS BELOW EXPOSURE
GUIDELINES. USER SHOULD TEST & MONITOR EXPOSURE LEVELS TO INSURE ALL
PERSONNEL ARE BELOW GUIDELINES. IF NOT SURE OR IF NOT ABLE TO MONITOR USE
NIOS H APPROVED AIR-PURIFYING RESPIRATOR.
Ventilation: USE EXPLOSION-PROOF VENTILATION WHEN REQUIRED TO KEEP BELOW HEALTH
EXPOSURE GUIDELINES & LOWER EXPLOSION LIMIT.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING. IF MATL PENETRATES SKIN, CHANGE GLOVES & CLOTHING.
Work Hygienic Practices: WASH W/SOAP & WATER BEFORE EATING, DRINKING, APPLYING
COSMETICS. LAUNDER CONTAMD CLTHG BEFORE REUSE. LEATHER (SUPDAT)
Supplemental Safety and Health: EXPLO HAZ: BELOW THE LEL. HAZ DECOMP PRODS:
VERY HAZ. WELDING, CUTTING OR ABRASIVE GRINDING CAN CREATE SMOKE & FUMES.
DO NOT BREATHE. SPILL PROC: OR SAND). TAKE UP ABSORB MATL & SEAL TIGHTLY
FOR PROPE R DISPOSAL. HYGIENE PRACT: SHOES CAN ABSORB & PASS THRU HAZ
MATLS. CHECK SHOES CAREFULLY AFTER SOAKING BEFORE REUSE.
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Physical/Chemical Properties
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B.P. Text: >248F,>120C
Vapor Density: HVR/AIR
Spec Gravity: 0.89
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEAT, SPARKS AND OPEN FLAMES.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON MONOXIDE, NITROGEN OXIDES &
UNIDENTIFIED ORGANIC CMPDS. CONSIDER ALL SMOKE & FUMES FROM BURNING MATL AS
(SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 97380
MSDS NAME: THINNER #33
MSDS Prepared Date: 11/04/1996
Review Date: 03/19/1998
Multiple KIT Number: 0
Review IND: Y
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Detail DOT Information
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DOT PSN Code: LFK
DOT Proper Shipping Name: PAINT RELATED MATERIAL
DOT PSN Modifier: INCLUDING PAINT THINNING, DRYING, REMOVING, OR REDUCING
COMPOUND
Hazard Class: 3
UN ID Num: UN1263
DOT Packaging Group: III
Label: FLAMMABLE LIQUID
Special Provision: B1,B52,T7,T30
Packaging Exception: 150
Non Bulk Pack: 173
Bulk Pack: 242
Max Qty Pass: 60 L
Max Qty Cargo: 220 L
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: LCT
IMO Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL
IMO PSN Modifier: (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING PAINT
THINNING OR REDUCING COMPOUND) o
IMDG Page Number: 3372
UN Number: 1263
UN Hazard Class: 3.3
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 3-05
MED First Aid Guide NUM: 310
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Detail IATA Information
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IATA PSN Code: SXM
IATA UN ID Num: 1263
IATA Proper Shipping Name: PAINT RELATED MATERIAL
IATA PSN Modifier: (INCLUDING PAINT THINNING OR REDUCING COMPOUNDS)
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: III
Packing Note Passenger: 309
Max Quant Pass: 60L
Max Quant Cargo: 220L
Packaging Note Cargo: 310
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Detail AFI Information
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AFI PSN Code: SXH
AFI Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL
AFI PSN Modifier: (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDIN PAINT
THINNING OR REDUCING COMPOUNDS)
AFI Hazard Class: 3
AFI UN ID NUM: UN1263
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A7.3
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HAZCOM Label
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MSDS NAME: THINNER #33
Company: CARBOLINE CO
Street: 350 S HANLEY INDUSTRIAL CT
City: ST. LOUIS MO
Zipcode: 63144-1599
Health Emergency Phone: 412-681-6669;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 02/05/1998
Status Code: C
Label Date: 02/05/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE LIQUID. ACUTE: INHALATION: HARMFUL IF
INHALED; MAY AFFECT BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR
NAUSEA. MAY CAUSE NOSE & THROAT IRRITATION. EYE CONTACT: IRRITATION. SKIN
CON TACT: IRRITATION. CHRONIC: CANCER HAZARD. CONTAINS CARBON BLACK WHICH IS
LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). ANIMAL STUDIES HAVE CLEARLY SHOWN
DOSE-RELATED ADVERSE EFFECTS ON THE CNS, BLOOD FO RMING TISSUES, BLOOD,
KIDNEYS AND LIVER ASSOCIATED WITH THE ADMINISTRATION OF 2-BUTOXYETHANOL (FP
N). REPORTS HAVE ASSOCIATED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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