3M GENERAL OFFICES -- MARINE ADHESIVE/SEALANT 4200, 06560
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGRHF
MSDS NAME: MARINE ADHESIVE/SEALANT 4200, 06560
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
=======================================================
Ingredients
=======================================================
Cas: 57596-50-6
Name: POLYURETHANE PREPOLYMER
% Wt: 30-40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 9002-86-2
RTECS #: KV0350000
Name: ETHYLENE, CHLORO-, POLYMER; (POLYVINYL CHLORIDE)
% Wt: 20-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 91082-17-6
Name: PLASTICIZERS
% Wt: 20-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA). VP: 3.66
% Wt: 5-10
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 64742-47-8
RTECS #: OA5504000
Name: KEROSENE (PETROLEUM), HYDROTREATED; (PETROLEUM HYDROCARBON)
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 1-5
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 101-68-8
RTECS #: NQ9350000
Name: ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (METHYLENE BISPHENYL
ISOCYANATE) (MDI) (SARA 313)
% Wt: <0.6
OSHA PEL: C 0.02 PPM
ACGIH TLV: 0.005 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: 0.73 LB/GAL CALCULATED PER SCAQMD RULE 443.1
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: 88 GMS/LITER CALCULATED PER SCAQMD RULE 443.1
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND LESS H*2O & EXEMPT SOLVENTS: 88 GMS/LITER
CALCULATED PER SCAQMD RULE 443.1
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS, AND BLOOD IN
FECES.
-----------------------------
Name: SPILL PROC: UNPROTECTED PERS FROM HAZARD AREA. COLLECT USING NON-SPARKING
TOOLS. CLEAN UP RESIDUE W/APPROPRIATE
-----------------------------
Name: ING 12: ORGANIC SOLVENT. READ & FOLLOW SAFETY PRECAUTIONS ON SOLVENT
LABEL & MSDS. PLACE IN APPRVD METAL CNTNR.
-----------------------------
Name: ING 13: SEAL THE CONTAINER.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYE: MILD IRRIT: SIGNS/SYMPS CAN INCL REDNESS,
SWELL, PAIN, & TEARING. SKIN: MILD IRRIT (AFTER PRLNGD/RPTD CONT):
SIGNS/SYMPS CAN INCL REDNESS, SWELL, & ITCHING. PERSONS PREVIOUSLY
SENSITIZED T O ISOCYANATES MAY EXPERIENCE AN ALLERGIC SKIN RXN: SIGNS/SYMPS
CAN INCL REDNESS, SWELL, BLISTERING, & (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: ITCHING. INHAL: CNS DEPRESS:
SIGNS/SYMPS CAN INCL HDCH, DIZZ, DROW, INCOORDINATION, SLOWED RXN TIME,
SLURRED SPEECH, GIDD & UNCON. IRRIT (UPPER RESP): SIGNS/SYMPS CAN INCL
SORENESS OF NOSE & THROAT, COUGH & SNEEZING. PERSONS PREVIOUSLY
SENSITIZED TO ISOCYANATES MAY EXPERIENCE ALLERGIC RESP REACTION: (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE CONT: IMMED FLUSH W/LARGE AMTS OF WATER. GET IMMED MEDICAL ATTN.
SKIN CONT: WASH AFFECTED AREA WITH SOAP & WATER. INHAL: IF SIGNS/SYMPS
OCCUR, REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPS CONTINUE, CALL PHYS.
INGEST: DO NOT INDUCE VOMIT.DRINK 2 GLASSES OF WATER. CALL PHYSICIAN.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING
PHYSICAL & HLTH HAZS, RESP PROT, VENT, & PERSONAL PROT EQUIP. IN
U.S.A., CALL (612) 733-1110/(612) 733-6100 FOR 24-HR SPILL ASSISTANCE.
VENTILATE ARE A. EXTING ALL IGNIT SOURCES. EVACUATE
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCIN IN PERMITTED HAZ WASTE INCINERATOR. SINCE REGS
VARY, CONSULT APPLIC FED, STATE & LOC REGS/AUTH BEFORE DISP. IN EVENT OF
UNCONTROLLED RELS OF MATL, USER SHOULD DETERM IF RELS QUALIFIES AS REPORTA
BLE QTY. U.S. EPA HAZ WASTE NO: D001(IGNITABLE).
Handling And Storage Precautions: KEEP CNTNR CLSD WHEN NOT IN USE. KEEP OUT OF
REACH OF CHILDREN. KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME, & OTHER SOURCES
OF IGNITION. AVOID EYE CONT. AVOID SKIN CONT. AVOID BRTHG OF VAPORS. DO NOT
INGEST.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point Text: 110F,43C
Lower Limits: 1%
Upper Limits: 8%
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE KNOWN.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF
CONCERN (FP N).
Ventilation: USE IN A WELL-VENTILATED AREA.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: % VOLAT: 7.5% BY WT. EFTS OF OVEREXP:
SIGNS/SYMPS CAN INCL DFCLTY BRTHG, WHEEZING, TIGHTNESS OF CHEST, & RESP
FAILURE. INGEST: ASPIR PNEUM: SIGNS/SYMPS CAN INCL COUGH, DFCLTY BRTHG,
WHEEZING, COUGH UP BLOOD & PNEUM, WHICH CAN BE FATAL. INGEST MAY CAUSE:
IRRIT OF GI TISS: SIGNS/SYMPS CAN INCL PAIN, VOMIT,
=======================================================
Physical/Chemical Properties
=======================================================
Vapor Density: SEE ING 4
Spec Gravity: 1.17
Solubility in Water: NIL
Appearance and Odor: WHITE PASTE WITH SOLVENT ODOR.
Percent Volatiles by Volume: SUPDAT
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AMINES, ALCOHOLS, WATER. RXN W/WATER, ALCOHOLS &
AMINES IS NOT HAZ IF CNTNR CAN VENT TO ATM TO PVNT PRESS BUILDUP.
Materials To Avoid: AMINES, ALCOHOLS, WATER. RXN W/WATER, ALCOHOLS & AMINES IS
NOT HAZ IF CNTNR CAN VENT TO ATM TO PVNT PRESS BUILDUP.
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE, OXIDES OF
NITROGEN, ISOCYANATES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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=======================================================
HAZCOM Label
=======================================================
MSDS NAME: MARINE ADHESIVE/SEALANT 4200, 06560
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 03/05/1998
Status Code: C
Label Date: 03/05/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: COMBUSTIBLE. AVOID WATER. ACUTE: EYE: MILD IRRITATION.
SKIN: MILD IRRITATION. INHALATION: CENTRAL NERVOUS SYSTEM DEPRESSION:
SIGNS/SYMPTOMS CAN INCLUDE HEADCHE, DIZZINESS, DROWSINESS, INCOORDINATION,
SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS AND UNCONSCIOUSNESS.
IRRITATION (UPPER RESPIRATORY): SIGNS/SYMPTOMS CAN INCLUDE SORENESS OF NOSE
& THROAT, COUGHING AND SNEEZING. INGESTION: IRRITATION, ASPIRATION
PNEUMONITIS. CHRONIC: SKIN OR INHALATION: SENSITIZATION.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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