| MSDS | : | ABC 30 BLACK ABLATIVE ANTIFOULING PAINT, 283S9822 | | CAS | : | 1317-39-1
1317-61-9
71-36-3
8050-09-7
1330-20-7
1314-13-2 | | NAME | : | copper (i) oxide
iron oxide
butyl alcohol; (n-butyl alcohol) (sara 313) (cercla). vp: 4.2. ld50:
plasticizers. vp: <1. ld50: (oral, rat) 2250 mg/kg.
resin. ld50: (oral, rat) >23.1 g/kg.
rosin acid; (rosin)
xylene (sara 313) (cercla). vp: 6. ld50: (oral, rat) >5 g/kg.
zinc oxide (sara 313) (cercla). ld50: >24 g/kg.
volatile organic compound: 335.90 g/l
supdat: may ignite. during emer cndtns overexp to decomp prods may cause
ing 10: apparent. obtain med attn. zinc oxide fume may result from
efts of overexp: concentrating & inhaling contents may be harmful or
first aid: ingest: consult md immed. do not induce vomit. aspir of
spill proc: & non-sparking tools. store in closed container until
hndlg/stor precs: non-explo-proof elec equip, during use & until all
ing 15: may spread long dists & beyond closed doors. pvnt build-up of
ing 16: fresh air. do not store above 120f or near fire/open flame. store
ing 17: w/osha 1910.106. keep container closed when not in use.
resp prot: dust. when used in restricted vent areas, wear niosh apprvd
ing 19: combination of particulates & vap. when used in confined
ing 20: hoods. use niosh apprvd resp when flame cutting, welding, brazing
vent: safety & health stds in mixing, application & curing areas
ing 22: decomp prods during welding & flame cutting on surfs coated
ing 23: prevent build-up by removing heavy solv vaps from lower levels of
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DEVOE COATINGS CO -- ABC 30 BLACK ABLATIVE ANTIFOULING PAINT, 283S
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGTJH
MSDS NAME: ABC 30 BLACK ABLATIVE ANTIFOULING PAINT, 283S9822
Responsible Party
Name: DEVOE COATINGS CO
Address: 4000 DUPONT CIRCLE
City: LOUISVILLE KY 40207
Info Phone: 502-897-9861
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DEVOE COATINGS CO
Address: 4000 DUPONT CIRCLE
Box: 7600
City: LOUISVILLE KY 40207-4802
Phone: 502-897-9861
=======================================================
Ingredients
=======================================================
Cas: 1317-39-1
RTECS #: GL8050000
Name: COPPER (I) OXIDE
% Wt: 50
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1317-61-9
Name: IRON OXIDE
% Wt: <5
OSHA PEL: 10 MG/M3
ACGIH TLV: 5 MG/M3
------------------------------
Cas: 71-36-3
RTECS #: EO1400000
Name: BUTYL ALCOHOL; (N-BUTYL ALCOHOL) (SARA 313) (CERCLA). VP: 4.2. LD50:
(ORAL, RAT) 2.5 G/KG.
% Wt: 10
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM, S, C
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Name: PLASTICIZERS. VP: <1. LD50: (ORAL, RAT) 2250 MG/KG.
% Wt: <5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: RESIN. LD50: (ORAL, RAT) >23.1 G/KG.
% Wt: <5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 8050-09-7
Name: ROSIN ACID; (ROSIN)
% Wt: 10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA). VP: 6. LD50: (ORAL, RAT) >5 G/KG.
% Wt: 5
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM; 150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1314-13-2
RTECS #: ZH4810000
Name: ZINC OXIDE (SARA 313) (CERCLA). LD50: >24 G/KG.
% Wt: 15
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: 335.90 G/L
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: MAY IGNITE. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE
HEALTH HAZ. SYMPS MAY NOT BE IMMED
-----------------------------
Name: ING 10: APPARENT. OBTAIN MED ATTN. ZINC OXIDE FUME MAY RESULT FROM
COMBUSTION. TLV & PEL FOR ZNO FUME IS 5 MG/M3.
-----------------------------
Name: EFTS OF OVEREXP: CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL OR
FATAL.
-----------------------------
Name: FIRST AID: INGEST: CONSULT MD IMMED. DO NOT INDUCE VOMIT. ASPIR OF
VOMITUS CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL.
-----------------------------
Name: SPILL PROC: & NON-SPARKING TOOLS. STORE IN CLOSED CONTAINER UNTIL
PROPERLY DISPOSED OF.
-----------------------------
Name: HNDLG/STOR PRECS: NON-EXPLO-PROOF ELEC EQUIP, DURING USE & UNTIL ALL
VAPS ARE ONE. VAPS MAY IGNITE EXPLO. VAPS
-----------------------------
Name: ING 15: MAY SPREAD LONG DISTS & BEYOND CLOSED DOORS. PVNT BUILD-UP OF
VAPS BY MAINTAINING CONTINUOUS FLOW OF
-----------------------------
Name: ING 16: FRESH AIR. DO NOT STORE ABOVE 120F OR NEAR FIRE/OPEN FLAME. STORE
LG QTYS IN BLDGS DESIGNED TO COMPLY
-----------------------------
Name: ING 17: W/OSHA 1910.106. KEEP CONTAINER CLOSED WHEN NOT IN USE.
-----------------------------
Name: RESP PROT: DUST. WHEN USED IN RESTRICTED VENT AREAS, WEAR NIOSH APPRVD
CHEM/MECH FILTER DESIGNED TO REMOVE A
-----------------------------
Name: ING 19: COMBINATION OF PARTICULATES & VAP. WHEN USED IN CONFINED
AREAS, WEAR NIOSH APPRVD AIR SUPPLY RESPS/USE
-----------------------------
Name: ING 20: HOODS. USE NIOSH APPRVD RESP WHEN FLAME CUTTING, WELDING, BRAZING
& SANDING MATL COATED W/THIS PROD.
-----------------------------
Name: VENT: SAFETY & HEALTH STDS IN MIXING, APPLICATION & CURING AREAS
& TO REMOVE SANDING DUSTS OF DRIED COATINGS &
-----------------------------
Name: ING 22: DECOMP PRODS DURING WELDING & FLAME CUTTING ON SURFS COATED
W/THIS PROD. VAPS MAY SPREAD LONG DISTS.
-----------------------------
Name: ING 23: PREVENT BUILD-UP BY REMOVING HEAVY SOLV VAPS FROM LOWER LEVELS OF
WORK AREA. ELIMINATE ALL IGNIT SOURCES.
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL: IRRIT OF RESP TRACT; HDCH, NAUS, DIZZ, WEAK
& FATG. EXTREME EXPOS CAN RSLT IN UNCON & EVEN RESP ARREST. SKIN/EYE
CNTCT: CAUSES EYE & SKIN IRRIT. MAY BE HARMFUL IF ABSORBED THRU SKIN. ING
EST: CAN CAUSE STOM &/OR INTESTINAL IRRIT, NAUS, VOMIT & DIARR.
CHRONIC: RPTS HAVE ASSOC RPTD & PRLNGD (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: OCCUP OVEREXP TO SOLVS W/PERM
BRAIN & NERVOUS SYS DMG. PRLNGD/RPTD BRTHG OF SPRAY MIST &/OR SANDING
DUST OVER PERIOD OF YRS MAY CAUSE DUST DISEASE OF LUNGS. WARNING: THIS PROD
MAY CNTN CHEM KNOWN TO STATE OF CA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER
REPRO HARM. NOTICE: INTENTIONAL MISUSE BY DELIB
Medical Cond Aggravated By Exposure: NONE, WHEN USED IN ACCORDANCE WITH SAFE
HANDLING AND USE INFORMATION.
First Aid: INHAL: IF YOU EXPERIENCE DFCLTY BRTHG, LEAVE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DFCLTY IS EXPERIENCED, SUMMON MED ASSISTANCE IMMED. IF
BRTHG CEASES, RESTORE USING APPRVD CPR TECHNIQUES & SUMMON ME D HELP
IMMED. EYES: FLUSH IMMED W/LG AMTS OF WATER FOR AT LEAST 15 MIN. GET MED
ASSISTANCE. SKIN: WASH AFFECTED AREAS W/SOAP & WATER. REMOVE SOILED
CLTHG. GET MED ASSISTANCE IF IRRIT PERSISTS.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE ALL SOURCES OF IGNIT (FLAMES, HOT SURFS &
ELEC, STATIC OR FRICTIONAL SPKS). PREVENT BRTHG OF VAPS. VENT AREA. BEFORE
ATTEMPTING CLEAN-UP, REFER TO HAZ CAUTION INFO IN OTHER SECTIONS OF MSDS. CO
NTAIN SPILLED MATL & REMOVE W/INERT ABSORB
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED
CONTAINERS.
Handling And Storage Precautions: KEEP AWAY FROM HEAT, SPKS & FLAMES. DO
NOT SMOKE. EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT
INCLUDING HEATERS, FANS & OTHER
Other Precautions: DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELLED
CNTNRS. DO NOT REUSE EMPTY CNTNRS. IF THIS MATL IS PART OF TWO COMPONET PROD,
THEN MIXTURE OF BASE & CONVERTER PORTIONS WILL HAVE HAZS OF BOTH C
OMPONENTS. OBSERVE ALL APPLIC PRECS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point Text: 80.0F,26.7C
Lower Limits: 1%
Extinguishing Media: IN CASE OF FIRE USE CARBON DIOXIDE, DRY CHEMICAL, FOAM OR
OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
SUMMON PROFESSIONAL FIREFIGHTERS. WATER SPRAY MAY BE INEFTIVE. IF WATER IS
USED, FOG NOZZS PREF. IF (SUPDAT)
Unusual Fire/Explosion Hazard: KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT,
ELEC EQUIP, SPKS & FLAME. VAPS MAY CAUSE FLASH FIRE. VAPS MAY IGNITE
EXPLO. VAPS MAY SPREAD LONG DISTS & (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: DO NOT BREATHE VAPS, SPRAY MIST OR SANDING DUST. WHEN
SPRAY APPLIED IN OUTDOOR OR OPEN AREAS & DURING SANDING OR GRINDING
OPERATIONS, USE NIOSH APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE
PARTICL ES OF OVERSPRAY & SANDING
Ventilation: PROVIDE GEN DILUTION OR LOC EXHST VENT IN VOL & PATTERN TO
KEEP AIR CONTAMINANT CONC BELOW CURRENT APPLIC
Protective Gloves: SOLVENT IMPERMEABLE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). DO NOT
GET ON SKIN. SOLV IMPERMEABLE CLTHG & BOOTS TO PVNT SKIN CNTCT REC.
Work Hygienic Practices: REMOVE AND WASH SOILED CLOTHING BEFORE REUSE. WASH
HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health: FIRE FIGHT PROC: EXPOSED TO FIRE/EXTREME HEAT,
WATER SHOULD BE USED TO COOL CLSD CNTNRS & PVNT PRESS BUILDUP OR POSS
AUTOIGNIT. EXPLO HAZ: BEYOND CLSD DOORS. DUE TO PRESS BUILDUP, CLSD CNTNRS
EXPOSED TO EXTREME HEAT MAY EXPLODE. NEVER USE WELDING/CUTTING TORCH ON/NEAR
CNTNR (EVEN EMPTY) AS PROD/ITS RESIDUE
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >244F,>118C
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Spec Gravity: 2.23 (FP N)
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 40.3
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY CAUSE TOX FUMES WHEN HEATED TO DECOMP.
FUMES MAY CNTN CO, CO*2, ZINC & COPPER CMPDS & OXIDES OF NITROGEN & SULFUR.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: ABC 30 BLACK ABLATIVE ANTIFOULING PAINT, 283S9822
Company: DEVOE COATINGS CO
Street: 4000 DUPONT CIRCLE
PO Box: 7600
City: LOUISVILLE KY
Zipcode: 40207-4802
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 04/01/1998
Status Code: C
Label Date: 04/01/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE LIQUID - CLASS IC. ACUTE: INHALATION:
RESPIRATORY TRACT IRRITATION; HEADACHE, NAUSEA, DIZZINESS, WEAKNESS, FATIGUE,
UNCONSCIOUSNESS AND RESPIRATORY ARREST. SKIN: IRRITATION. MAY BE HARMFUL I F
ABSORBED THROUGH SKIN. EYES: IRRITATION. INGESTION: STOMACH AND/OR INTESTINAL
IRRITATION, NAUSEA, VOMITING AND DIARRHEA. CHRONIC: OVEREXPOSURE TO SOLVENTS
HAS BEEN ASSOCIATED WITH PERMANENT BRAIN AN D NERVOUS SYSTEM DAMAGE.
PROLONGED OR REPEATED BREATHING OF SPRAY MIST AND/OR SANDING DUST OVER PERIOD
OF YEARS MAY CAUSE DUST DISEASE OF LUNGS. INTENTIONAL MISUSE MAY BE HARMFUL
OR FATAL.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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