n-(trichloromethylthio) phthalimide titanium dioxide talc silica, crystalline - quartz; (quartz) stoddard solvent; (naphtha) supdat: spks, flame, & other sources of ignit (i.e, pilot lights, ing 6: travel to source of ignit & flash back. do not smoke while ing 7: in use. clsd cntnrs may explode when overheated. do not apply to ing 8: this prod comes in contact with extreme heat. haz decom prod: extreme heat incl but is not limited to, flame cutting, efts of overexp: are cndtns assoc w/excess skin cont. chronic: avoid ing 11: crystalline silica/quartz which iarc assoc w/incr risk of cancer ing 12: crystalline silica/quartz may also lead to disabling injury known ing 13: brthg excess amts of silica dust. applic of prod is not expected ing 14: silica/quartz. prod cntns titanium dioxide. animals inhal massive ing 15: long-term amts study developed lung tumors. studies w/humans ing 16: incr risk of cancer from expos. potntl for inhal of titanium ing 17: prod cntns talc. in lifetime inhal study female rats expos to ing 18: cosmetic grade talc developed lung cancer. to date, no u.s. ing 19: carcinogen based on this data. first aid proc: overexp/symps of overexp occur during/following use of ing 21: immed; have msds information available. spill proc: cntnrs for disp. only spilled matl & absorbant should be other prec: free fall of liquids in excess of few inches. vent: expos limits, lel below stated limit, & to remove decomp prods
PPG INDUSTRIES INC -- OLYMPIC S/C OIL BEIGE GRAY, 55008
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CHLXR
MSDS NAME: OLYMPIC S/C OIL BEIGE GRAY, 55008
Responsible Party
Name: PPG INDUSTRIES INC
Address: 4325 ROSANNA DR
Box: 9
City: ALLISON PARK PA 15101
Info Phone: 412-492-5555
Emergency Phone Number: 304-843-1300
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: PPG INDUSTRIES INC
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
Name: PPG INDUSTRIES INC. COATINGS & RESINS GP
Address: 4325 ROSEANNA DR PO BOX 9
Box: 9
City: ALLISON PARK PA 15101
Phone: 412-492-5555
=======================================================
Ingredients
=======================================================
Cas: 133-07-3
RTECS #: TI5685000
Name: N-(TRICHLOROMETHYLTHIO) PHTHALIMIDE
% Wt: 1-<5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM DIOXIDE
% Wt: 5-<10
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC
% Wt: 30-<40
OSHA PEL: 0.2 FIBERS/CC
ACGIH TLV: 0.2 FIBER/CC, A1
------------------------------
Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)
% Wt: 0.1-<1
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 0.1 MG/M3 RDUST
------------------------------
Cas: 8052-41-3
RTECS #: WJ8925000
Name: STODDARD SOLVENT; (NAPHTHA)
% Wt: 20-<30
OSHA PEL: 500 PPM
ACGIH TLV: 100 PPM
------------------------------
Name: SUPDAT: SPKS, FLAME, & OTHER SOURCES OF IGNIT (I.E, PILOT LIGHTS,
ELEC MOTORS, STATIC ELEC). INVISIBLE VAPS CAN
-----------------------------
Name: ING 6: TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DO NOT SMOKE WHILE
USING PROD. KEEP CNTNRS TIGHTLY CLSD WHEN NOT
-----------------------------
Name: ING 7: IN USE. CLSD CNTNRS MAY EXPLODE WHEN OVERHEATED. DO NOT APPLY TO
HOT SURFS. TOXIC GASES MAY FORM WHEN
-----------------------------
Name: ING 8: THIS PROD COMES IN CONTACT WITH EXTREME HEAT.
-----------------------------
Name: HAZ DECOM PROD: EXTREME HEAT INCL BUT IS NOT LIMITED TO, FLAME CUTTING,
BRAZING, AND WELDING.
-----------------------------
Name: EFTS OF OVEREXP: ARE CNDTNS ASSOC W/EXCESS SKIN CONT. CHRONIC: AVOID
LONG-TERM & RPTD CONT. PROD CNTNS FORM OF
-----------------------------
Name: ING 11: CRYSTALLINE SILICA/QUARTZ WHICH IARC ASSOC W/INCR RISK OF CANCER
IN LAB ANIMALS. LONG-TERM EXPOS TO
-----------------------------
Name: ING 12: CRYSTALLINE SILICA/QUARTZ MAY ALSO LEAD TO DISABLING INJURY KNOWN
AS SILICOSIS. THESE EFTS AREA ASSOC W/
-----------------------------
Name: ING 13: BRTHG EXCESS AMTS OF SILICA DUST. APPLIC OF PROD IS NOT EXPECTED
TO GENERATE EXCESS AMTS OF RESPIRABLE
-----------------------------
Name: ING 14: SILICA/QUARTZ. PROD CNTNS TITANIUM DIOXIDE. ANIMALS INHAL MASSIVE
QTYS OF TITANIUM DIOXIDE DUST IN
-----------------------------
Name: ING 15: LONG-TERM AMTS STUDY DEVELOPED LUNG TUMORS. STUDIES W/HUMANS
INVOLVED IN MFR OF THIS PIGMENT INDICATE NO
-----------------------------
Name: ING 16: INCR RISK OF CANCER FROM EXPOS. POTNTL FOR INHAL OF TITANIUM
DIOXIDE DUST FROM COATINGS IS VERY LIMITED.
-----------------------------
Name: ING 17: PROD CNTNS TALC. IN LIFETIME INHAL STUDY FEMALE RATS EXPOS TO
ELEVATED RESPIRABLE CONCS (9 TIME PEL) OF
-----------------------------
Name: ING 18: COSMETIC GRADE TALC DEVELOPED LUNG CANCER. TO DATE, NO U.S.
REGULATORY AGENCY HAS CLASSIFIED TALC AS
-----------------------------
Name: ING 19: CARCINOGEN BASED ON THIS DATA.
-----------------------------
Name: FIRST AID PROC: OVEREXP/SYMPS OF OVEREXP OCCUR DURING/FOLLOWING USE OF
PROD, CONT POIS CTL CTR, EMER ROOM/PHYS
-----------------------------
Name: ING 21: IMMED; HAVE MSDS INFORMATION AVAILABLE.
-----------------------------
Name: SPILL PROC: CNTNRS FOR DISP. ONLY SPILLED MATL & ABSORBANT SHOULD BE
PLACED IN THIS CONTAINER.
-----------------------------
Name: OTHER PREC: FREE FALL OF LIQUIDS IN EXCESS OF FEW INCHES.
-----------------------------
Name: VENT: EXPOS LIMITS, LEL BELOW STATED LIMIT, & TO REMOVE DECOMP PRODS
DURING WELDING/FLAME CUTTING.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INGEST: MAY BE HARMFUL. EYE CONT: CAUSES IRRIT.
SKIN CONT: MAY CAUSE SLIGHT IRRIT. PRLNGD/RPTD CONT MAY CAUSE ALLERGIC SKIN
RXN. INHAL: VAP AND/OR MIST MAY BE HARMFUL. RPTD EXPOS TO HIGH VAP CO NCS MAY
CAUSE IRRIT OF RESP SYS & PERM BRAIN & NERV SYS DMG. SIGNS &
SYMPS OF OVEREXP: EYE WATERING, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE-QUARTZ: IARC MONO, VOL 68,
1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994: ANTIC TO BE CARCIN.
Signs And Symptions Of Overexposure: HLTH HAZ: HDCH, NAUS, DIZZ, & LOSS OF
COORDINATION ARE INDICATIONS THAT SOLV LEVELS ARE TOO HIGH. INTENTIONAL
MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATAL. REDNESS,
ITCHING, BURNING S ENSATION & VISUAL DISTURB MAY INDICATE EXCESS EYE
CONT. DRYNESS, ITCHING, CRACKING, BURNING, REDNESS, & SWELL
First Aid: INGEST: DO NOT INDUCE VOMIT. GENTLY WIPE OUT INSIDE MOUTH TO REMOVE
ANY RESIDUAL MATL. EYE CONT: REMOVE CONT LENSES & FLUSH IMMED W/GENTLE
STREAM OF LUKE WARM WATER FOR @ LST 15 MINS. SKIN CONT: FLUSH IMMED W/PLENTY
OF WATER FOR @ LST 15 MINS FOLLOWED BY WASHING W/SOAP & WATER. INHAL:
REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHER SUPPORT MEASURES ARE REQD.
OTHER: IF INGEST, ANY TYPE OF
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: PROVIDE MAX VENT. ONLY PERSONNEL EQUIPPED W/PROPER
NIOSH APPRVD RESP, SKIN, & EYE PROT SHOULD BE PERMITTED IN AREA. REMOVE
ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAND, VERMICULITE/OTHER NONCOMBU
ST ABSORBENT MATL & PLACE IN CLEAN, EMPTY
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE, PROVINCIAL, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WA STE
MANAGEMENT FACILITY.
Handling And Storage Precautions: DO NOT STORE >120F (48C). STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS II
COMBUSTIBLE LIQUIDS.
Other Precautions: VAPS MAY COLLECT IN LOW AREAS. IF THIS MATL IS PART OF
MULTIPLE COMPONENT SYS, READ MSDS(S) FOR OTHER COMPONENT/COMPONENTS BEFORE
BLENDING AS RSLTG MIX MAY HAVE HAZ OF ALL OF ITS PARTS. CNTNRS SHOULD BE
GROUNDED WHEN POURING. AVOID
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point Text: 109F,43C
Lower Limits: 2.8%
Extinguishing Media: USE NFPA CLASS B EXTINGUISHERS (CO*2, DRY CHEM/UNIVERSAL
AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA (SUPDAT)
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER
SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO COOL CLSD CNTNRS TO PVNT
PRESS BUILD-UP & POSSIBLE (SUPDAT)
Unusual Fire/Explosion Hazard: WHEN THIS PROD IS USED, OVERSPRAY & OTHER
COMBUST MATLS SUCH AS PAINT BOOTH FILTERS, RAGS, MASKING MATLS, ETC, CONTAMD
BY COATING MATL ARE SUBJECT TO (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: OVEREXP TO VAPS MAY BE PREVENTED BY ENSURING PROPER
VENT CTLS, VAP EXHAUST/FRESH AIR ENTRY. NIOSH APPRVD AIR PURIFYING RESP
W/APPROP CHEM CARTRIDGES/POS-PRESS, AIR-SUPPLIED RESP MAY ALSO REDUCE EXPOS.
FOR MORE INFORMATION CONT NEHC (FP N).
Ventilation: PROVIDE GEN DILUTION/LOC EXHAUST VENT IN VOL & PATTERN TO KEEP
CONC OF INGREDS LISTED BELOW LOWEST SUGGESTED
Protective Gloves: NEOPRENE RUBB/NITRILE RUBB GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
NEOPRENE RUBBER/NITRILE RUBBER APRON.
Work Hygienic Practices: CLEAN CONTAMINATED CLOTHING AND SHOES.
Supplemental Safety and Health: EXTING MEDIA: CLASS II COMBUST LIQ FIRES. FIRE
FIGHT PROC: AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. IF WATER IS USED, FOG
NOZZLES ARE PREF. EXPLO HAZ: SPONT COMBUST. WETTING CONTAMD MATLS & NOT
PAC KING THEM TIGHTLY TOGETHER IN REFUSE CNTNRS WILL MINIMIZE POTNTL FOR THIS
TO OCCUR. KEEP PROD AWAY FROM HEAT,
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >212F,>100C
Vapor Pres: 8.3
Vapor Density: HVR/AIR
Spec Gravity: 1.282
Evaporation Rate & Reference: 15 (BUOAC = 100)
Solubility in Water: 1.2%
Appearance and Odor: VISCOUS LIQUID WITH AN ODOR CHARACTERISTIC OF THE SOLVENTS
LISTED IN SECTION 2.
Percent Volatiles by Volume: 43.920
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: THIS PRODUCT IS NORMALLY STABLE AND WILL NOT
UNDERGO HAZARDOUS REACTIONS.
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRDCE FOLLOWING HAZ DECOM PRODS WHEN
EXPOS TO EXTREME HEAT: CO, CO*2; LOWER MOLECULAR WT POLYMER FRACTIONS;
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: OLYMPIC S/C OIL BEIGE GRAY, 55008
Assigned IND: Y
Company: PPG INDUSTRIES INC. COATINGS & RESINS GP
Street: 4325 ROSEANNA DR PO BOX 9
PO Box: 9
City: ALLISON PARK PA
Zipcode: 15101
Health Emergency Phone: 304-843-1300
Label Required IND: Y
Date Of Label Review: 07/01/1998
Status Code: C
Label Date: 07/01/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: INGEST: MAY BE HARMFUL. EYE CONT:
CAUSES IRRIT. SKIN CONT: MAY CAUSE SLIGHT IRRIT. ALLERGIC SKIN RXN. INHAL:
VAP AND/OR MIST MAY BE HARMFUL. SIGNS & SYMPS OF OVEREXP: EYE WATERING,
HEADACHES, NAUSEA, DIZZINESS, & LOSS OF CONSCIOUSNESS FROM HIGH SOLVENT
LEVELS. REDNESS, ITCHING, BURNING SENSATION & VISUAL DISTURBANCES FROM
EXCESS EYE CONT. DRYNESS, ITCHING, CRACKING, BURNING RED NESS & SWELL
FROM EXCESS SKIN CONTACT. CHRONIC: CANCER HAZ. CONTAINS CRYSTALLINE
SILICA-QUARTZ WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N). RPTD EXPOS
TO HIGH VAP CONCENTRATIONS MAY CUASE IRRIT OF RESP SYS & PERM BRAIN
& NERVOUS SYSTEM DAMAGE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.