| MSDS | : | DECK AND PATIO ENAMEL, 3-417 | | CAS | : | 68855-54-9
471-34-1
13463-67-7
7732-18-5
107-21-1
14808-60-7 | | NAME | : | silica,amorphous,diatomaceous earth
calcium carbonate
pigments
titanium dioxide (in some colors)
water
ethylene glycol (sara 313) (cercla)
film,formers, resins, & additives
silica, crystalline - quartz
supdat: cancer from exposure. potntl for inhal of titanium dioxide dusts
ing 9: overexposures are not expected, there is no significant hazard for
ing 10: which may cause kidney & liver dmg & which has been shown
ing 11: of these efts has been found in humans. this prod cntns form of
ing 12: associates w/incr risk of cancer in lab animals. long-term
ing 13: also lead to disabling injury known as silicosis. these efts are
ing 14: dust. applic of this prod is not expected to generate excess amts
ing 15: potential hazard for humans is limited.
vent: the lel in fire & explo hazard data section below stated limit;
ing 17: during welding or flame cutting.
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PPG INDUSTRIES INC -- DECK AND PATIO ENAMEL, 3-417
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Material Safety Data Sheet
=======================================================
MSDS Num: CHYKN
MSDS NAME: DECK AND PATIO ENAMEL, 3-417
Responsible Party
Name: PPG INDUSTRIES INC
Address: 4325 ROSANNA DR
Box: 9
City: ALLISON PARK PA 15101
Info Phone: 412-492-5555
Emergency Phone Number: 304-843-1300
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: PPG INDUSTRIES INC
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
Name: PPG INDUSTRIES INC. COATINGS & RESINS GP
Address: 4325 ROSEANNA DR PO BOX 9
Box: 9
City: ALLISON PARK PA 15101
Phone: 412-492-5555
=======================================================
Ingredients
=======================================================
Cas: 68855-54-9
Name: SILICA,AMORPHOUS,DIATOMACEOUS EARTH
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 471-34-1
RTECS #: FF9335000
Name: CALCIUM CARBONATE
% Wt: 10-15
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: PIGMENTS
% Wt: 2-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM DIOXIDE (IN SOME COLORS)
% Wt: 20-25
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: 45-50
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 107-21-1
RTECS #: KW2975000
Name: ETHYLENE GLYCOL (SARA 313) (CERCLA)
% Wt: 2-5
OSHA PEL: N/K (FP N)
ACGIH TLV: C 50 PPM, VAPOR
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Name: FILM,FORMERS, RESINS, & ADDITIVES
% Wt: 20-25
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE - QUARTZ
% Wt: 5-10
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 0.1 MG/M3 RDUST
------------------------------
Name: SUPDAT: CANCER FROM EXPOSURE. POTNTL FOR INHAL OF TITANIUM DIOXIDE DUSTS
FROM COATINGS IS VERY LIMITED. SINCE
-----------------------------
Name: ING 9: OVEREXPOSURES ARE NOT EXPECTED, THERE IS NO SIGNIFICANT HAZARD FOR
MAN. THIS PROD CNTNS ETHYLENE GLYCOL
-----------------------------
Name: ING 10: WHICH MAY CAUSE KIDNEY & LIVER DMG & WHICH HAS BEEN SHOWN
TO CAUSE BIRTH DEFECTS IN LAB ANIMALS. NO EVID
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Name: ING 11: OF THESE EFTS HAS BEEN FOUND IN HUMANS. THIS PROD CNTNS FORM OF
CRYSTALLINE SILICA QUARTZ WHICH IARC
-----------------------------
Name: ING 12: ASSOCIATES W/INCR RISK OF CANCER IN LAB ANIMALS. LONG-TERM
EXPOSURES TO CRYSTALLINE SILICA QUARTZ MAY
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Name: ING 13: ALSO LEAD TO DISABLING INJURY KNOWN AS SILICOSIS. THESE EFTS ARE
ASSOC W/BRTHG EXCESS AMTS OF SILICA
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Name: ING 14: DUST. APPLIC OF THIS PROD IS NOT EXPECTED TO GENERATE EXCESS AMTS
OF RESPIRABLE SILICA QUARTZ, SO THE
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Name: ING 15: POTENTIAL HAZARD FOR HUMANS IS LIMITED.
-----------------------------
Name: VENT: THE LEL IN FIRE & EXPLO HAZARD DATA SECTION BELOW STATED LIMIT;
AND TO REMOVE DECOMPOSITION PRODUCTS
-----------------------------
Name: ING 17: DURING WELDING OR FLAME CUTTING.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INGEST: HARMFUL/FATAL IF SWALLOWED. EYE CONT:
CAUSES IRRIT. SKIN CONT: MAY CAUSE SLIGHT IRRIT. INHAL: VAP & SPRAY MIST
MAY BE HARMFUL. VAP GENERATED & ELEVATED TEMPS IRRITATE EYES, NOSE &
THROA T, SANDING & GRINDING DUSTS MAY BE HARMFUL, IF INHALED. SIGNS &
SYMPS OF OVEREXP: REDNESS, ITCHING, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE QUARTZ: IARC MONO, VOL 68,
1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE CARCIN.
Signs And Symptions Of Overexposure: HLTH HAZ: BURNING SENSATION & VISUAL
DISTURB MAY INDICATE EXCESS EYE CONT. DRYNESS, ITCHING, CRACKING, BURNING,
REDNESS, & SWELL ARE CNDTNS ASSOC W/EXCESS SKIN CONT. CHRONIC: AVOID LONG
TERM & RPTD CO NT. PROD CNTNS TITANIUM DIOXIDE. ANIMALS INHALING MASSIVE
QTYS OF TITANIUM DIOXIDE DUST IN LONG-TERM STUDY (SUPDAT)
First Aid: INGEST: DO NOT INDUCE VOMIT. EYE CONT: FLUSH IMMED W/PLENTY OF WATER
FOR AT LST 15 MINS. SKIN CONT: FLUSH IMMED W/PLENTY OF WATER FOLLOWED BY
WASHING W/SOAP & WATER. INHAL: REMOVE TO FRESH AIR. APPLY ARTF RESP
& OTHER SUPPORTIVE MEASURES AS REQD. OTHER: IF INGEST, ANY TYPE OF
OVEREXP/SYMPS OF OVEREXP OCCUR DURING/FOLLOWING USE OF PROD, CONT POIS CTL
CTR, EMER ROOM/PHYS IMMED; HAVE MSDS INFO AVAIL.
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Handling and Disposal
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Spill Release Procedures: PROVIDE MAX VENT. ONLY PERSONNEL EQUIPPED W/PROPER
NIOSH APPRVD RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA.
REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAWDUST,
VERMICULITE/OTHER ABSOR B MATL & PLACE INTO CONTAINERS FOR DISPOSAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF I/A/W FEDERAL,
STATE, PROVINCIAL, & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY
CONTAINERS SHOULD BE RECYCLED/DISPOSED OF THROUGH APPRVD WASTE MANAGEMENT
FACILITY .
Handling And Storage Precautions: DO NOT STORE >120F. STORE LARGE QTYS IN
BUILDING DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS IIIB COMBUST
LIQUIDS. PROTECT FROM FREEZING.
Other Precautions: IF THE MATERIAL IS PART OF MULTIPLE COMPONENT SYSTEM, READ
MSDS(S) FOR OTHER COMPONENT/COMPONENTS BEFORE BLENDING AS RESULTING MIXTURE
MAY HAVE HAZARDS OF ALL ITS PARTS.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Extinguishing Media: USE NFPA CLASS B EXTINGUISHERS (CO*2, DRY CHEMS/UNIVERSAL
AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH (SUPDAT)
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER
SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO COOL CLSD CNTNRS TO PVNT
PRESS BUILD-UP & POSSIBLE (SUPDAT)
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS EXPLODE OR BURST (DUE TO THE
BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
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Control Measures
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Respiratory Protection: WHERE VENTILATION IS INADEQUATE, USE A SUITABLE NIOSH
APPROVED RESPIRATOR.
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT VOL & PATTERN TO KEEP CONC
OF INGREDS BELOW LOWEST SUGGESTED EXPOS LIMITS,
Protective Gloves: NITRILE, NEOPRENE, OR LATEX GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERMEABLE APRON. WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices: CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES.
Supplemental Safety and Health: APPEAR/ODOR: ANY SOLVENTS LISTED IN
INGREDIENTS. EXTING MEDIA: NFPA CLASS IIIB COMBUST LIQUID FIRES. FIRE FIGHT
PROC: AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG
NOZZ ARE PREF. EFTS OF OVEREXP: DEVELOPED LUNG TUMORS. STUDIES W/HUMANS
INVOLVED MFR OF THIS PIGMENT INDICATE NO INCR RISK OF
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >212F,>100C
Vapor Pres: <18
Vapor Density: HVR/AIR
Spec Gravity: 1.2-1.3
Solubility in Water: 55
Appearance and Odor: VISCOUS LIQUID WITH AN ODOR CHARACTERISTIC OF THE CHEMICAL
FAMILY AND (SUPDAT)
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
OR STRONG OXIDIZING AGENTS.
Materials To Avoid: AVOID WITH STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG
OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRDCE HAZARDOUS DECOMP PRODS WHEN HEATED.
WELDING, BRAZING/FLAME-CUTTING MAY PRDCE FUMES INCL: CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: DECK AND PATIO ENAMEL, 3-417
Assigned IND: Y
Company: PPG INDUSTRIES INC. COATINGS & RESINS GP
Street: 4325 ROSEANNA DR PO BOX 9
PO Box: 9
City: ALLISON PARK PA
Zipcode: 15101
Health Emergency Phone: 304-843-1300
Label Required IND: Y
Date Of Label Review: 10/20/1998
Status Code: C
Label Date: 10/20/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INGEST: HARMFUL OR FATAL. EYE CONT: IRRITATION.
SKIN CONT: SLIGHT IRRITATION. INHAL: MAY BE HARMFUL. VAPOR IRRITATES EYES,
NOSE AND THROAT, SANDING AND GRINDING DUSTS MAY BE HARMFUL, IF INHALED . EYE:
REDNESS, ITCHING, BURNING SENSATION AND VISUAL DISTURBANCES. SKIN: DRYNESS,
ITCHING, CRACKING, BURNING, REDNESS, AND SWELLING. CHRONIC: CANCER HAZARD.
CONTAINS SILICA, CRYSTALLINE QUARTZ WHICH IS LISTED AS HUMAN CARCINOGEN (FP
N). LUNG DAMAGE AND TUMORS. KIDNEY AND LIVER DAMAGE. POSSIBLE BIRTH DEFECTS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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