UNIROYAL CHEMICAL INC -- BETATHANE 23740
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Material Safety Data Sheet
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MSDS Num: BRLBH
MSDS NAME: BETATHANE 23740
Responsible Party
Name: UNIROYAL CHEMICAL CO INC
Address: WORLD HEADQUARTERS
City: MIDDLEBURY CT 06749
Info Phone: 203-573-3303
Emergency Phone Number: 203-723-3670;800-424-9300(CHEMTREC)
Published: Y
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Contractor Summary
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Name: UNIROYAL CHEMICAL CO/NAUGATUCK, CONN 06770
Address: UNKNOWN
City: UNKNOWN NK 00000
Phone: UNKNOWN
Name: UNIROYAL INC OXFORD MANAGEMENT AND RESEARCH CTR
Address: BENSON RD
City: MIDDLEBURY CT 06762
Phone: UNKNOWN
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Ingredients
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Cas: 101-68-8
RTECS #: NQ9350000
Name: ISOCYANIC ACID, METHYLENE DI-P-PHENYLENE ESTER;(METHYLENE BISPHENYL
ISOCYANATE)
OSHA PEL: 0.02 PPM,C
ACGIH TLV: 0.005 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 117-81-7
RTECS #: TI0350000
Name: DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYL-PHTHALATE) (SARA III)
OSHA PEL: 5 MG/M3;10 STEL
ACGIH TLV: 5 MG/M3;10 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Health Hazards Data
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LD50 LC50 Mixture: LD50:(ORAL RAT)>10,000 MG/KG.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CONTACT WITH EYES AND SKIN MAY CAUSE IRRITATION. VAPORS
MAY CAUSE RESPIRATORY IRRITATION OR SENSITIZATION. SYMPTOMS COULD BE
IMMEDIATE OR DELAYED AND INCLUDE CHEST TIGHTNESS, RESPIRATORY DISTRESS OR A
STHMATIC ATTACK. RESPIRATORY RESPONSE MAY BE DELAYED 4-8 HOURS AFTER
EXPOSURE.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MD. SKIN:WIPE
EXCESS. WASH WITH RUBBING ALCOHOL, IF AVAILABLE, FOLLOWED BY SOAP &
WATER. DISCARD SHOES IF CONTAMINATED. INHAL:REMOVE TO FRESH AIR. TRE AT FOR
POTENTIAL RESPIRATORY IRRITATION. INGEST:GET MD IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: WEAR PROTECTIVE EQUIPMENT. CNTN SPILL, COVER LIQUID
W/ABSORBENT MATERIAL (SAWDUST, OIL ABSORBENT, ETC). PLACE IN OPEN TOP CNTNR.
REMOVE TO WELL VENT AREA & TREAT W/DILUTE AMMONIA SOLN (90% WATER/8% CO
NC. NH*4*OH 2% LIQ DETERGENT). LEAVE VENT 24 HRS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: IN A WELL-VENT AREA, FILL DRUMS W/A COUPLE OF INCHES OF
WATER. LEAVE BUNG OFF & SLOWLY SHAKE & ROLL DRUM TO ALLOW WATER
CNTCT. LEAVE OPEN TO AIR FOR SUFFICIENT TIME TO CURE. CURED POLYURETHANE IS
NOT RCRA HAZ WASTE. DISPOSE OF I/A/W LOC, (SUPP DATA)
Handling And Storage Precautions: STORE AWAY FROM SOURCES OF DIRECT HEAT AND
MOISTURE. SEAL CONTAINERS WITH A DRY NITROGEN BLANKET & KEEP CLOSED WHEN
NOT IN USE.
Other Precautions: MOISTURE CONTAMINATION WILL EVOLVE CO*2 AND CREATE PRESSURE
INC CLOSED SYSTEMS. IF MATERIAL IS HEATED, VENTILATE AREA AND USE RESPIRATORY
EQUIPMENT. AVOID BREATHING VAPORS.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: >250F,>121C
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: AVOID WATER CONTAMINATION IN CLOSED CONAINER FOR
CONFINED AREA (CO*2 EVOLVED-EXOTHERMIC).
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Control Measures
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Respiratory Protection: IN THE ABSENCE OF GOOD VENTILATION UNDER EMERGENCY
SITUATION FOR HIGH CONCENTRATIONS, A NIOSH/MSHA APPROVED SCBA OR SUPPLIED
RESPIRATORY PROTECTION IS RECOMMENDED.
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: LAUNDER CONTAMINATED CLOTHING BEFORE REUSING.
Supplemental Safety and Health: SOL IN H*20:REACTS IN WATER TO LIBERATE CO*2
GAS. WASTE DISP METH:STATE OR FEDERAL REGULATIONS REGARDING POLYMERIC WASTE.
WARNING! BURNING THIS MATERIAL CAN PRODUCE TOXIC FUMES. CNDTNS (POLYM):MOVED
T O A SAFE AREA FOR NEUTRALIZATION AND PROPER DISPOSAL.
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Physical/Chemical Properties
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Vapor Density: >8
Spec Gravity: 1.06 (H*2O=1)
Solubility in Water: SUPP DATA
Appearance and Odor: BLUE LIQUID WITH A MILD ODOR
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AVOID CONTAMINATION WITH WATER, OXIDIZERS, INORGANIC ACIDS,
ALDEHYDES OR STRONG BASES.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF
NITROGEN, ISOCYANATES.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: MAY OCCUR BY MOISTURE CONTAM OR OTHER MATLS
THAT REACT W/ISOCYANATES. CONTAM CNTNRS SHOULD BE LEFT VENTED & (SUPP DATA)
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: BETATHANE 23740
Company: UNIROYAL CHEMICAL CO/NAUGATUCK, CONN 06770
Street: UNKNOWN
City: UNKNOWN NK
Zipcode: 00000
Health Emergency Phone: 203-723-3670;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 02/11/1993
Status Code: C
Label Date: 02/11/1993
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: AVOID MOISTURE. COMBUSTIBLE. ACUTE:INHALATION OF VAPORS
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE CHEST TIGHTNESS, RESPIRATORY
DISTRESS OR ASTHMATIC ATTACK. MAY CAUSE EYE AND SKIN IRRITATION. CHRONI
C:NONE LISTED BY MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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