LAROCHE CHEMICALS INC. -- R-11;CFC-11;REFRIGERANT 11
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Material Safety Data Sheet
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NIIN: 00-281-3036
MSDS Num: BRQCP
MSDS NAME: R-11;CFC-11;REFRIGERANT 11
Responsible Party
Name: LAROCHE CHEMICALS INC.
Box: 5500
City: GRAMERCY LA 70052
Info Phone: 504-356-8565 504-869-2300
Emergency Phone Number: 504-356-8565 800-424-9300(CHEMTREC)
Preparer's Name: CORP OFFICE OF REG.AFFAIR
Review Ind: Y
Published: Y
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Contractor Summary
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Name: KAISER ALUMINUM AND CHEMICAL CO
Address: RIVER RD
Box: 337
City: GRAMERCY LA 70052
Phone: 504-355-1260 OR 504-869-5111
Name: LAROCHE CHEMICALS INC
Address: UNKNOWN
Box: 5500
City: GRAMERCY LA 70052
Phone: 504-356-8565
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Item Description Information
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Item Manager: S9G
Item Name: TRICHLOROMONOFLUOROMETHANE,TECHNICAL
Unit of Issue: DR
Quantitative Expression: 00000000200LB
UI Container Qty: 1
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Ingredients
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Cas: 75-69-4
RTECS #: PB6125000
Name: TRICHLOROFLUOROMETHANE (CFC-11) (SARA III)
% Wt: >99.9
Other REC Limits: NONE SPECIFIED
OSHA PEL: 1000 PPM
ACGIH TLV: C, 1000 PPM; 9293
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
Ozone Depleting Chemical: 1
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Health Hazards Data
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LD50 LC50 Mixture: LC50 INHAL MOUSE=10 PPH/30M
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES:MAY CAUSE FROSTBITE.SKIN:MAY CAUSE FROSTBITE.LIQUID
IS NOT INJUROUS IF PROMPTLY WASHED OFF.INHAL:ABOVE 100PPM, MAY CAUSE
NARCOSIS.HIGH CONCENTRATIONS MAY CAUSE ASPHYXIATION.INGEST:NO HAZARD EXPEC
TED.
Explanation Of Carcinogenicity: THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE
IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Signs And Symptions Of Overexposure: BREATHING HIGH CONCENTRATIONS OF VAPOR MAY
CAUSE LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, AND MAY LEAD TO
NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. LIQUID IS
IRRITATING TO S KIN AND EYES, AND MAY CAUSE FROSTBITE.
Medical Cond Aggravated By Exposure: PERSONS WITH CARDIAC ARRYTHMIAS MAY BE AT
INCREASED RISK FROM EXPOSURE.
First Aid: EYES:FLUSH WITH WATER FOR 15 MINUTES.CALL PHYSICIAN IF IRRITATION
PERSISTS.SKIN:FLUSH WITH WATER.CALL PHYSICIAN IF REDDENING
DEVELOPS.INHAL:REMOVE FROM EXPOSURE.GIVE OXYGEN OR ARTIFICIAL RESPIRATION I F
NEEDED AND GET MEDICAL ATTENTION.INGEST:GET PROMPT QUALIFIED MEDICAL
ATTENTION.
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Handling and Disposal
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Spill Release Procedures: STOP DISCHARGE.EVACUATE PERSONNEL.AVOID CONTACT WITH
THE LIQUID.ISOLATE AND REMOVE THE DISCHARGED MATERIAL.SPILLS MUST BE REPORTED
TO THE NATIONAL RESPONSE CENTER,800-424-8802.FOR TRANSPORTATION EMERG ENCIES
CALL 800-424-9300(CHEMTREC).
Neutralizing Agent: NONE
Waste Disposal Methods: THIS PRODUCT IS CLASSIFIED AS HAZARDOUS WASTE
U121.DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.DO NOT
VENT INTO ATMOSPHERE OR DISCHARGE TO GROUND OR WATER.RECYCLING/ RECLAMATION
IS PREFERRED.
Handling And Storage Precautions: STORE IN WELL-VENTILATED, DRY AREA BELOW
125F. PROTECT CONTAINERS FROM PHYSICAL DAMAGE AND KEEP TIGHTLY CLOSED. AVOID
CONTACT WITH FLAMES OR HIGH HEAT
Other Precautions: HIGH PRESSURE CYLINDERS SHOULD NOT BE EXPOSED TO HIGH
TEMPERATURES OR PRESSURES BECAUSE OF THE INCREASED RISK OF CYLINDER
EXPLOSION.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Autoignition Temp Text: NONE
Extinguishing Media: USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures: WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL
FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard: >600F MAY PRODUCE PRODUCTS SUCH AS HALOGEN
ACIDS AND PHOSGENE.
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Control Measures
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Respiratory Protection: WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED
SPACES USE A POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS.
Ventilation: LOCAL EXHAUST FOR OPERATIONS.
Protective Gloves: BUTYL RUBBER
Eye Protection: SAFETY GLASSES,SIDE SHIELDS,MONOGLASSES
Other Protective Equipment: USE IMPERVIOUS CLOTHING TO PROTECT EXPOSED SKIN
FROM LIQUID CONTACT. SAFETY SHOES IF HANDLING CYLINDERS.
Work Hygienic Practices: DO NOT SMOKE IN AREA WHILE PRODUCT IS IN USE.
Supplemental Safety and Health: NONE
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Physical/Chemical Properties
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HCC: G3
B.P. Text: 74.8F,23.8C
M.P/F.P Text: -168F,-111C
Vapor Pres: 694
Vapor Density: 5.1
Spec Gravity: 1.46
Evaporation Rate & Reference: 0.4 ET2O=1
Solubility in Water: NEGLIGIBLE .011%
Appearance and Odor: COLORLESS TO WATER-WHITE, NEARLY ODORLESS LIQUID OR GAS.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAMES,HIGH TEMPERATURE
Materials To Avoid: SLIGHT HYDROLYSIS WITH WATER.
Hazardous Decomposition Products: ABOVE 600F MAY DECOMPOSE TO HALOGEN ACIDS OR
PHOSGENE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 65787
MSDS NAME: R-11;CFC-11;REFRIGERANT 11
MSDS Prepared Date: 08/15/1991
Review Date: 05/07/1998
Tech Entry NOS Shipping Nm: TRICHLOROFLUOROMETHANE,>99.9%
Net Unit Weight: 200 LBS
AF MMAC Code: NR
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 1
Additional Data: THICKNESS OF DRUM MATERIAL IS AS
FOLLOWS:TOP=1.5MM/BODY=0.9MM/BOTTOM=1.5MM.RQ FOR THIS ITEM IS 5000 LBS.
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: R-11;CFC-11;REFRIGERANT 11
Company: LAROCHE CHEMICALS INC
Street: UNKNOWN
PO Box: 5500
City: GRAMERCY LA
Zipcode: 70052
Health Emergency Phone: 504-356-8565 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 05/07/1998
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 05/07/1998
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: EYES:MAY CAUSE FROSTBITE.SKIN:MAY CAUSE
FROSTBITE.LIQUID IS NOT INJUROUS IF PROMPTLY WASHED OFF.INHAL:ABOVE 100PPM,
MAY CAUSE NARCOSIS.HIGH CONCENTRATIONS MAY CAUSE ASPHYXIATION.INGEST:NO
HAZARD EXPEC TED. STORE IN WELL-VENTILATED, DRY AREABELOW 125F. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE AND KEEP TIGHTLY CLOSED. AVOID CONTACT WITH
FLAMES OR HIGH HEAT FIRST AID: EYES:FLUSH WITH WATER FOR 15 MINUT ES.CALL
PHYSICIAN IF IRRITATION PERSISTS.SKIN:FLUSH WITH WATER.CALL PHYSICIAN IF
REDDENING DEVELOPS.INHAL:REMOVE FROM EXPOSURE.GIVE OXYGEN OR ARTIFICIAL
RESPIRATION IF NEEDED AND GET MEDICAL ATTENTION .INGEST:GET PROMPT QUALIFIED
MEDICAL ATTENTION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.