ESSCHEM CO. -- AUDALIN IMPRESSION POLYMER BLUE SHADE# 37264,
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Material Safety Data Sheet
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MSDS Num: CKTZR
MSDS NAME: AUDALIN IMPRESSION POLYMER BLUE SHADE# 37264, Z6001194
Responsible Party
Name: ESSCHEM CO.
Box: 56
City: ESSINGTON PA 19029
Info Phone: 610-521-3800
Emergency Phone Number: 610-497-9000
Preparer's Name: LISA H. CARLOUI
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Assigned Ind: Y
Name: STARKEY LABS
Address: UNK
City: UNK NK 00000
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Contractor Summary
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Name: ESSCHEM CO
Address: WANAMAKER AVE & GOVERNOR PRINTZ
City: ESSINGTON PA 19029
Phone: 215-521-3801
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: REFER TO TOXICOLOGICAL
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: PRIMARY ROUTES OF ENTRY: EYES OR SKIN (NO ABSORPTION);
INHALATION OF DUSTS. TARGET ORGANS: FOR POLYMER: NONE LISTED. FOR DECOMP
PRODUCTS: METHYL METHACRYLATE MONOMER: NOSE, LIVER & KIDNEYS, & ETHYL
ME THACRYLATE MONOMER: NONE LISTED. FOR TITANIUM DIOXIDE: NONE LISTED. FOR
MINERAL PIGMENT: NONE LISTED. THRESHOLD LIMIT VALUE (TLV): FOR POLYMER: NE.
FOR DECOMPOSITION PRODUCTS: METHYL METHACRYLATE MONO MER: 100PPM. FOR ETHYL
METHACRYLATE MONOMER: NE, HOWEVER RECOMMEND 100PPM. FOR TITANIUM DIOXIDE:
10MG/M3. FOR MINERAL PIGMENT: NE. PERMISSIBLE EXPOSURE LIMIT (PEL): FOR
POLYMER: NE. FOR METHYL METHACR YLATE MONOMER: (SEE FED REG)
Explanation Of Carcinogenicity: TITANIUM DIOXIDE IS LISTED AS A POSSIBLE
CARCINOGEN BY IARC. NONE OF THE OTHER COMPONENTS OF THIS MATERIAL ARE LISTED
BY IARC,NTP,OSHA,OR ACIGH AS CACINOGENS. TITANIUM DIOXIDE PRESENT IN PRODUCT
LESS THAN 0.1%.
Signs And Symptions Of Overexposure: FOR POLYMER: OSHA CLASSIFIES THIS MATERIAL
AS PARTICULATES, NOT OTHERWISE CLASSIFIED. EYES, SKIN & RESPIRATORY TRACT
MAY BE IRRITATED BY GROSS OVEREXPOSURE TO PARTICULATES, NOT OTHERWISE
CLASSIFIED, N O MATTER HOW THEY ARE GENERATED. AVOID INHALATION OF DUST. KEEP
DUST OUT OF EYES TO PREVENT POSSIBLE IRRITATION. FOR DECOMPOSITION PRODUCTS:
METHYL METHACRYLATE MONOMER: LIQUID OR HIGH VAPOR CONCENTRA TIONS CAN
IRRITATE EYES, RESPIRATORY SYSTEM & CAUSE SKIN RASHES. PROLONGED EXPOSURE
CAN LEAD TO HEADACHES, NAUSEA, STAGGERED GAIT, CONFUSION, DROWSINESS, &
UNCONSCIOUSNESS. REPEATED & PROLONGED OVEREX POSURE MAY CAUSE(MEDICAL
CONDITION)
Medical Cond Aggravated By Exposure: N/P. OVEREXPOSURE: PERM BRAIN& NERV
SYS DMG,ALLERGIC SKIN RASHES,EYE CORR & PERM INJURY, CHANGES IN LIVER
& KIDNEY FUNCTION OR DAMAGE.ETHYL METHACRYLATE MONOMER:LIQ OR HIGH VAPOR
CONC CAN(TRANSPORT)
First Aid: INHALATION: REMOVE TO FRESH AIR. GET MEDICAL HELP IF DISCOMFORT
PERSISTS. EYES: FLUSH WITH WATER FOR 15 MINUTES, INCLUDING UNDER EYELIDS. GET
MEDICAL HELP IF DISCOMFORT PERSISTS. SKIN: WASH WITH SOAP AND WATER. GET
MEDICAL HELP IF DISCOMFORT PERSISTS. INGESTION: RINSE MOUTH OUT WITH WATER.
CALL DOCTOR IF AMOUNT WAS LARGE. CLOTHING: WASH THOROUGHLY BEFORE REUSE.
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Handling and Disposal
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Spill Release Procedures: SWEEP UP TO AVOID SLIPPING HAZARD. KEEP AIRBORNE
PARTICULATES AT A MINIMUM WHEN CLEANING UP SPILLS.
Waste Disposal Methods: MAY BE DISPOSED OF IN LANDFILL OR INCINERATED. FOLLOW
FEDERAL, STATE AND LOCAL REGULATIONS FOR DISPOSAL.
Handling And Storage Precautions: STORE IN COOL DRY PLACE. KEEP CONTAINER
CLOSED TO PREVENT WATER ABSORPTION AND CONTAMINATION.
Other Precautions: WASH HANDS AND FACE THOROUGHLY WITH SOAP AND WATER AFTER USE
AND BEFORE EATING, DRINKING, OR SMOKING.
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Fire and Explosion Hazard Information
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Flash Point: =303.9C, 579.F
Autoignition Temp Text: NE
Lower Limits: NA
Upper Limits: NA
Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures: USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS
AND FULL PROTECTIVE EQUIPMENT (FP N). AVOID EXTINGUISHING METHODS WHICH MAY
GENERATE DUST CLOUDS. WATER STREAM CAN DISPERSE DUST INTO AIR, PRODUCI NG A
FIRE HAZARD AND POSSIBLE EXPLOSION HAZARD IF EXPOSED TO IGNITION SOURCE.
Unusual Fire/Explosion Hazard: POLYMER DUST IS COMBUSTIBLE. THE EXPLOSIVE
LIMITS OF THE POLYMER PARTICLES SUSPENDED IN AIR ARE APPROXIMATELY THOSE OF
COAL DUST. FIREFIGHTERS SHOULD WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPAR ATUS.
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Control Measures
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Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE
OF CONCERN (FP N). USE TYPE FOR PARTICULATES NOT OTHERWISE CLASSIFIED, IF
NEEDED.
Ventilation: GOOD LOCAL EXHAUST AT PROCESSING EQUIPMENT, INCLUDING BUFFERS,
GRINDERS, SANDERS AND POLISHERS. HIGH TEMPERATURE PROCESSING EQUIPMENT SHOULD
BE WELL VENTILATED.
Protective Gloves: IMPERVIOUS GLOVES (FP N). IF HOT PLASTIC IS HANDLED (MFR).
Eye Protection: SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES.
Other Protective Equipment: EYE WASH STATION AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). HIGH TEMPERATURE PROCESSING EQUIPMENT SHOULD BE WELL
VENTILATED.
Work Hygienic Practices: WASH HANDS AND FACE THOROUGHLY WITH SOAP AND WATER
AFTER USE AND BEFORE EATING, DRINKING OR SMOKING.
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Physical/Chemical Properties
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B.P. Text: NE
Vapor Pres: NA
Vapor Density: NA
Spec Gravity: (H2O=1): 1.125
Evaporation Rate & Reference: NA
Solubility in Water: INSOLUBLE
Appearance and Odor: FINE LIGHT BLUE POWDER. FAINT ODOR IN BULK.
Percent Volatiles by Volume: W / W %: < 5
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEATING ABOVE 240C, 464F.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: METACRYLATE, MONOMERS AND OXIDES OF CARBON.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NA
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Toxicological Information
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Toxicological Information: FOR POLYMER: NO DATA FOUND. RTECS: NOT LISTED. TSCA:
1986 FOR DECOMPOSITION PRODUCTS: METHYL METHACRYLATE MONOMER: ACUTE DERMAL
LD50, RABBIT: 35,500MG/KG. ACUTE INHAL LC50, RAT: >12,500 TO 16,500PPM F
OR 0.5 HOURS. INHAL TCLO HUMAN: 125PPM. INHAL TCLO, HUMAN: 60MG/M3. HUMAN
PATCH TEST: APPROX 1/3 OF SUBJECTS DEVELOPED MILD REDNESS AT SITE OF
APPLICATION. 20% SHOWED SENSITIVITY WHEN TESTED 10 DAYS L ATER. REPRODUCTIVE
EFFECTS: INHAL TCLO, RAT: 109 GM/M3/54 MINS, 6-15 DAYS OF PREGNANCY. INHAL
TCLO RAT: 54MG/M3/24 HOURS, 8 WEEKS OF PREGNANCY. INHAL TCLO, RAT: 4480
MG/M3/2 HOURS, 6-18 DAYS OF PREGNA NCY. RTECS: (OTHER INFO)
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Ecological Information
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Ecological: AQUATIC TOXICITY: FOR DECOMPOSITION PRODUCT, METHYL METHACRYLATE
MONOMER: ESTIMATE OF 96 HOURS MEDIAN THRESHOLD LIMIT(TLMG6): 100-1000PPM.
FLATHEAD MINNOWS AND GOLDFISH TLM24: 420PPM. BLUEGILLS TLM24: 368PPM.
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MSDS Transport Information
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Transport Information: D.O.T./UN SHIPPING NAME: SYNTHETIC GUM RESIN GRANULAR,
NOIBN NMFC ITEM # 46030. MED CONDITIONS: IRRIT EYES & RESP SYSTEM &
CAUSE SKIN RASHES. MUCOUS MEMBRANE IRRIT & RAPID RESPIRATION WAS SEEN IN
ANI MALS FROM A SINGLE EXPOSURE BY INHALATION. TOXICITY IN ANIMALS
ADMINISTERED LETHAL ORAL DOSES INCLUDE WEAK, LABORED & IRREGULAR RESP,
DROP IN ARTERIAL BLOOD PRESS & COMA. EFFECTS IN HUMANS INCLUDE SKI N
IRRITATION WITH DISCOMFORT OR ALLERGIC SKIN RASHES. EYE CONTACT MAY CAUSE
IRRIT WITH DISCOMFORT,TEARING,BLURRING OF VISION. INHALATION MAY CAUSE IRRIT
OF RESP TRACT WITH COUGHING, NON SPECIFIC DISC OMFORT, NAUSEA, HEADACHE(STATE
REG)
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Regulatory Information
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Sara Title III Information: OVEREXPOSURE: FOR TITANIUM DIOXIDE: MAY CAUSE
TEMPORARY DRYING EFFECT OR IRRIT OF MUCOUS MEMBRANE. ALTHOUGH NON-CORROSIVE,
NON-IRRIT & NON-SENSITIZING, IT MAY HAVE A DRYING EFFECT ON SKIN. IN
CONTACT WITH THE EYE IT IS AN INERT FOREIGN BODY. HARMLESS IF SWALLOWED,
PHSIOLOGICALLY INERT. FOR MINERAL PIGMENT: NO KNOWN CASES OF POISONING HAVE
OCCURRED A RESULT OF INGEST: THE PIGMENT IS VIEWED AS HARML ESS.
Federal Regulatory Information: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON
THE CANADIAN DSL. HEALTH HAZARDS: 100 PPM. FOR ETHYL METHACRYLATE MONOMER:
NE, HOWEVER RECOMMEND 100PPM. FOR TITANIUM DIOXIDE: 10MG/M3. FOR MINERAL
PIGMENT : NE.
State Regulatory Information: N/P. TRANSPORT: & OR WEAKNESS. INGESTION:
ANESTHETIC EFFECTS DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION & LOSS
OF CONSCIOUNESS. SYMPTOMS MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING,
LARYNGIT IS, SHORTNESS OF BREATH, HEADACHE, NAUSEA & VOMIT. MAY ALSO
CAUSE ALLERGIC REACTION. FOR TITANIUM DIOXIDE:MAY CAUSE TEMP DRYING EFFECT OR
IRRIT OF MUCOUS MEMBRANES. ALTHOUGH NON-CORROSIVE,NON-IRRIT &
NON-SENSITIZING, IT MAY HAVE A DRYING EFFECT ON SKIN. IN CONTACT W/EYES, IT
IS AN INERT FOREIGN BODY . HARMLESS IF SWALLOWED, PHYSIOLOGICALLY INERT. FOR
MINERAL PIGMENT: NO CASES OF POISONING FROM ING; PIGMENT VIEWED TO BE
HARMLESS.
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Other Information
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Other Information: HAZARDOUS MATERIAL INFORMATION SYSTEM () RATING: HEALTH:1,
FLAMMABILITY:1, REACTIVITY:0. CHEMICAL NAME: BLEND OF METHACRYLATE
HOMOPOLYMERS. (TOXOLOGICAL) 0Z50750000. TSCA INVENTORY: 1986. ETHYL
METHACRYLATE MONOMER: ORAL LD50, RAT: 13,486MG/KG. INHAL LC50, RABBIT:
8300PPM/4H. DERMAL ALD, RABBIT: >10,000MG/KG. RTECS: 0Z4550000. TSCA:
1986. FOR TITANIUM DIOXIDE: LD50 ORAL RAT: >9000MG/KG. RTEC S: TI08755079.
TSCA: 1986. FOR MINERAL PIRMENT: NONE LISTED. RTECS: NOT LISTED. TSCA: 1986.
CAS REG. NO.: NE. FORMULA: PROPRIETARY MIXTURE.
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HAZCOM Label
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MSDS NAME: AUDALIN IMPRESSION POLYMER BLUE SHADE# 37264, Z6001194
Company: ESSCHEM CO
Street: WANAMAKER AVE & GOVERNOR PRINTZ
City: ESSINGTON PA
Zipcode: 19029
Health Emergency Phone: 610-497-9000
Label Required IND: Y
Date Of Label Review: 10/16/2000
Status Code: A
Origination Code: G
Hazard And Precautions: PRIMARY ROUTES OF ENTRY: EYES OR SKIN (NO ABSORPTION);
INHALATION OF DUSTS. TARGET ORGANS: FOR POLYMER: NONE LISTED. FOR DECOMP
PRODUCTS: METHYL METHACRYLATE MONOMER: NOSE, LIVER & KIDNEYS, & ETHYL
ME THACRYLATE MONOMER: NONE LISTED. FOR TITANIUM DIOXIDE: NONE LISTED. FOR
MINERAL PIGMENT: NONE LISTED. THRESHOLD LIMIT VALUE (TLV): FOR POLYMER: NE.
FOR DECOMPOSITION PRODUCTS: METHYL METHACRYLATE MONO MER: 100PPM. FOR ETHYL
METHACRYLATE MONOMER: NE, HOWEVER RECOMMEND 100PPM. FOR TITANIUM DIOXIDE:
10MG/M3. FOR MINERAL PIGMENT: NE. PERMISSIBLE EXPOSURE LIMIT (PEL): FOR
POLYMER: NE. FOR METHYL METHACR YLATE MONOMER: (SEE FED REG)
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information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
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nor any person or persons contracting with any instrumentality of the United
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utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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