LAROCHE CHEMICALS INC. -- R-12,CFC-12,REFRIGERANT 12
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Material Safety Data Sheet
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NIIN: 00-106-1656
MSDS Num: BRSYQ
MSDS NAME: R-12,CFC-12,REFRIGERANT 12
Responsible Party
Name: LAROCHE CHEMICALS INC.
Box: 5500
City: GRAMERCY LA 70052
Info Phone: 800-528-4963
Emergency Phone Number: 800-528-4963/800-424-9300(CHEMTREC)
Preparer's Name: UNKNOWN
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LAROCHE CHEMICALS INC
Address: 1134 JEFFERSON HWY
Box: 5500
City: GRAMERCY LA 70052
Phone: 800-528-4963
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Item Description Information
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Item Manager: S9G
Item Name: DICHLORODIFLUOROMETHANE,TECHNICAL
Specification Number: BB-F-1421
Type/Grade/Class: 12 TYPE
Unit of Issue: CY
Quantitative Expression: 00000000050LB
UI Container Qty: 0
Type of Container: CYLINDER
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Ingredients
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Cas: 75-71-8
RTECS #: PA8200000
Name: DICHLORODIFLUOROMETHANE (SARA III)
% Wt: >99.9
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM; 9293
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
Ozone Depleting Chemical: 1
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Health Hazards Data
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LD50 LC50 Mixture: TLV 1000 PPM
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE- IF INHALED IN CONCENTRATIONS ABOVE 1000 PPM MAY
CAUSE IRRITATION, NARCOSIS & ASPHYXIATION. MAY CAUSE FROSTBITE IF EYES OR
SKIN WAS EXPOSED TO LIQUID OR SPRAY. INGESTION IS UNLIKELY DUE TO EXIST ANCE
AS A GAS AT ROOM TEMPERATURES. CHRONIC- UNKNOWN. TARGET ORGANS:EYES, SKIN,
HEART, LUNG, CNS.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: EYE AND/OR SKIN FROSTBITE, NARCOSIS,
ASPHYXIATION, RESPIRATORY IRRITATION
Medical Cond Aggravated By Exposure: INDIVIDUALS WITH CARDIAC ARRHYTHMIA OR
RESPIRATORY DISORDERS MAY BE AT INCREASED RISK IN SEVERE EXPOSURES.
First Aid: GET MEDICAL ATTENTION IN ALL CASES. EYE/SKIN:FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE
OXYGEN/CPR IF NEEDED. ORAL:NOT NORMALLY CONSIDERED HAZARDOUS BY I NGESTION;
GET MEDICAL ATTENTION AS NECESSARY.
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Handling and Disposal
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Spill Release Procedures: KEEP UPWIND. VENTILATE ENCLOSED SPACES UNTIL GAS IS
DISPERSSED. DO NOT SMOKE OR OPERATE INTERNAL COMBUSTION ENGINES IN IMMEDIATE
VICINITY. IF 5000 LBS (RQ) OR MORE IS RELEASED, NOTIFY THE NATIONAL RES PONSE
CENTER AT 800-424-8802.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: FOR DISCHARGE OR DISPOSING OF WASTE MATERIAL, CONSULT
LOCAL, STATE AND FEDERAL AUTHORITIES. HAZARDOUS WASTE NUMBER: U075. DO NOT
WENT TO ATMOSPHERE. RECYLCE PRODUCT. WASTE OR USED R-12 IS NOT A "U" L ISTED
WASTE.
Handling And Storage Precautions: STORE IN WELL-VENTILATED, DRY AREA (BELOW
125F) AWAY FROM HIGH TEMPERATURES AND FLAMES.
Other Precautions: AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH WITH
SOAP AND WATER BEFORE EATING OR DRINKING. USE WITH ADEQUATE VENTILATION.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR
SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures: WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE
POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard: MAY FORM HYDROGEN FLUORIDE, HYDROGEN CHLORIDE
AND/OR PHOSGENE ABOVE 600C (1112F).
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Control Measures
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Respiratory Protection: WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS
OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR RESPIRATOR WITH FULL
FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE .
Ventilation: LOCAL EXHAUST/MECHANICAL
Protective Gloves: CLOTH-LINED RUBBER GLOVES
Eye Protection: SAFETY GOGGLES/FACE SHIELD
Other Protective Equipment: EYEBATH, SAFETY SHOWER, PROTECTIVE CLOTHING
Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING.
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Physical/Chemical Properties
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HCC: G3
NRC/State LIC No: NOT RELEVANT
B.P. Text: -22F,-30C
M.P/F.P Text: UNKNOWN
Decomp Text: UNKNOWN
Vapor Pres: 4389 @ 70F
Vapor Density: 4.2
Spec Gravity: 1.29
Viscosity: NOT RELEVANT
Evaporation Rate & Reference: >1 (CCL4=1)
Solubility in Water: 0.028%
Appearance and Odor: COLORLESS LIQUID AND VAPOR - FAINT ETHEREAL ODOR
Percent Volatiles by Volume: 100
Corrosion Rate: UNKNOWN
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAME, EXTREMELY HOT METAL SURFACES, HIGH
TEMPERATURES
Materials To Avoid: UNKNOWN
Hazardous Decomposition Products: MAY FORM HYDROGEN FLUORIDE, HYDROGEN CHLORIDE
AND/OR PHOSGENE ABOVE 600C (1112F).
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 47692
MSDS NAME: R-12,CFC-12,REFRIGERANT 12
MSDS Prepared Date: 09/01/1992
Review Date: 10/26/1993
Net Unit Weight: 50 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CY
Container QTY: 0
Type Of Container: CYLINDER
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Detail DOT Information
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DOT PSN Code: ETJ
DOT Proper Shipping Name: DICHLORODIFLUOROMETHANE OR REFRIGERANT GAS R 12
Hazard Class: 2.2
UN ID Num: UN1028
Label: NONFLAMMABLE GAS
Non Bulk Pack: 304
Bulk Pack: 314,315
Max Qty Pass: 75 KG
Max Qty Cargo: 150 KG
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: FKB
IMO Proper Shipping Name: DICHLORODIFLUOROMETHANE
IMDG Page Number: 2129
UN Number: 1028
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-09
MED First Aid Guide NUM: 350
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Detail IATA Information
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IATA PSN Code: IWJ
IATA UN ID Num: 1028
IATA Proper Shipping Name: DICHLORODIFLUOROMETHANE
IATA PSN Modifier: (R12)
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 200
Max Quant Pass: 75KG
Max Quant Cargo: 150KG
Packaging Note Cargo: 200
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Detail AFI Information
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AFI PSN Code: IWJ
AFI Proper Shipping Name: DICHLORODIFLUOROMETHANE
AFI Hazard Class: 2.2
AFI UN ID NUM: UN1028
Special Provisions: P5
Back Pack Reference: A6.3, A6.5
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HAZCOM Label
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MSDS NAME: R-12,CFC-12,REFRIGERANT 12
Company: LAROCHE CHEMICALS INC
Street: 1134 JEFFERSON HWY
PO Box: 5500
City: GRAMERCY LA
Zipcode: 70052
Health Emergency Phone: 800-528-4963/800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 10/26/1993
Status Code: C
MFG Label NO: NOT RELEVANT
Label Date: 10/26/1993
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE- IF INHALED IN CONCENTRATIONS ABOVE 1000 PPM MAY
CAUSE IRRITATION, NARCOSIS & ASPHYXIATION. MAY CAUSE FROSTBITE IF
EYES/SKIN WAS EXPOSED TO SPRAY. INGESTION IS UNLIKELY. CHRONIC- UNKNOWN.
TARGET ORGANS:EYES, SKIN, HEART, LUNG, CNS. STORE IN VENTILATED AREA (BELOW
125F). IF SPILLED, VENTILATE UNTIL GAS IS DISPERSSED. IF 5000 LBS (RQ)/MORE
IS RELEASED, NOTIFY NRC AT 800-424-8802. FIRST AID- GE T MEDICAL ATTENTION IN
ALL CASES. EYE/SKIN:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN.
INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL:NOT
NORMALLY CONSIDERED HAZARDOUS BY ING ESTION; GET MEDICAL ATTENTION AS
NECESSARY.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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