LUCAS-MILHAUPT INC -- SILVER-COPPER-PHOSPHOROUS BRAZING ALLOYS, SIL
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Material Safety Data Sheet
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MSDS Num: BXFGJ
MSDS NAME: SILVER-COPPER-PHOSPHOROUS BRAZING ALLOYS, SIL-FOS 18
Responsible Party
Name: LUCAS-MILHAUPT INC
Address: 5656 S PENNSYLVANIA AVE
Box: 638
City: CUDAHY WI 53110
Info Phone: 414-769-6000
Emergency Phone Number: 414-769-6000
Published: Y
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Contractor Summary
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Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Address: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI 53110
Phone: 414-769-6000
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Ingredients
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Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER (SARA 313) (CERCLA) %:74.75-92.6
% Wt: >75
OSHA PEL: 0.1MG/M3 FUME/1 DUST
ACGIH TLV: 0.2 MG/M3 FUME
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7723-14-0
RTECS #: TH3500000
Name: PHOSPHOROUS (YELLOW) (SARA 302/313) (CERCLA)
% Wt: 5-7.25
OSHA PEL: 0.1 MG/M3
ACGIH TLV: 0.02 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 7440-22-4
RTECS #: VW3500000
Name: SILVER (SARA 313) (CERCLA)
% Wt: 0.9-18
OSHA PEL: 0.01 MG/M3
ACGIH TLV: 0.1 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Name: EFTS OF OVEREXP:MAY PRDCE GASTRIC IRRIT, VOMIT, ABDOM PAIN, HEMMORHAGE
& DIARR. CHRONIC:INHAL:SILVER:MAY PRDCE
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Name: ING 4:ARGYRIA, PERM BLUE-GRAY DISCOLORATION OF SKIN, EYES, MUC MEMBS
& RESP TRACT. COPPER:MAY CAUSE DMG TO LIVER,
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Name: ING 5:KIDNEY, SPLEEN, PANCREAS & BRAIN. INGEST:MAY PRDCE DMG TO
LIVER, KIDNEY, SPLEEN, PANCREAS, SKELETAL SYS & BRAIN.
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Name: OTHER PREC:STANDARDS INSTITUTE (ANSI) Z49.1, "SFTY IN WELDING &
CUTTING" (AMERICAN WELDING SOCIETY, MIAMI, FL 33135).
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Name: VENT:RESPECTIVE OSHA PELS.
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Name: SUPP DAT:PRLNGD/RPTD CONT W/FINELY-DIVIDED MATL.
Other REC Limits: NONE RECOMMENDED
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHAL:COPPER:ACUTE EXPOS MAY CAUSE RESP TRACT IRRIT,
FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAKNESS & METALLIC TASTE.
PHOSPHORUS:STABLE & RELATIVELY NON-TOX AT ROOM TEMP. WHEN HEATED IN
PRESENCE OF AIR, IT IS CONVERTED TO PHOSPHORUS PENTOXIDE, WHICH IS CORR
& IRRIT TO EYES, NOSE, THROAT & MUC MEMBS. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZS:SKIN:CONT W/MATL IN SOLID FORMS
IS NOT KNOWN TO BE HAZ. IN POWDERED FORM, MAY PRDCE LOCALIZED IRRIT,
LOCALIZED ARGYRIA (FROM SILVER), & OR DISCOLORATION & CONT DERM (FROM
COPPER). EYES:IN PO WDERED FORM MAY PRDCE LOCALIZED ARGYRIA, IRRIT, CONJUNCT,
& ULCERATION OF CORNEA. INGEST:IN FINELY-DIVIDED FORM
Medical Cond Aggravated By Exposure: PRE-EXISTING PULMONARY DISEASES (E.G.,
BRONCHITIS, EMPHYSEMA) MAY BE AGGRAVATED BY INHALATION EXPOSURE TO THIS
MATERIAL, PARTICULARLY AS FUME.
First Aid: INHAL:REMOVE FROM CONTAM AREA, ADMIN OXYG, & SEEK MED ATTN. KEEP
WARM & AT REST. PERFORM ARTF RESP IF BRTHG HAS STOPPED. SKIN:REMOVE
CONTAM CLTHG. WASH AFFECTED AREA W/LG QTYS OF WATER FOR AT LST 15 M IN. SEEK
MED ATTN IF NEC. EYES:FLUSH AFFECTED AREAS W/WATER FOR AT LST 15 MIN. SEEK
MED ATTN IF NEC. INGEST:IF CONSCIOUS, INDUCE VOMIT. IF UNCON/CONVULSIVE, SEEK
IMMED MED ASSISTANCE.
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Handling and Disposal
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Spill Release Procedures: CLEAN UP SPILLED MATL SO AS TO MIN DISPERSION OF
DUST. WET SWEEPING/VACUUMING USING HEPA FILTRATION ARE RECOM METHODS. RQ'S OF
COMPONENT MATLS UNDER SARA TITLE III, SECTION 313 ARE AS FOLLOWS:SILVER:1 000
LBS, PHOSPHOROUS:1 LB, COPPER:5000 LBS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). RETURN TO MANUFACTURER OR RECLAIM.
Handling And Storage Precautions: DO NOT STORE AT HIGHLY-ELEVATED TEMPS/IN
PROXIMITY TO INCOMPATIBLE MATLS (SEE REACTIVITY DATA). AVOID FLAMMABLE
FABRICS.
Other Precautions: BRAZING ALLOYS MAY BE USED W/SEPARATELY-APPLIED FLUX WHICH,
WHEN HEATED, MAY EMIT IRRIT &/OR TOX GASES & FUMES. CONSULT MSDS FOR
SPEC FLUX IN USE TO DETERM ITS HAZS & APPROP PROT MEASURES. FOR GEN GUI
DANCE, REFER TO AMERICAN NATL
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Fire and Explosion Hazard Information
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Extinguishing Media: USE DRY POWDER. DO NOT USE WATER.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THIS MATL MAY IGNITE
WHEN EXPOSED TO FLAME/BY RXN W/INCOMPATIBLE MATLS (SEE REACTIVITY DATA FOR
INCOMPATIBLE MATLS). FIRES/EXPLO(SUPDAT)
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Control Measures
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Respiratory Protection: IF EXPOSURE LEVELS EXCEED THE OSHA PEL, WEAR A
NIOSH/MSHA APPROVED RESPIRATOR HAVING A PROTECTION FACTOR APPROPRIATE TO THE
AIRBORNE CONCENTRATIONS OF THE CONTAMINANTS GENERATED.
Ventilation: USE MECH LOC EXHST VENT ADEQ TO MAINTAIN AIRBORNE CONCS OF ALL
COMPONENTS & THEIR DECOMP PRODS TO W/IN THEIR
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: EMER EYE BATH & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FPN). APPROP PROT CLTHG TO PVNT SKIN INJURIES (SUPP DAT)
Work Hygienic Practices: TO AVOID INGEST OF MATL, WASH HANDS & FACE BEFORE
EATING, DRINKING, OR CONSUMPTION OF TOBACCO.
Supplemental Safety and Health: EXPLO HAZS:INVOLVING MATL MAY RELS POTNTLY TOX
EMISSIONS OF METAL, METAL OXIDE, & PHOSPHORUS FUMES (SEE INGS FOR HAZ
COMPONENTS & DECOMP PRODS). MATL TO AVOID:PEROXYFORMIC ACID; F*2;
PERMONOSULFURIC A CID; CHLORATES; CS*2; SEOCL; SEOF; SEF*4; BROMATES;
IODATES. OTHER PROT EQUIP:FROM HAZS OF BRAZING &/OR FOR
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Physical/Chemical Properties
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M.P/F.P Text: 1190F,643C
Spec Gravity: 7.86-8.44
Solubility in Water: INSOLUBLE
Appearance and Odor: LIGHT-COPPER METAL IN FORM OF WIRE, ROD, STRIP, POWDER OR
PREFORMED SHAPES.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE.
Materials To Avoid: ACETYLENE; NH*3; HNO*3; AZIDES; ETHANOL; ETHYLENE IMINE;
MG; CF*3; CL*2; CLO*2; CLO; INORG & ORG PEROXIDES; (SUPP DATA)
Hazardous Decomposition Products: HEATING AT BRAZING TEMPS MAY LIBERATE OXIDES
OF METALS & PHOSPHORUS (FOR SPEC HAZ COMPONENTS & DECOMP PRODS, SEE INGS).
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: SILVER-COPPER-PHOSPHOROUS BRAZING ALLOYS, SIL-FOS 18
Company: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Street: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI
Zipcode: 53110
Health Emergency Phone: 414-769-6000
Label Required IND: Y
Date Of Label Review: 04/07/1995
Status Code: C
Label Date: 04/07/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHAL:MAY CAUSE RESP TRACT IRRIT, FEVER, MUSCLE
ACHE, CHILLS, COUGH, WEAKNESS & METALLIC TASTE. PHOSPHORUS PENTOXIDE IS
CORR & IRRIT TO EYES, NOSE, THROAT & MUC MEMBS. SKIN:IN POWDERED
FORM, MAY PRODUCE LOCALIZED IRRIT, LOCALIZED ARGYRIA (FROM SILVER), AND/OR
DISCOLORATION & CONT DERM (FROM COPPER). EYES:IN POWDERED FORM MAY
PRODUCE LOCALIZED ARGYRIA, IRRIT, CONJUNCT & ULCERATION OF CORNEA.
INGEST:IN FINELY-DIVIDED FORM MAY PRDCE GASTRIC IRRIT, VOMIT, ABDOM PAIN,
HEMORRHAGE & DIARR. CHRONIC:SILVER:MAY PRDCE ARGYRIA, PERM BLUE-GRAY
DISCOLORATION OF SKIN, EYES, MUCOUS MEMBRANES AND RESPIRA TORY TRACT.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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