===================== Product Identification =====================
MSDS NAME:GENETRON 22 CHLORODIFLUOROMETHANE
NIIN:00-106-1659
MSDS Number: BJPBQ
=== Responsible Party ===
Company:ALLIED-SIGNAL CORP,ENGINEERED MATERIALS DIV
Address:PARK AVE AND COLUMBIA RD
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
Info Phone Num:201-455-2000
Emergency Phone Num:201-455-2000
CAGE:40991
=== Contractor Identification ===
Company:ALLIED-SIGNAL CORP ENGINEERED MATERIALS DIV
Address:PARK AVE AND COLUMBIA RD
Box:City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
Phone:201-455-2000
CAGE:40991
============= Composition/Information on Ingredients =============
Name:CHLORODIFLUOROMETHANE
CAS:75-45-6
RTECS #:PA6390000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM
ACGIH TLV:1000PPM; 9192
Ozone Depleting Chemical:2
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: THIS MATERIAL IS LOW
TOXICITY AT CONCENTRATIONS AS HIGH AS 4%. WHEN OXYGEN LEVELS ARE
REDUCED TO 12-14%, ASPHYXIATION WILL OCCUR. NARCOTIC EFFECTS AT
LOWER CONCENTRATIONS. EYES/SKIN: FROST BITE. INGESTION: NOT
APPLICABLE, SINCE MATERIAL IS GASEOUS AT NORMAL TEMPERATURE AND
PRESSURE.
Explanation of Carcinogenicity:PRODUCT CONTAINS NO MATERIALS CURRENTLY
CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:INHALATION: WHEN OXYGEN LEVELS ARE REDUCED TO
12-14%, LOSS OF COORDINATION, INCREASED PULSE RATE, AND DEEPER
RESPIRATION. SKIN/EYES: FROSTBITE, INDICATED BY PALLOR OR REDNESS,
LOSS OF SENSATION AND SW ELLING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:IN CASE OF INHALATION, REMOVE IMMEDIATELY TO FRESH AIR. IF
BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. USE OXYGEN AS
REQUIRED. DO NOT GIVE EPINEPHRINE(ADRENALINE). IN CASE OF SKIN/EYE
CONTACT, IMMEDIATELY BATHE(DO NOT RUB) ANY FROSTBITE WITH LUKEWARM
WATER. CONTACT A PHYSICIAN FOR ANY LOW TEMPERATURE BURNS. IN CASE
OF INGESTION, THIS IS IMPROBABLE DUE TO LOW BOILING POINT.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:ANY STANDARD AGENT--CHOOSE THE ONE MOST SUITABLE
FOR SURROUNDING FIRE. THIS MATERIAL IS NOT FLAMMABLE.
Fire Fighting Procedures:ALTHOUGH NOT FLAMMABLE, WHEN THIS MATERIAL IS
IN A FIRE, FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING
APPARATUS FOR PROTECTION AGAINST SUFFOCATION/FUMES.
Unusual Fire/Explosion Hazard:USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
================== Accidental Release Measures ==================
Spill Release Procedures:USING A SELF-CONTAINED AIR SUPPLY AND
PROTECTION AGAINST FROSTBITE, PERSONNEL SHOULD ATTEMPT TO CLOSE
VALVES OR REPAIR SOURCE OF LEAK IF WITHOUT RISK. IF LARGE QUANTITY
IS RELEASED, EVACUATE PERSONNEL AND ALLOW TO DISSIPATE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE GAS; AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. DO NOT PUNCTURE OR DROP CYLINDERS OR EXOSE
THEM TO OPEN FLAME OR EXCESSIVE HEAT.
Other Precautions:USE AUTHORIZED CONTAINERS ONLY. STORE IN COOL, DRY,
WELL-VENTILATED AREA AWAY FROM HEAT, FLAME OR COMBUSTIBLES. PROTECT
CYLINDERS AND FITTINGS FROM PHYSICAL DAMAGE. STORAGE IN SUBSURFACE
LOCATIONS SHO ULD BE AVOIDED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE GENERALLY REQUIRED FOR NORMALLY VENTED
SITUATIONS. OTHERWISE, WEAR SUPPLIED AIR OR SELF-CONTAINED
BREATHING APPARATUS, NIOSH APPROVED. AT HIGH CONCENTRATIONS, ADD A
FULL FACEPIECE.
Ventilation:VENTILATION SHOULD BE ADEQUATE TO MEET TLV REQUIREMENTS AND
MINIMIZE EXPOSURE SHOULD MATERIAL BE RELEASED.
Protective Gloves:PVA, NEOPRENE
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:IMPERVIOUS SHOES AND CLOTHING, THERMALLY
INSULATED. PROVIDE CONVENIENT WATER SOURCE FOR FIRST AID TREATMENT
FOR FROSTBIT
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES.
Supplemental Safety and Health
PROVIDE LOCAL EXHAUST AT FILLING ZONES AND WHERE LEAKAGE IS PROBABLE.
MECHANICAL (GENERAL) VENTILATION IS ADEQUATE FOR OTHER OPERATING
AREAS AND FOR STORAGE AREAS.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:B.P. Text:-41F,-41C
Melt/Freeze Pt:M.P/F.P Text:-256F,-160C
Vapor Pres:136PSIA@21
Vapor Density:2.98
Spec Gravity:1.21@21.1CPRESS
Evaporation Rate & Reference:NOT APPLICABLE - GAS
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUIFIED GAS WITH FAINT ETHEREAL ODOR AT
HIGHER CONCENTRATIONS
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, ALKALI METALS, ALKALI EARTH METALS, FRESHLY EXPOSED
ALUMINUM SURFACES.
Stability Condition to Avoid:FLAMES, LIGHTED CIGARETTES, HOT SPOTS,
WELDING.
Hazardous Decomposition Products:HALOGENS, HALOGEN ACIDS, CARBON
DIOXIDE, CARBON MONOXIDE, AND POSSIBLY CARBONYL HALIDES SUCH AS
PHOSGENE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MAY BE SUBJECT TO STATE AND LOCAL
REGULATIONS. USERS SHOULD REVIEW THEIR OPERATIONS IN TERMS OF
APPLICABLE STATE, LOCAL AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|
|