===================== Product Identification =====================
MSDS NAME:MERCURIC OXIDE CELL,BA-1574/U
NIIN:00-073-8939
MSDS Number: BKBJK
=== Responsible Party ===
Company:DURACELL INC TECHNICAL SALES & MARKETING GROUP
Address:BERKSHIRE INDUSTRIAL PARK BLDG 9
City:BETHEL
State:CT
ZIP:06801
Country:US
Info Phone Num:800-243-9540/FAX 203-796-4518
Emergency Phone Num:203-796-4654/617-449-7600
CAGE:90303
=== Contractor Identification ===
Company:DURACELL INC TECHNICAL SALES AND MARKETING GROUP
Address:BERKSHIRE CORPORATE PARK
Box:City:BETHEL
State:CT
ZIP:06801
Country:US
Phone:203-796-4000
CAGE:90303
============= Composition/Information on Ingredients =============
Name:POTASSIUM HYDROXIDE (SARA III)
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C, 2 MG/M3
ACGIH TLV:C 2 MG/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:MERCURIC OXIDE (SARA III)
CAS:21908-53-2
RTECS #:OW8750000
Fraction by Wt: 35 - 45%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG HG/M3;SKIN;C
ACGIH TLV:0.1 MG HG/M3; 9293
Name:MERCURY (SARA III)
CAS:7439-97-6
RTECS #:OV4550000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, C, 0.1 MG/M3
ACGIH TLV:S, 0.05 MG/M3; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 12%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG ZNO/M3
ACGIH TLV:10 MG ZNO/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:MANGANESE DIOXIDE
CAS:1313-13-9
RTECS #:OP0350000
Fraction by Wt: 6%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG MN/M3 CEILING
ACGIH TLV:5 MG MN/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV FOR MERCURY IS 0.05 MG/M3.
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE AND CHRONIC- RISK OF EXPOSURE
OCCURS ONLY IF CELL IS MECHANICALLY, PHYSICALLY OR ELECTRICALLY
ABUSED. KOH IS CAUSTIC AND MAY CAUSE SKIN BURNS, SEVERE EYE INJURY.
AT ELEVATED TEMPERATURES, MERCUR Y VAPORS MAY BE GENERATED WHICH
CAN CAUSE MERCURY INTOXICATION, CNS DISTURBANCES AND DISORDERS OF
THE GUMS AND MOUTH.
Effects of Overexposure:RISK OF EXPOSURE OCCURS ONLY IF CELL IS
MECHANICALLY, PHYSICALLY OR ELECTRICALLY ABUSED. KOH IS CAUSTIC AND
MAY CAUSE SKIN BURNS, SEVERE EYE INJURY. AT ELEVATED TEMPERATURES,
MERCURY VAPORS MAY BE GEN ERATED WHICH CAN CAUSE MERCURY
INTOXICATION, CNS DISTURBANCES AND DISORDERS OF THE GUMS AND MOUTH.
Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT
GENERALLY AGGRAVATE ANY MEDICAL CONDITION.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IMMEDIATELY. EYE/SKIN:IMMEDIATELY FLUSH
WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN.
INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.
ORAL:GET EMERGENCY MEDI CAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS OPERATED IN THE POSITIVE
PRESSURE MODE.
Unusual Fire/Explosion Hazard:CELL MAY RELEASE TOXIC MERCURY VAPOR WHEN
THE INTEGRITY OF THE CELL IS BROKEN OR INVOLVED IN FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:BATTERY AND CELL CASES WILL NORMALLY CONTAIN
MATERIALS OF CONCERN. USE INDUSTRIAL ABSORBENT TO COLLECT LIQUID
POTASSIUM HYDROXIDE. AVOID SKIN AND EYE CONTACT. DO NOT INHALE
VAPORS. USE RUBBER GLOVES W HEN HANDLING LEAKERS OR INTERNAL PARTS
OF CELLS.
Neutralizing Agent:ACID FOR POTASSIUM HYDROXIDE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. AVOID
BREAKING, CRUSHING OR OTHERWISE DESTROYING THE PHYSICAL INTEGRITY
OF THE CELL OR BATTERY.
Other Precautions:DO NOT TOUCH BROKEN OR LEAKING BATTERIES. AVOID
MECHANICAL OR ELECTRICAL ABUSE. DO NOT ATTEMPT TO RECHARGE. AVOID
SHORT CIRCUITS. DO NOT CARRY BATTERIES LOOSE IN POCKET OR BAG. KEEP
BATTERIES AWAY FRO M SMALL CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS WHEN CELLS ARE INVOLVED IN A FIRE.
Ventilation:USE ADEQUATE LOCAL EXHAUST VENTILATION WHEN CELLS ARE
INVOLVED IN A FIRE.
Protective Gloves:NEOPRENE, LATEX-NITRILE, OR RUBBER
Eye Protection:SAFETY GLASSES WHEN HANDLING LEAKERS
Other Protective Equipment:EYE WASH STATION
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
THE ITEM OF SUPPLY IS A BATTERY (AN ARTICLE). UNDER NORMAL CONDITIONS
OF USE AND STORAGE, NO EXPOSURE TO HAZARD CHEMICALS POSSIBLE. THE
PHYSICAL PROPERTIES GIVEN BY MSDS COVERS THE COMPONENTS OF THE B
ATTERY.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:357C (HG)
Melt/Freeze Pt:M.P/F.P Text:360C KOH
Decomp Temp:Decomp Text:500C HGO
Vapor Pres:1 @126C HG
Spec Gravity:11.1 (HGO)
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water: 50 % KOH
Appearance and Odor:CLEAR LIQUID (KOH), RED CRYSTALS (HGO), BLACK
POWDER (MNO2), GREY POWDER (HG+ZN
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:OVER-HEATING, CHARGING, SHORT CIRCUITS,
DISASSEMBLING, CRUSHING OR PUNCTURING
Hazardous Decomposition Products:TOXIC MERCURY VAPORS CAN BE PRODUCED
AT ELEVATED TEMPERATURES. LIQUID POTASSIUM HYDROXIDE CAN LEAK.
==================== Disposal Considerations ====================
Waste Disposal Methods:CELLS AND BATTERIES MAY BE RETURNED AT SENDERS
EXPENSE TO A PERMITTED TREATMENT, STORAGE, DISPOSAL FACILITY
(TSDF). DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL LAW S AND REGULATIONS. DO NOT INCINERATE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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