===================== Product Identification =====================
MSDS NAME:2-ETHYLHEXYL ACRYLATE
NIIN:00N014842
MSDS Number: BKMBR
=== Responsible Party ===
Company:HOECHST CELANESE CORPORATION
Box:569320
City:DALLAS
State:TX
ZIP:75356-9320
Country:US
Info Phone Num:201-231-2566
Emergency Phone Num:201-231-4944
CAGE:02687
=== Contractor Identification ===
Company:HOECHST CELANESE CORP PRINTING PRODUCTS DIV
Address:3070 U S HWY 22 W
Box:3700
City:SOMERVILLE
State:NJ
ZIP:08870
Country:US
Phone:908-231-3829
CAGE:02687
============= Composition/Information on Ingredients =============
Name:ING 6: CONT W/EYES, SKIN & CLTHG. WASH THOROUGHLY W/SOAP &
WATER AFTER HANDLING. WASH CONTAM CLTHG THORO (SEE ING 8)
RTECS #:9999999ZZ
Name:ING 7: BEFORE RE-USE. DISCARD CONTAM LEATHER CLTHG. AIR
SHOULD BE USED TO BLANKET & SPARGE STORAGE VESSELS (SEE ING 9)
RTECS #:9999999ZZ
Name:ING 8: IN ORDER FOR INHIBITOR TO FUNCTION. OXYGEN-FREE
ATMOSPHERES SHOULD NEVER BE USED. RESP PROT: FULL (SEE ING 10)
RTECS #:9999999ZZ
Name:ING 9: FACEPIECE OPERATED IN PRESS-DMD OR OTHER POSITIVE
PRESS MODE OR W/FULL FACEPIECE, HELMET OR HOOD (SEE ING 11)
RTECS #:9999999ZZ
Name:ING 10: OPERATED IN CONTINUOUS-FLOW MODE. NIOSH/MSHA APPRVD
SCBA W/FULL FACEPIECE OPERATED IN PRESS-DMD (SEE ING 12)
RTECS #:9999999ZZ
Name:ING 11: OR OTHER POSITIVE PRESS MODE.
RTECS #:9999999ZZ
Name:2-ETHYLHEXYL ACRYLATE (99.5%)
CAS:103-11-7
RTECS #:AT0855000
Fraction by Wt: 99.5%
Other REC Limits:5 PPM (MFR)
Name:SPILL PROC: OR DISP TO CLEAN UP SPILL, FLUSH AREA SPARINGLY
W/WATER OR USE AN ABSORBENT. AVOID RUNOFF INTO (SEE ING 3)
RTECS #:9999999ZZ
Name:ING 2: STORM SEWERS & DITCHES WHICH LEAD TO NATL WATERWAYS.
IF AN ODOR OR ACIDITY PROBLEM EXISTS, ADD LIME (SEE ING 4)
RTECS #:9999999ZZ
Name:ING 3: OR SODIUM BICARBONATE. CALL THE NATIONAL RESPONSE
CTR (800-424-8602) IF SPILL IS EQUAL TO OR GREATER (SEE ING 5)
RTECS #:9999999ZZ
Name:ING 4: THAN REPORTABLE QUANTITY (100 LB DAY) UNDER
"SUPERFUND". ALL CLEAN-UP & DISPOSAL SHOULD BE CARRIED (SEE ING 6)
RTECS #:9999999ZZ
Name:ING 5: OUT I/A/W FED, ST & LOC REGS. IF REQUIRED, ST & LOC
AUTH SHOULD BE NOTIFIED. OTHER PREC: VAP. AVOID (SEE ING 7)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORL,RAT)5.7G/KG;(DERM,RBT)8.5G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:(ACUTE) INGEST: CAN SEVERELY IRRITATE
MOUTH, THROAT & STOMACH. CAN CAUSE DIZZ, SEVERE DIFFICULTY IN
BRTHG, AND NERVOUSNESS. PRACTICALLY NON-TOXIC TO ANIMALS. INHAL:
CAN IRRITATE NASAL PASSAGES, THROAT & LUNGS. CAN CAUSE DROWSINESS
& HDCH. CAN CAUSE PULM EDEMA (ACCUMULATION OF FLUID IN LUNGS); (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SIGNS & SYMPTOMS CAN BE DELAYED FOR
SEVERAL HRS. SKIN: ESSENTIALLY NON-IRRITATING. SENSITIZATION
(ALLERGIC RXN) CAN OCCUR. SLIGHTLY TOXIC TO ANIMALS BY ABSORPTION.
EYE: CAN CAUSE SEVERE INJU RY - DAMAGE REVERSIBLE. (CHRONIC) NO
ADVERSE EFFECTS WERE SEEN IN A 90-DAY INHAL STUDY OF RATS EXPSD
(SEE SUPP DATA)
Medical Cond Aggravated by Exposure:SIGNIFICANT EXPOSURE TO CHEM MAY
ADVERSELY AFFECT PEOPLE W/CHRONIC DISEASE OF THE RESPIRATORY
SYSTEM, SKIN AND/OR EYES.
======================= First Aid Measures =======================
First Aid:INGEST: PATIENT SHOULD BE MADE TO DRINK LARGE QTYS OF WATER.
DO NOT INDUCE VOMIT. CONTACT MD IMMED. INHAL: REMOVE PATIENT FROM
CONTAM AREA. IF BRTHG HAS STOPPED, GIVE ARTF RESP, THEN OXYGEN IF
NEEDED. CONTACT MD IMMED. SKIN: REMOVE CONTAM CLTHG & WASH CONTAM
SKIN W/LRG AMTS OF WATER. IF IRRIT PERSIST, CONSULD MD. EYE: FLUSH
EYES W/WATER FOR AT LEAST 15 MIN. CONTACT MD IMMED.
===================== Fire Fighting Measures =====================
Flash Point:SEE SUPP DATA
Lower Limits:0.7
Upper Limits:8.2
Extinguishing Media:CO*2 OR DRY CHEM FOR SM FIRES. ALCOHOL-TYPE AQUEOUS
FILM-FORMING FOAM OR WATER SPRAY FOR LRG FIRES.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA W/FULL FACEPIECE &
OPERATED IN PRESS DMD OR OTHER POSITIVE PRESS MODE. USE WATER SPRAY
TO COOL FIRE EXPSD STRUCTURES AND VESSELS.
Unusual Fire/Explosion Hazard:RAPID. UNCONTROLLED POLYMERIZATION CAN
CAUSE EXPLOSION. MATERIAL CREATES A SPECIAL HAZARD BECAUSE IT
FLOATS ON WATER.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM IGNIT SOURCES. CAUTION: SPONTANEOUS POLYM
CAN OCCUR. AVOID EYE OR SKIN CONT. PLACE LEAKING CNTNRS IN
WELL-VENT AREA. IF FIRE POTENTIAL EXISTS, BLANKET SPILL TO DISPERSE
VAPS. CONTAIN SPILL TO MIN IMIZE CONTAM AREA & FACILITATE SALVAGE
(SEE ING 2)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, WELL-VENT AREA. DO
NOT EXPOSE TO TEMPS ABOVE 100F. KEEP AWAY FROM HEAT, SPARKS &
FLAME. KEEP CNTNRS CLOSED. SAMPLES (SEE OTHER PREC)
Other Precautions:HNDLG/STOR PREC: SHOULD BE STORED IN OPAQUE OR AMBER
GLASS CNTNRS. USE ONLY DOT-APPRVD CNTNRS. DO NOT LOAD INTO
COMPARTMENTS ADJACENT TO HEATED CARGO. WHEN TRANSFERRING FOLLOW
PROPER GROUNDING PROC. U SE W/ADEQ VENT. AVOID BRTHG (SEE ING 6)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPRVD CHEM CART RESP W/ORG VAP CART
W/FULL FACEPIECE. NIOSH/MSHA APPRVD GAS MASK W/ORG VAP CANISTER
(CHIN-STYLE OR FRONT OR BACK MOUNTED CANISTER) W/FULL FACEPIECE.
NIOSH/MSHA APPRVD TYPE 'C' SUPPLIED AIR RESP W/FULL (SEE ING 9)
Ventilation:LOCAL EXHST REC WHEN APPROP TO CONTROL EMPLOYEE EXPOS. MECH
(GEN) NOT REC AS SOLE MEANS OF CONTROLLING EMPLOYEE EXPOS.
Protective Gloves:NEOPRENE OR RUBBER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:FOR OPER WHERE SPILLS/SPLASHING CAN OCCUR,
IMPERVIOUS BODY COVERING & BOOTS. A SAFETY SHOWER & EYE BATH SHOULD
BE AVAIL.
Work Hygienic Practices:WASH THOROUGHLY WITH SOAP AND WATER AFTER
HANDLING.
Supplemental Safety and Health
FL PT (TEST METH): TOC; 198F. TCC; 188F. CNDTNS (POLYM): STORAGE
VESSELS OR CNTNRS. EFTS OF OVEREXP: TO 10 PPM OF 2-ETHYLHEXYL
ACRYLATE AS VAP. AT 30 & 100 PPM, NASAL LESIONS (PROBABLY DUE TO
LOCAL IR RIT) & BODY WEIGHT DECREASES WERE THE PRIMARY EFFECTS
OBSERVED.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:416F,213C
Vapor Pres:0.14
Vapor Density:6.4
Spec Gravity:0.8865
Evaporation Rate & Reference:<0.02 (BUAC = 1)
Solubility in Water:0.01
Appearance and Odor:CLEAR, COLORLESS, MOBILE LIQUID; STRONG, ACRID,
MUSTY ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
PEROXIDES, FOR EXAMPLE. T-BUTYL PEROXIDE AND HYDROGEN PEROXIDE; OTHER
POLYMERIZATION INITIATORS; OXIDIZING AGENTS.
Stability Condition to Avoid:TEMPERATURES ABOVE 100F; SUNLIGHT; X-RAY
OR ULTRA-VIOLENT RADIATION; SPARKS AND FLAME.
Hazardous Decomposition Products:CO.
Conditions to Avoid Polymerization:UNCONTROLLED POLYM CAN CAUSE RAPID
EVOLUTION OF HEAT & INCR PRESS WHICH CAN RESULT IN VIOLENT RUPTURE
OF (SUPP DATA)
==================== Disposal Considerations ====================
Waste Disposal Methods:PROD WHEN SPILLED/DISPOSED IS A HAZ SOLID WASTE
AS DEFINED IN RESOURCE CONSERVATION RECOVERY ACT REGS (40CFR261).
PREFERRED METHOD IS INCINERATION OR BIOLOGICAL TREATMENT IN FED ST
APPRVD FACILITY. DI SPOSE I/A/W FED, ST & LOCAL LAWS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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