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MSDS  : PROPARGYL ALCOHOL 99%, P5080-3
CAS  : 107-19-7
NAME  : propargyl alcohol (sara iii)
===================== Product Identification =====================

MSDS NAME:PROPARGYL ALCOHOL 99%, P5080-3
NIIN:00N016564
MSDS Number: BKRYS
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Info Phone Num:414-273-3850
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928

============= Composition/Information on Ingredients =============

Name:PROPARGYL ALCOHOL (SARA III)
CAS:107-19-7
RTECS #:UK5075000
Fraction by Wt: 99%
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 1 PPM; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

===================== Hazards Identification =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT) 55MG/KG (SEE SUPP DATA)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHALED, SWALLOWED, OR
ABSORBED THROUGH SKIN. CAUSES SEVERE IRRIT. HIGH CONCENTRATION ARE
EXTREMELY DESTRUCTIVE TO TISSUES OF MUCOUS MEMBRANES AND UPPER RESP
TRACT, EYES AND SKIN.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. TO
THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

======================= First Aid Measures =======================

First Aid:EYE/SKIN:IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF
BREATHI NG IS DIFFICULT, GIVE O*2. CALL A MD. REMOVE AND WASH
CONTAMINATED CLOTHING PROMPTLY.INGEST:CALL MD IMMED .

===================== Fire Fighting Measures =====================

Flash Point:97. F,36.1C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM. H*2O MAY BE EFFECTIVE FOR COOLING,BUT MAY NOT
EXTINGUISH.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. FLAMMABLE. USE
WATER SPRAY TO COOL FIRE-EXPOSD CONTAINERS.
Unusual Fire/Explosion Hazard:VAP MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IFNITION & FLASH BACK. CONTAINER EXPLOSION MAY OCCUR
UNDER FIRE CONDITIONS. FORMS EXPLOSIVE MIXTURES IN AIR.

================== Accidental Release Measures ==================

Spill Release Procedures:EVAC AREA.SHUT OFF ALL SOURCES OF
IGNITION.WEAR NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS & HEAVY RUB
GLOVES.COVER W/AN ACTIVATED CARBON ABSORB,TAKE UP & PLACE IN CLSD
CNTNRS.TRANSPORT OUTDOORS.VENT AREA & WASH SPILL SITE AFTER MATL
PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

====================== Handling and Storage ======================

Handling and Storage Precautions:USE NON SPARKING TOOLS.DO NOT BRTH
VAP.DO NOT GET IN EYES,ON SKIN/CLOTHING.READILY ABSORBED THROUGH
SKIN.HIGHLY TOXIC.LACHRYMATOR. (SEE OTHER PREC)
Other Precautions:HNDLG/STOR PREC: SEVERE IRRIT.KEEP TIGHTLY CLOSED.
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. REFRIGERATE.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:OTHER PROTECTIVE CLOTHING AS NEEDED. SAFETY
SHOWER AND EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LD50:(ORAL,MUS) 50MG/KG, LD50:(ORAL,GPG) 60MG/KG.

================== Physical/Chemical Properties ==================

HCC:F5
Boiling Pt:B.P. Text:237F,114C
Melt/Freeze Pt:M.P/F.P Text:-63F,-53C
Vapor Pres:11.6 @ 20C
Vapor Density:1.93
Spec Gravity:0.963
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

================= Stability and Reactivity Data =================

OXIDIZING AGENTS,STRONG ACIDS,STRONG BASES,ACID CHLORIDES,ACID
ANHYDRIDES,MAY UNDERGO AUTOPOLYMERIZATION.HEAT SENSITIVE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE &
TOXIC FUMES OF CO & CO*2.

==================== Disposal Considerations ====================

Waste Disposal Methods:BURN IN CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

*** END OF RECORD ***
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