===================== Product Identification =====================
MSDS NAME:DIETHYLENE GLYCOL, P1223
NIIN:00N019205
MSDS Number: BLHLH
=== Responsible Party ===
Company:VAN WATERS & ROGERS INC
Address:1600 NORTON BLDG
City:SEATTLE
State:WA
ZIP:98104-1564
Info Phone Num:408-435-8700
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:DO735
=== Contractor Identification ===
Company:VAN WATERS & ROGERS SUBSIDIARY OF UNIVAR
Address:6100 CARILLON POINT
City:KIRKLAND
State:WA
ZIP:98033
Country:US
Phone:425-889-3400
CAGE:DO735
Company:VAN WATERS AND ROGERS INC., UNIVAR CORP.
Address:1600 NORTON BLDG. 801 2ND AVENUE
Box:City:SEATTLE
State:WA
ZIP:98104-1564
Country:US
Phone:206-447-5911/800-424-9300(CHEMTREC)
CAGE:87664
============= Composition/Information on Ingredients =============
Name:INGRED 7: WASTE CNTNRS. FOR LRG SPILLS, CONT BY DIKING
W/SOIL/OTHER NON-COMBUST ABSORBENT MATL & THEN PUMP (SEE ING 9)
RTECS #:9999999ZZ
Name:INGRED 8: INTO DOT-APPRVD WASTE CNTNRS; OR ABSORB
W/NON-COMBUST SORBENT MATL, PLACE RESIDUE IN DOT-APPRVD (SEE ING
10)
RTECS #:9999999ZZ
Name:ING 9: WASTE CNTNRS. KEEP OUT OF SEWERS, STORM DRAINS, SURF
WATERS, & SOILS. COMPLY W/APPLIC GOVERNMENTAL (SEE ING 11)
RTECS #:9999999ZZ
Name:INGRED 10: REGULATIONS ON SPILL REPORTING, AND HANDLING AND
DISPOSAL OF WASTE.
RTECS #:9999999ZZ
Name:WASTE DISP METH: TO PROPER WASTE DISPOSAL, AS ABOVE.
RTECS #:9999999ZZ
Name:OTHER PREC: HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL.
RTECS #:9999999ZZ
Name:SPILL PROC: IN ANY EVENT, ALWAYS WEAR EYE PROT. FOR SMALL
SPILLS/DRIPS, MOP/WIPE UP & DISP OF IN DOT-APPRVD (SEE ING 8)
RTECS #:9999999ZZ
Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: >99%
Name:ETHYLENE GLYCOL (SARA III)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 0.2%
OSHA PEL:C 50 PPM
ACGIH TLV:C 50 PPM,VAPOR; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:TRIETHYLENE GLYCOL
CAS:112-27-6
RTECS #:YE4550000
Fraction by Wt: <1%
Name:SUPP DATA: OXALATE STONES.
RTECS #:9999999ZZ
Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 2 GLASSES OF H*2O &
STICKING FINGER DOWN THROAT. GET IMMED MED ATTN. (SEE ING 6)
RTECS #:9999999ZZ
Name:INGRED 5: DO NOT GIVE ANYTHING BY MOUTH TO AN UNCON OR
CONVULSING PERSON.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 14.8 G/KG.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: PRLNGD/RPTD EXPOS/BRTHG VERY
HIGH CONC MAY CAUSE HDCH, NAUS, & VOMIT. EYE: LIQ & MIST MAY IRRIT
EYES. SKIN: NO IRRIT IS LIKELY AFTER BRIEF CONT BUT MAY BE IRRIT
AFTER PRLNGD CONT. MAY BE ABSORB THRU SKIN BUT IN LOW TOXICITY BY
THIS ROUTE. INGEST: PROD MAY BE HARMFUL/FATAL IF SWALLOWED. (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SWALLOWING MAY PRDCE CNS DEPRESSION &
KIDNEY DAMAGE, WHICH MAY BE FATAL, & LIVER DAMAGE. SWALLOWING MAY
ALSO CAUSE PAIN & DISCOMFORT IN ABDOMINAAL/LUMBAR REGION, NAUS,
VOMIT, DIARRHEA, DIZZ, DROW, DECREASED URINE PRODUCTION, MALAISE,
& LOSS OF CON. CHRONIC: NO SPECIFIC INFORM AVAILABLE. CHRONIC (SUPP
DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, AND
RESPIRATORY DISORDERS OR IMPAIRED KIDNEY, LIVER, AND CNS FUNCTIONS.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. GIVE ARTF RESP IF NOT BRTHG. GET
IMMED MED ATTN. EYE: IMMED FLUSH EYES W/LOTS OF RUNNING WATER FOR
AT LEAST 15 MIN, LIFTING UPPER & LOWER EYELIDS OCCASIONALLY. GET
IMMED ME D ATTN. SKIN: IMMED WASH SKIN WITH LOTSOF SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND SHOES; WASH BEFORE REUSE. GET MED
ATTN IF IRRIT PERSISTS AFTER WASHING. INGEST: IF CON, IMMED (SEE
ING 5)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:255F,124C
Lower Limits:2.0%
Upper Limits:12.3%
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL OR CO2.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP
. USE H2O SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO
FIRE.
Unusual Fire/Explosion Hazard:HOT VAPORS OR MISTS MAY BE SUSCEPTIBLE TO
SPONTANEOUS COMBUSTION IF MIXED WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD PROT EQUIP INCLUDING
RUB BOOTS, RUB GLOVES, RUB APRON, & SCBA IN PRESS DEMAND
MODE/SUP-AIR RESP. IF SPILL/LEAK IS SMALL, A FULL FACEPIECE
AIR-PURIFYING CARTRIDGE RESP EQUIPPED F OR ORG VAPS MAY BE
SATISFACTORY. (SEE ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENT PLACE
AWAY FROM INCOMPATIBLE MATLS. KEEP CNTNR TIGHTLY CLSD WHEN NOT IN
USE. DO NOT USE PRESS TO EMPTY CNTNR.
Other Precautions:WASH THORO AFTER HANDLING. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT CUT, GRIND, WELD, OR DRILL ON/NEAR
CNTNR. CNTNRS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PROD
RESIDUE & VAPS. ALW AYS OBEY HAZ WARNINGS & (SEE ING 13)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPRVD RESP APPROP FOR THOSE
EMISSION LEVELS. APPROP RESP MAY BE FULL FACEPIECE/HALF MASK
AIR-PURIFYING CARTRIDGE RESP W/PARTICULATE FILTERS, SCBA IN PRESS
DEMAND MODE, OR SUP-AIR RESP .
Ventilation:GENERAL ROOM VENTILATION.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:AN EYEWASH AND SAFETY SHOWER SHOULD BE
NEARBY AND READY FOR USE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: DIETARY FEEDING STUDY W/ RATS SHOWED MILD KIDNEY INJ
AT 1% WHILE CONC OF 2% & 4% CAUSED MORE MARKED KIDNEY INJ. IN
ADDTN, AT 2% & 4% OF DIETHYLENE GLYCOL IN DIET, SOME RATS DEVELOPED
BENIGN PAPILLARY TUMORS IN URINARY BLADDER. THESE HAVE BEEN
ATTRIBUTED TO PRESENCE OF URINARY BLADDER CALCIUM (SEE ING 4
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:474F,246C
Melt/Freeze Pt:M.P/F.P Text:20.3F,-6.5C
Vapor Pres:NIL
Vapor Density:3.66
Spec Gravity:1.118
Evaporation Rate & Reference:<0.001 (BUTYL ACETATE=1)
Solubility in Water:100
Appearance and Odor:CLEAR, COLORLESS VISCOUS LIQUID; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZING MATERIALS AND ALKALIES.
Stability Condition to Avoid:EXCESSIVE HEAT. IGNITES IN AIR AT 444 F.
Hazardous Decomposition Products:MAY LIBERATE CARBON MONOXIDE OR CARBON
DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP OF CONTAM PROD & MATLS USED IN CLEANING UP
SPILLS/LEAKS IN MANNER APPRVD FOR MATL. CONSULT APPROP FED, ST &
LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISP PROC. NOTE:
EMPTY CNTNRS CAN HAVE RE SIDUES, GASES & MISTS & ARE SUBJECT (SEE
ING 12)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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