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MSDS  : DISCHARGED BATTERY ALKALINE, MK142-0
CAS  : 7439-97-6
7439-96-5
1310-58-3
1313-13-9
1333-86-4
7782-42-5
1314-13-2
NAME  : mercury
manganese
potassium hydroxide
manganese dioxide
carbon black
graphite
zinc oxide (mfr rec limits: 5 mg/m3, c)
===================== Product Identification =====================

MSDS NAME:DISCHARGED BATTERY ALKALINE, MK142-0
NIIN:01-252-0315
MSDS Number: BMDKY
=== Responsible Party ===
Company:NAVAL MINE WARFARE ENGINEERING ACTIVITY
Address:CODE 60 BUILDING 1959
City:YORKTOWN
State:VA
ZIP:23691-5076
Country:US
Info Phone Num:804-887-4930
Emergency Phone Num:804-887-4930
Preparer's Name:ANN ALLEN
CAGE:30265
=== Contractor Identification ===
Company:HOECHST CELANESE CHEM GROUP
Box:City:DALLAS
State:TX
ZIP:75356-9320
Country:US
Phone:214-689-4000
CAGE:10001
Company:NAVAL MINE WARFARE ENGINEERING ACTIVITY
Address:CODE 60 BUILDING 1959
Box:City:YORKTOWN
State:VA
ZIP:23691-5076
Country:US
Phone:804-887-4930
CAGE:30265

============= Composition/Information on Ingredients =============

Name:MERCURY
CAS:7439-97-6
RTECS #:OV4550000
Fraction by Wt: 0.01%
OSHA PEL:0.1 MG/M3, S, C
ACGIH TLV:0.05 MG/M3, S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Name:MANGANESE
CAS:7439-96-5
RTECS #:OO9275000
Other REC Limits:1 MG/M3 FUME;3 STEL
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293

Name:POTASSIUM HYDROXIDE
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 10%
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:MANGANESE DIOXIDE
CAS:1313-13-9
RTECS #:OP0350000
Fraction by Wt: 10%
Other REC Limits:1 MG/M3 FUME;3 STEL
OSHA PEL:5 MG/M3 DUST, C (MN)
ACGIH TLV:5 MG/M3 (MN DUST)

Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3

Name:GRAPHITE
CAS:7782-42-5
RTECS #:MD9659600
Fraction by Wt: 5%
Other REC Limits:15 MPPCF (MFR)
OSHA PEL:15 MPPCF RDUST
ACGIH TLV:2 MG/M3 RDUST; 9293

Name:ZINC OXIDE (MFR REC LIMITS: 5 MG/M3, C)
CAS:1314-13-2
RTECS #:ZH4810000
Other REC Limits:5 MG/M3 FUME;10 STEL
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293

===================== Hazards Identification =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MERCURY IS EXPERIMENTAL TERATOGEN & GI
& CNS POISON. MANGANESE IS AN EXPERIMENTAL TERATOGEN & MUTAGEN.
ZINC OXIDE IS A HUMAN PULMONARY DISEASE PRODUCER. IN FIRE
SITUATION, CELLS MAY RELEASE HAZ SUBSTA NCES. (ACUTE) INHAL: MAY
CAUSE IRRIT/METAL FUME FEVER IN FIRE SITUATION. INGEST: MATLS ARE
POISONOUS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SKIN/EYE: MATLS MAY CAUSE EYE & SKIN
IRRIT BY VAPOR/DIRECT CONT. (CHRONIC) NOT LIKELY UNDER NORMAL USE.
Medical Cond Aggravated by Exposure:RESPIRATORY INFECTIONS AND
DISEASES, SKIN DISORDERS.

======================= First Aid Measures =======================

First Aid:INHAL:REMOVE TO FRESH AIR, USE ARTF RESP IF NEEDED. CALL MD.
EYE:FLUSH FOR AT LEAST 15 MIN W/FRESH RUNNING WATER, OCCASNLY
LIFTING UPPER & LOWER LIDS. CALL MD. SKIN:THORO WASH AFFECTED AREA
UNTIL NO T RACE OF MATL REMAINS. INGEST:NOT LIKELYUNDER NORMAL USE.
IF INGEST OCCURS, CALL MD IMMED. DRINK LRG QTY OF WATER. EXPOS IN
FIRE: REMOVE VICTIM FROM FIRE HAZ TO FRESH AIR. CALL MD.

===================== Fire Fighting Measures =====================

Flash Point:NOT KNOWN
Extinguishing Media:IN BULK STORAGE USE CO*2, FOAM OR DRY POWDER. WATER
MAY CAUSE ELECTRICAL SHORTS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. AVOID CONTACT WITH HAZARDOUS DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:CELLS MAY RUPTURE WHEN EXPOSED TO
EXCESSIVE HEAT.

================== Accidental Release Measures ==================

Spill Release Procedures:BATTERIES ARE A DRY SOLID & CAN BE HANDLED
EASILY WITH SHOVELS OR SIMILAR EQUIPMENT. WHEN ACCUMULATING LRG
QTYS OF UNDISCHARGED BATTERIES FOR DISP PACK IN NON-CONDUCTIVE
INSULATING MATERIAL. AVOID HEA T & WATER. USE RUBBER GLOVES FOR
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

====================== Handling and Storage ======================

Handling and Storage Precautions:DO NOT STORE UNPACKAGED CELLS TOGETHER
SO CONTACTS CAN TOUCH. THIS SITUATION WILL RESULT IN CELL SHORTING
AND HEAT BUILD-UP.
Other Precautions:DO NOT CHARGE, OVERHEAT (GREATER THAN 160F), OR OPEN
CELLS. AVOID CONTACT WITH WATER, SPARKS, AND OPEN FLAMES.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE NEEDED UNDER NORMAL USE.
Ventilation:NONE NEEDED UNDER NORMAL USE.
Protective Gloves:NONE NEEDED UNDER NORMAL USE.
Eye Protection:NONE NEEDED UNDER NORMAL USE.
Other Protective Equipment:NONE REQUIRED UNDER NORMAL USE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPILL PROC: CLEANING UP SPILLS OR HANDLING INTERNAL PARTS OF CELLS. USE
ADEQUATE VENTILATION AND AVOID CONTACT OF CELL INTERNAL COMPONENTS
WITH SKIN OR EYES.

================== Physical/Chemical Properties ==================

Boiling Pt:B.P. Text:>212F,>100C
Vapor Density:>1
Spec Gravity:>1
Evaporation Rate & Reference:+1 (NK)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK SOLID GRANULES WITH NO APPRECIABLE ODOR,
ENCASED IN BATTERY ASSEMBLY.

================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:YES
KEEP AWAY FROM WATER.
Stability Condition to Avoid:EXCESSIVE HEAT AND FIRE (HEATING ABOVE
160F), CHARGING.
Hazardous Decomposition Products:IN A FIRE SITUATION, MERCURY VAPOR,
MANGANESE, AND ZINC OXIDE FUMES MAY BE EMITTED.

==================== Disposal Considerations ====================

Waste Disposal Methods:DISCARD IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS. DISPOSAL BY LANDFILL MAY BE PROHIBITED IN SOME
AREAS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

*** END OF RECORD ***
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