===================== Product Identification =====================
MSDS NAME:ELECTROLYTE (SULFURIC ACID SOLUTION)
NIIN:00-449-5938
MSDS Number: BMWHT
=== Responsible Party ===
Company:GNB INC INDUSTRIAL BATTERY DIV WOODLAKE CORP PARK
Address:829 PARKVIEW BOULEVARD
City:LOMBARD
State:IL
ZIP:60148-3249
Country:US
Info Phone Num:708-691-7886
Emergency Phone Num:800-424-9300 (CHEMTREC)
Preparer's Name:JAMES B. DOE
CAGE:88219
=== Contractor Identification ===
Company:EXIDE TECHNOLOGIES INC CO, GNB INDUSTRIAL POWER DIV
Address:829 PARKVIEW BOULEVARD
Box:City:LOMBARD
State:IL
ZIP:60148-3249
Country:US
Phone:800-872-0471/630-691-7841
CAGE:88219
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPORS CAUSES SEVERE
IRRITATION OR BURNS OF THE RESPIRATORY SYSTEM, PULMONARY EDEMA, OR
LUNG INFLAMMATION. EYE CONTACT CAUSES SEVERE DAMAGE AND POSSIBLE
BLINDNESS. SKIN CONTACT CAUSES BU RNS AND POSSIBLE DEEP ULCERATION.
INGESTION CAUSES SEVERE BURNS TO MOUTH, THROAT, AND STOMACH.
Explanation of Carcinogenicity:THIS CHEMICAL IS NOT LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:INHALATION: COUGHING, WHEEZING, SHORTNESS OF
BREATH, CHEST PAIN. EYES: PAIN, REDNESS, BLURRED VISION, TEARING.
SKIN: REDNESS, RASH, BURNS, PAIN. INGESTION: NAUSEA, VOMITING,
DIARRHEA, SEVERE STOMACH P AIN, BURNS OF THROAT AND ESOPHAGUS.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY
BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET PROMPT MEDICAL ATTENTION.
SKIN :REMOVE CONTAMINATED CLOTHING. WASH WITHPLENTY OF WATER FOR 15
MINUTES. GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING.
GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. DO NOT USE WATER
DIRECTLY ON ELECTROLYTE. USE WATER TO ABSORB VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. WEAR FULL
PROTECTIVE EQUIPMENT. STOP LEAK IF YOU CAN DO SO WITHOUT RISK.
CONTAIN SPILL. NEUTRALIZE WITH SODA ASH OR LIME. MAKE SLURRY AND
SHOVEL INTO DISPOSAL DRUM.
Neutralizing Agent:SODIUM BICARBONATE OR A SODA ASH/SLAKED LIME MIXTURE
(50-50)
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
CONTAINERS AWAY FROM HEAT. ISOLATE FROM INCOMPATIBLE MATERIALS. ADD
ACID TO WATER SLOWLY TO PREVENT SPLATTERING.
Other Precautions:ADDITION TO WATER RELEASES HEAT WHICH CAN RESULT IN
VIOLENT BOILING AND SPATTERING. ALWAYS ANDD SLOWLY AND IN SMALL
AMOUNTS. NEVER USE HOT WATER. NEVER ADD WATER TO ACIDS. ALWAYS ADD
ACIDS TO WATER. E MPTY CONTAINERS MAY BE HAZARDOUS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED.
Ventilation:USE SUFFICIENT MECHANICAL (GENERAL) VENTILATION TO MAINTAIN
EXPOSURE BELOW TLV REQUIREMENTS.
Protective Gloves:POLYVINYL CHLORIDE GLOVES
Eye Protection:CHEMICAL SPLASH GOGGLES AND FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE IMPERVIOUS WORK CLOTHING, BOOTS AND APRON AS
REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
MSDS IS FOR ELECTROLYTE FOR DRY CHARGE BATTERY. ACID IS ADDED
IMMEDIATLEY PRIOR TO INSTALLATION OF BATTERY. ELECTROLYTE AND CASE
ARE SHIPPED AS SEPARATE PACKAGES.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:=104.C, 219.2F
Melt/Freeze Pt:M.P/F.P Text:8F,-14C
Vapor Pres:20.8
Vapor Density:3.4
Spec Gravity:1.14
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID WITH A SHARP PUNGENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ALKALIS, ORGANIC MATERIALS, POWDERED
METALS, IRON, ZINC, STEEL
Stability Condition to Avoid:AVOID ADDING WATER TO ACID; ADD ACID TO
WATER.
Hazardous Decomposition Products:OXIDES OF SULFUR AND HYDROGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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