===================== Product Identification =====================
MSDS NAME:UNION CARBIDE CYCLOALIPHATIC EPOXY RESIN ERL-4206
NIIN:00F023610
MSDS Number: BNJBM
=== Responsible Party ===
Company:UNION CARBIDE CORP
Address:39 OLD RIDGEBURY RD
City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Info Phone Num:203-794-2000
Emergency Phone Num:203-794-2000
CAGE:36346
=== Contractor Identification ===
Company:UNION CARBIDE CORP LINDE DIV
Address:39 OLD RIDGEBURY RD
Box:City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Phone:800-822-4357; 304-744-3487
CAGE:36346
============= Composition/Information on Ingredients =============
Name:VINYLCYCLOHEXENE DIOXIDE (A2 CARCINOGEN BY ACGIH)
CAS:106-87-6
RTECS #:RN8640000
ACGIH TLV:10 PPM (SKIN) (A2)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGESTION: MODERATELY TOXIC, NAUSEA,
ABDOMINAL DISCOMFORT, VOMITING, DIARRHEA. SKIN: ABSORPTION,
IRRITATION, DISCOMFORT, REDNESS & SWELLING. INHALATION: IRRITATION,
NASAL DISCOMFORT & DISCHARGE. EYES: PAIN, REDDENING & SWELLING OF
CONJUNCTIVA, W/CHEMICAL BURNS OF THE CORNEA.
Explanation of Carcinogenicity:VINYL CYCLOHEXENE DIOXIDE IS A SUSPECTED
(A2) ANIMAL CARCINOGEN BY ACGIH.
Effects of Overexposure:INGESTION: NAUSEA, ABDOMINAL DISCOMFORT,
VOMITING, DIARRHEA. SKIN: IRRITATION W/DISCOMFORT, REDNESS,
SWELLING, SENSITIZATION, ALLERGIC REACTION & ABSORPTION.
INHALATION: IRRITATION, NASAL DISCOMFORT & DISCHARGE. EYES: PAIN,
REDDENING & SWELLING OF THE CONJUNCTIVA.
Medical Cond Aggravated by Exposure:DERMATITIS.
======================= First Aid Measures =======================
First Aid:INGESTION: IF CONSCIOUS AND HAS A GAG REFLEX, GIVETWO GLASSES
OF WATER. INDUCE VOMITING. SKIN: WASH SKIN/W SOAP & WATER.
INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/WATER FOR AT LEAST
15 MINUTES. O BTAIN MEDICAL ATTENTION IN ALL CASES. PHYSICAN NOTE:
NO SPECIFIC ANTIDOTE. TREATMENT DIRECTED AT THE CONTROL OF SYMPTOMS
& THE CLINICAL CONDITION OF THE PATIENT.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:225 F
Extinguishing Media:LARGE FIRE: ALCOHOL TYPE/ALL PURPOSE TYPE FOAMS.
SMALL FIRE: CO2 OR DRY CHEMICALS.
Fire Fighting Procedures:USE REMOTE SPRAY MONITORS OR FIGHT FIRE FROM
BEHIND SHIELDS. USE SELF CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:WHEN THIS MATERIAL IS EXPOSED TO EXTREME
HEAT AS IN A FIRE, IT MAY POLYMERIZE & RUPTURE A CLOSED CONTAINER.
EXPOSURE TO HIGH TEMPERATURES MAY CAUSE INSTABILITY.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT; AVOID
CONTACT W/LIQUID AND VAPORS. COLLECT FOR DISPOSAL. AVOID DISCHARGE
TO SEWERS OR WATERWAYS.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. USE W/ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
Other Precautions:HOT ORGANIC CHEMICAL VAPORS OR MISTS ARE SUSCEPTIBLE
TO SUDDEN SPONTANEOUS COMBUSTION WHEN MIXED W/AIR. IGNITION MAY
OCCUR AT TEMPS BELOW AUTOIGNITION OR IGNITION TEMPS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED-AIR RESPIRATOR (SELF-CONTAINED OR
AIR-LINE) IN HIGH VAPOR CONCENTRATIONS.
Ventilation:MECHANICAL OR LOCAL
Protective Gloves:NITRILE OR PVC-COATED
Eye Protection:FACESHIELD/MONOGOGGLES
Other Protective Equipment:CHEMICAL APRON, EYE BATH AND SAFETY SHOWER.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DISCARD SHOES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:440.6 F
Melt/Freeze Pt:M.P/F.P Text:-67F
Vapor Pres:<0.1
Vapor Density:4.8
Spec Gravity:1.10
Evaporation Rate & Reference:(BU AC = 1) 0
Solubility in Water:18.3%
Appearance and Odor:LOW VISCOSITY LIQUID; CHARACTERISTIC ODOR
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, AMINES, AMMONIA, ACIDS, HALOGENS, ANHYDRIDES.
Stability Condition to Avoid:EXTREME HEAT
Hazardous Decomposition Products:CO, CO2
Conditions to Avoid Polymerization:EXTREME HEAT, AMINES, ALKALIES,
MINERAL ACIDS, METAL SALTS
==================== Disposal Considerations ====================
Waste Disposal Methods:DILUTE WITH AN INERT SOLVENT AND INCINERATE IN A
FURNACE WHERE PERMITTED UNDER APPROPRIATE FEDERAL, STATE AND LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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