===================== Product Identification =====================
MSDS NAME:13423-6 MORPHOLINE, >99%, GOLD LABEL
NIIN:00F025117
MSDS Number: BNZDW
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO SUB OF SIGMA-ALDRICH
Address:1001 W ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Country:US
Info Phone Num:(414) 273-3850
Emergency Phone Num:(414) 273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:MORPHOLINE
INTENDED CHANGE (IC)
CAS:110-91-8
RTECS #:QD6475000
Fraction by Wt: >99%
Other REC Limits:20 PPM
OSHA PEL:70 MG/CUM (SKIN)
ACGIH TLV:71 MG/CUM (SKIN) IC
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 1050 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGESTION: HARMFUL/STOMACH
PAIN/VOMITING/DIARRHEA/DAMAGE TO KIDNEYS & LIVER. INHALATION:
HARMFUL/IRRITATION TO MUCOUS MEMBRANES & UPPER RESPIRATORY
TRACT/FATAL AS A RESULT OF SPASM/INFLAMMATION & EDEM A OF LARYNX &
BRONCHI/CHEMICAL PNEUMONITIS/PULMONARY EDEMA. SKIN: HARMFUL
ABSORPTION/IRRITATION. EYE: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: HARMFUL/STOMACH
PAIN/VOMITING/DIARRHEA/DAMAGE TO KIDNEYS & LIVER. INHALATION:
HARMFUL/IRRITATION TO MUCOUS MEMBRANES & UPPER RESPIRATORY
TRACT/FATAL AS A RESULT OF SPASM/INFLAMMATION & EDEM A OF LARYNX &
BRONCHI/CHEMICAL PNEUMONITIS/PULMONARY EDEMA. SKIN: HARMFUL
ABSORPTION/IRRITATION. EYE: IRRITATION.
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & COPIOUS AMOUNTS OF WATER. EYES: FLUSH
W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINS. INHALATION: REMOVE
TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION,
PREFERABLY MO UTH-TO-MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:96F
Extinguishing Media:CO2, DRY CHEMICAL POWDER, ALCOHOL, OR POLYMER FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:FLAMMABLE. VAPOR TRAVELS CONSIDERABLE
DISTANCE TO IGNITION SOURCE/FLASH BACK. UNDER FIRE CONDITIONS,
MATERIAL DECOMPOSES TO FORM EXPLOSIVE MIXTURES IN AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR PROTECTIVE CLOTHING. SHUT
OFF ALL IGNITION SOURCES. COVER W/DRY-LIME/SAND/SODA ASH. PLACE IN
COVERED CONTAINERS USING NON-SPARKING TOOLS & TRANSPORT OUTSIDE OF
BUILDING.
Neutralizing Agent:DRY-LIME, SAND, SODA ASH, SODIUM CARBONATE, & SLAKED
LIME (CALCIUM HYDROXIDE)
====================== Handling and Storage ======================
Handling and Storage Precautions:DON'T BREATHE VAPOR. AVOID CONTACT
W/FUMES. DON'T GET IN EYES/SKIN/CLOTHING. KEEP TIGHTLY CLOSED.
Other Precautions:KEEP AWAY FROM HEAT, SPARKS, & OPEN FLAMES. THIS
MATERIAL IS HYGROSCOPIC. STORE IN A COOL DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE APPROPRIATE OSHA/MSHA-APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST: REQUIRED. USE NON-SPARKING TOOLS.
Protective Gloves:CHEMICAL-RESISTANT, HEAVY RUBBER
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:OTHER PROTECTIVE CLOTHING, FACESHIELD
(8-INCH MINIMUM), SAFETY SHOWER, EYE BATH, & RUBBER BOOTS
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE/LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
MELTING RANGE: 19.4-23F.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:264.20F
Melt/Freeze Pt:M.P/F.P Text:SEE SUPP
Appearance and Odor:UNPLEASANT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
ACIDS, ACID ANHYDRIDES, ACID CHLORIDES, OXIDIZING AGENTS
Stability Condition to Avoid:SOURCES OF IGNITION SUCH AS HEAT, SPARKS,
& OPEN FLAME
Hazardous Decomposition Products:CO, CO2, & NITROGEN OXIDES
==================== Disposal Considerations ====================
Waste Disposal Methods:IGNITE MATERIAL IN PRESENCE OF SODIUM
CARBONATE/SLAKED LIME (CALCIUM HYDROXIDE). MIX W/VERMICULITE/THEN
W/DRY CAUSTICS/WRAPPED IN PAPER/BURNED IN CHEMICAL INCINERATOR
EQUIPPED W/AFTERBURNER/SCRUBBER. OBSERVE ALL REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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