===================== Product Identification =====================
MSDS NAME:PYROSET TPO FLAME RETARDANT
NIIN:00N012364
MSDS Number: BPCGZ
=== Responsible Party ===
Company:AMERICAN CYANAMID CO
Address:1 CYANAMID PLAZA
City:WAYNE
State:NJ
ZIP:07470
Country:US
Info Phone Num:800-438-5615
Emergency Phone Num:201-835-3100
Preparer's Name:MARVIN A. FRIEDMAN
CAGE:06404
=== Contractor Identification ===
Company:AMERICAN CYANAMID CO LEDERLE LABORATORIES DIV
Address:1 CAMPUS DR
Box:City:PARSIPPANY
State:NJ
ZIP:07054-4404
Country:US
Phone:973-683-2000
CAGE:06404
============= Composition/Information on Ingredients =============
Name:UREA P/W TETRAKISHYDROXYMETHYL PHOSPHONIUM SULFATE
CAS:63502-25-0
Fraction by Wt: 70-74%
Name:VENT: SHOULD BE PROVIDED TO CONTROL EXPOSURE.
RTECS #:9999999ZZ
Name:OTHER PROT EQUIP: SLEEVE WORKSHIRT, OR DISPOSABLE
COVERALLS.
RTECS #:9999999ZZ
Name:HYGIENE PRACT: COMPLETION OF WORKSHIFT ESPECIALLY IF
SIGNIFICANT CONTACT HAS OCCURED. WORK CLTHG SHOULD THEN BE (ING 6)
RTECS #:9999999ZZ
Name:ING 5:LAUNDERED PRIOR TO REUSE. STREET CLTHG SHOULD BE
STORED SEPARATELY FROM WORK CLTHG & PROT EQUIP. WORK CLTHG(ING 7)
RTECS #:9999999ZZ
Name:ING 6: & SHOES SHOULD NOT BE TAKEN HOME.
RTECS #:9999999ZZ
Name:FORMALDEHYDE. LD50:(ORAL,RAT) 500-800 MG/KG
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: 0-0.8%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)0.442 ML/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:DIRECT CONT W/MATL MAY CUASE SEV
EYE/SKIN IRRIT. MATL PRDCD SKIN/EYE BURNS IN IRRIT TESTS W/RABBITS.
HUMAN PATCH TEST RSLTS FOR COTTON FABRIC TREATED W/MATL DO NOT
REVEAL EVIDENCE OF SKIN IRRIT/SENSIT . EXPOS TO FORMALDEHYDE VAP @
CONC IN EXCESS OF 1PPM MAY CAUSE IRRIT OF EYES/RESP TRACT.
FORMALDEHYDE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE: ANTICIPATED TO BE A
CARCINOGEN(NTP), GROUP 2A(IARC), OSHA-REGULATED.
Effects of Overexposure:HTLH HAZ:SOLN CAN CAUSE SEV EYE/MOD SKIN IRRIT.
RPTD SKIN EXPOS TO SOLN OF 2%/MORE OF FORMALDEHYDE HAS CAUSED
ALLERGIC SKIN RXN. FORMALDEHYDE WAS FOUND TO BE WEAKLY ACTIVE IN
NUMBER OF IN VITRO GENOTO XICITY TESTS, BUT INACTIVE IN VIVO.
FORMALDEHYDE DO NOT CAUSE BIRTH DEFECTS IN RATS INHALING CONC UP TO
10 (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE CONTAMD CLTHG W/OUT DELAY. CLEANSE SKIN THORO
W/SOAP/H*2O. DO NOT OMIT CLEANING HAIR/UNDER FINGERNAILS IF
CONTAMD. DO NOT REUSE CLTHG W/OUT LAUNDERED. DO NOT REUSE CONTAMD
LEATHERWARE. EY E: IMMED IRRIGATE W/PLENTY OF H*2O FOR @ LST 15
MIN. OBTAIN MED ATTN W/OUT DELAY. INHAL:REMOVE TO FRESH AIR.
SUPPORT BRTHG. (GIVE O*2/ARTF RESP) . INGEST: CALL MD .
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>205F,>96C
Extinguishing Media:USE WATER SPRAY, CO*2 OR DRY CHEMICAL TO EXTINGUISH
FIRES.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE WATER TO KEEP CONTAINERS COOL.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:EXPOS LEVEL NOT KNOWN, NIOSH/MSHA APPRVD, POS
PRESS, SELF-CONTAINED RESP. EXPOS LEVEL KNOWN, NIOSH/MSHA APPRVD
RESP SUITABLE FOR LEVEL OF EXPOS. WEAR RAIN SUIT. COVER SPILLS
W/SOME INERT ABSORB MATL; SWEEP UP & PLACE IN WASTE DISP CONTR.
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID STRONG @ ELEVATED TEMP. SOLN IS
CORR, AVOID STOR IN METAL CONTR. PROD SHOULD NOT BE MIXED W/BASES
SINCE EVOLUTION OF FLAMM HYDROGEN (SUPP DATA)
Other Precautions:PVNT EYE & SKIN CONT. WEAR SPECIAL PROTECTIVE
EQUIPMENT FOR OPERATIONS WHERE EYE/SKIN CONTACT CAN OCCUR. FOOD,
BEVERAGES, & TOBACCO PRODUCTS SHOULD NOT BE CARRIED, STORED, OR
CONSUMED WHERE THIS MATER IAL IS IN USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE EXPOS BELOW PEL, NO RESP PROT IS REQD.
WHERE EXPOS EXCEED PEL, USE NIOSH/MSHA APPRVD RESP OR FULL PROT
SUIT W/AIR SUPPLY APPROP FOR MATL & LEVEL OF EXPOS.
Ventilation:UTILIZE CLSD SYS PROCESS WHERE FEASIBLE. WHERE MATL IS NOT
USED IN CLSD SYS, GOOD ENCLOSURE & LOC EXHAUST VENT (ING 3)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM WORK GOG & FULL LNGTH FSHLD.
Other Protective Equipment:PROVIDE EYEWASH FOUNTAIN & SFTY SHOWER IN
CLOSE PROXIMITY TO POINTS OF POTNTL EXPOS. APRON, WORKPANTS, LONG
(ING 4)
Work Hygienic Practices:BEFORE EATING, DRINKING, OR SMOKING, WASH FACE
& HANDS W/SOAP/H*2O. IT IS RECOM THAT SHOWER BE TAKEN AFTER (ING 5)
Supplemental Safety and Health
PH:4.0-5.0. %VOLAT: 25%-30% (H*2O). EFTS OF OVEREXP: PPM. LIFETIME
INHAL OF FORMALDEHYDE VAP @ CONC ABOVE 5PPM FOR 6HRS PER DAY,
CAUSED NASAL TUMORS IN LAB ANIMALS. MANY EPIDEMIOLOGY STUDIES HAVE
FAIL ED TO LINK CANCER IN HUMANS W/OCCUP EXPOS TO FORMALDEHYDE.
SPILL PROC:FLUSH AREA W/H*2O. HNDLG/STOR PREC:GAS COULD RSLT.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:222F,104.4C
Spec Gravity:1.37-1.39@25C
pH:SUPDAT
Solubility in Water:COMPLETELY SOLUBLE
Appearance and Odor:CLEAR, YELLOW, SLIGHTLY VISCOUS LIQUID; FAINT ODOR
OF FORMALDEHYDE
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND ALKALIES.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:THERMAL DECOMP OR COMBUSTION MAY PRDCE
CO, CO*2, SO*X AND/OR PHOSPHORUS, HYDROGEN GAS, FORMALDEHYDE,
PHOSPHINE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE MADE IN ACCORDANCE WITH
APPLICABLE FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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