===================== Product Identification =====================
MSDS NAME:25810-5, SULFURIC ACID, 95-98%, A.C.S. REAG
NIIN:00N033846
MSDS Number: BPQND
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Country:US
Info Phone Num:414-273-3850
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 95-98%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3;3 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WASTE DISP METH: AND FUMES WHICH CAN BE CONTROLLED BY RATE
OF ADDITION. DISPOSE OF I/A/W FED, ST AND LOCAL REGS .
RTECS #:9999999ZZ
Name:OTHER PREC: KEEP AWAY FROM COMBUSTIBLE MATERIAL. WEAR
SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROT. (ING 4)
RTECS #:9999999ZZ
Name:ING 3: DO NOT BREATHE VAPOR. IF YOU FEEL UNWELL, SEEK
MEDICAL ADVICE (SHOW LABEL WHERE POSSIBLE).
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 2140 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF SWALLOWED. HARMFUL IF
INHALED OR ABSORBED THROUGH SKIN. CAUSES BURNS. MATERIAL IS
EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT, EYES AND SKIN. INHALA TION MAY BE FATAL AS
RESULT OF SPASM, INFLAMMATION AND EDEMA OF LARYNX AND BRONCHI,
CHEMICAL PNEUM (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: AND PULMONARY EDEMA. SYMPTOMS OF
EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MINUTES.
ASSURE ADEQ FLUSHING OF EYES BY SEPARATING EYELIDS W/FINGERS. SKIN:
FLUSH WITH COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN WHILE REMOVING
CON TAM CLTHG AND SHOES. INHAL: REMOVE TO FRESH AIR. IF NOT
BREATHING GIVE ARTIFICIAL RESPIRATION. IF BRTHG IS DFCLT, GIVE O*2.
INGEST: WASH OUT MOUTH W/H*2O PROVIDED PERSON IS CONSCIOUS. CALL
PHYS IMMED.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS. DO NOT USE WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL
MAY CAUSE FIRE.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVAC AREA. WEAR NIOSH/MSHA APPRVD SCBA, RUB
BOOTS & HEAVY RUB GLOVES. COVER W/DRY-LIME, SAND, OR SODA ASH.
PLACE IN COVERED CNTNRS USING NON-SPARKING TOOLS & TRANSPORT
OUTDOORS. VENT AREA AND WASH SPI LL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BRTHG VAP.AVOID CONT W/EYES,SKIN
& CLTHG.AVOID PRLNGD/RPTD EXPOS. WASH THORO AFTER HNDLG. POIS.CORR.
KEEP TIGHTLY CLSD. REACTS VIOLENTLY W/H*2O.
Other Precautions:DO NOT STORE NEAR, NOR ALLOW CONT W/CLTHG & OTHER
COMBUST MATL.STORE IN COOL DRY PLACE. OXIDIZING. HIGHLY TOX. CONT
W/COMBUST MATL MAY CAUSE FIRE.CAUSES BURNS.VERY TOX BY INHAL, CONT
W/SKIN & IF SWALL OWED.REACTS VIOLENTLY W/H*2O. (ING 3)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEM WORK GOG&FULL LGTH FACESHLD .
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISCARD CONTAMINATED SHOES.
Supplemental Safety and Health
MATLS TO AVOID: FULMINATES, NITRATES, PICRATES, CYANIDES, ALKALI
HALIDES, ZINC IODIDE, PERMANGANATES, HYDROGEN PEROXIDE, AZIDES,
PERCHLORATES, NITROMETHANE, PHOSPHOROUS, NITRITES, VIOLENT RXN
WITH:CYC LOPENTADIENE, CYCLOPENTANONE OXIME, NITROARYL AMINES,
HEXALITHIUM DISILICIDE, PHOSPHOROUS (III) OXIDE.
================== Physical/Chemical Properties ==================
Vapor Pres:1 @ 145.8C
Vapor Density:<.3 @ 25C
Spec Gravity:1.840
Appearance and Odor:VISCOUS COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES,HALIDES. AVOID CONT W/METALS.DO NOT ALLOW H*2O TO ENTER CNTNR
BECAUSE OF VIOLENT RXN.CARBIDES, CHLORATES, (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOR SML QTYS:CAUTIOUSLY ADD TO LRG STIRRED
EXCESS OF H*2O. ADJUST PH TO NEUT, SEPARATE ANY INSOLUBLE
SOLIDS/LIQ & PACKAGE THEN FOR HAZ-WASTE DISP. FLUSH AQEOUS SOLN
DOWN DRAIN W/PLENTY OF H*2O. HYDROL YSIS & NEUTRALIZATION RXNS MAY
GEN HEAT(ING 2)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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