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MSDS  : FUMING SUFURIC ACID, A-304
CAS  : 8014-95-7
NAME  : sulfuric acid, fuming; (fuming sulfuric acid) pel/tlv
supdat:blood. asphy can occur from swelling of throat.
ing 2:mist causes chronic trachiobronchitis, erosion &
ing 3:studies suggest an increased risk of laryngeal cancer
ing 4:rptd/prlngd expos to liq/mist may cause irrit/derm.
first aid proc:remains (at least 15-20 min). in case of
ing 6:securely, but not too tight. get md attn immed.
ing 7:& lower lids, until no evid of chem remains (at least
ing 8:until ph has returned to normal (30-60 min). cover
ing 9:use gastric lavage/emesis. dilute immed by drinking
ing 10:repeatedly. ingested acid must be diluted approx 100
ing 11:airway and treat shock. get md atten immed. if vomit
ing 12:antidote:no special antidote. treat symptomatically
spill proc:of an expert. dike spill for later disp. do not
ing 14:people away. isolate haz area & deny entry. vent
===================== Product Identification =====================

MSDS NAME:FUMING SUFURIC ACID, A-304
NIIN:00-975-1537
MSDS Number: BPZJJ
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7523;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464

============= Composition/Information on Ingredients =============

Name:SULFURIC ACID, FUMING; (FUMING SULFURIC ACID) PEL/TLV
LIMITS GIVEN FOR SULFURIC ACID.
CAS:8014-95-7
RTECS #:WS5605000
Fraction by Wt: 100%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3;3 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:SUPDAT:BLOOD. ASPHY CAN OCCUR FROM SWELLING OF THROAT.
PERFORATION OF ESOPHAGUS/STOMACH MAY OCCUR. CHRONIC:INHAL:(ING 3)
RTECS #:9999999ZZ

Name:ING 2:MIST CAUSES CHRONIC TRACHIOBRONCHITIS, EROSION &
DISCOLORATION OF TEETH, BRONCHIAL PNEUMONIA/GI DISTURB. (ING 4)
RTECS #:9999999ZZ

Name:ING 3:STUDIES SUGGEST AN INCREASED RISK OF LARYNGEAL CANCER
FROM EXPOS TO HIGH CONCEN OF SULFURIC ACID. SKIN: (ING 5)
RTECS #:9999999ZZ

Name:ING 4:RPTD/PRLNGD EXPOS TO LIQ/MIST MAY CAUSE IRRIT/DERM.
EYES:RPTD/PRLNGD EXPOS MAY CAUSE CONJ.
RTECS #:9999999ZZ

Name:FIRST AID PROC:REMAINS (AT LEAST 15-20 MIN). IN CASE OF
CHEM BURNS, COVER AREA W/STERILE, DRY DRESSING, BANDAGE (ING 7)
RTECS #:9999999ZZ

Name:ING 6:SECURELY, BUT NOT TOO TIGHT. GET MD ATTN IMMED.
EYES:WASH IMMED W/LRG AMTS OF WATER, OCCAS LIFTING UPPER (ING 8)
RTECS #:9999999ZZ

Name:ING 7:& LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS (AT LEAST
15-20 MIN). CONTINUE IRRIGATING W/NORM SALINE (ING 9)
RTECS #:9999999ZZ

Name:ING 8:UNTIL PH HAS RETURNED TO NORMAL (30-60 MIN). COVER
W/STERILE BANDAGES. GET MD ATTN IMMED. INGEST:DO NOT (ING 10)
RTECS #:9999999ZZ

Name:ING 9:USE GASTRIC LAVAGE/EMESIS. DILUTE IMMED BY DRINKING
LOTS OF WATER/MILK. IF VOMIT PERSISTS, ADMIN FLUIDS (ING 11)
RTECS #:9999999ZZ

Name:ING 10:REPEATEDLY. INGESTED ACID MUST BE DILUTED APPROX 100
FOLD TO RENDER IT HARMLESS TO TISSUES. MAINTAIN (ING 12)
RTECS #:9999999ZZ

Name:ING 11:AIRWAY AND TREAT SHOCK. GET MD ATTEN IMMED. IF VOMIT
OCCURS, KEEP HEAD BELOW HIPS TO HELP PREV ASPIR. (ING 13)
RTECS #:9999999ZZ

Name:ING 12:ANTIDOTE:NO SPECIAL ANTIDOTE. TREAT SYMPTOMATICALLY
AND SUPPORTIVELY.
RTECS #:9999999ZZ

Name:SPILL PROC:OF AN EXPERT. DIKE SPILL FOR LATER DISP. DO NOT
APPLY WATER UNLESS DIRECTED TO DO SO. KEEP UNNEC (ING 15)
RTECS #:9999999ZZ

Name:ING 14:PEOPLE AWAY. ISOLATE HAZ AREA & DENY ENTRY. VENT
CLSD SPACES BEFORE ENTERING. SEE ORIG MSDS FOR FURTHER INFO.
RTECS #:9999999ZZ

===================== Hazards Identification =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:CORR/TOX. MAY CAUSE
NOSE/THROAT IRRIT, HDCH, COUGH, AN INCREASE IN RESP RATE/IMPAIRMENT
OF VENTILATORY CAPACITY. DELAYED SYMPT MAY INCLUDE PULM EDEMA,
TIGHTMESS IN CHEST, CYANOSIS, HYPOTEN SION, BRONCHITIS/EMPHYSEMA.
SKIN:CONTACT MAY CAUSE SEV IRRIT, PAIN, BURNS & VESICULATION. (EFTS
OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EYE:DIRECT CONTACT W/CONCENTRATED ACID
SOLUTION MAY CAUSE SEV DMG, OFTEN LEADING TO BLINDNESS. DILUTE
SOLUTION PRODUCE MORE TRANSIENT EFTS FROM WHICH RECOVERY MAY BE
COMPLETE. EXPOS TO MIST M AY CAUSE IRRIT & LACRIMATION. INGEST:MAY
PRODUCE SERIOUS BURNS OF MOUTH & ESOPHAGUS. MAY BE PAIN IN ABDOMEN
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

======================= First Aid Measures =======================

First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE
ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMIN O*2 IF AVAIL. KEEP
AFFECTED INDIV WARM & AT REST. TREAT SYMPTOMATICALLY &
SUPPORTIVELY. ADM IN OF O*2 SHOULD BE PERFORMED BY QUALIFIED INDIV.
GET MD ATTN IMMED. SKIN:REMOVE CONTAM CLTHG/SHOES IMMED. WASH
AFFECTED AREA W/SOAP & MILD DETERGENT & LRG AMT OF WATER UNTIL NO
EVID OF CHEM (ING 6)

===================== Fire Fighting Measures =====================

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE OR HALON. (1987
EMERGENCY RESPONCE GUIDEBOOK, DOT P 5800.4).
Fire Fighting Procedures:LRG FIRES:FLOOD AREA W/WATER FROM A DISTANCE.
DO NOT GET SOLID STREAM OF WATER ON SPILLED MATLS. USE FLOOD FOG.
MOVE CONTR FROM FIRE AREA IF POSS. COOL (SUPDAT)
Unusual Fire/Explosion Hazard:VIOLENT EXOTHERMIC REACTION W/WATER &
ORGANIC MATERIALS. MAY IGNITE FINELY DIVIDED COMBUSTIBLE MATERIALS
ON CONTACT. NEGLIG HAZ WHEN EXPOS TO HEAT/FLAME.

================== Accidental Release Measures ==================

Spill Release Procedures:OCCUP SPILL:KEEP COMBUST AWAY FROM SPILLED
MATLS. DO NOT TOUCH SPILLED MATLS. DO NOT GET WATER INSIDE CONTR.
STOP LEAK IF CAN BE DONE W/NO RISK. USE WATER TO REDUCE VAP. DO NOT
PUT WATER ON LEAK/SPILL AREA, CLEAN UP ONLY UNDER SUPERVISION (ING
14)
Neutralizing Agent:SLAKED LIME, SODIUM BICARBONITE, CRUSHED LIMESTONE.

====================== Handling and Storage ======================

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR CONCENTRATIONS FOUND IN WORKPLACE. FOR FURTHER INFORMATION SEE
ORIGINAL MSDS OR REFER TO CFR 1910.134.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM TO MEET PUBLISHED
EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOGG & FULL LNGTH FCSHLD
Other Protective Equipment:IMPERVIOUS CLOTHING AND EQUIPMENT. EYE WASH
FOUNTAIN & QUICK DRENCH SHOWER.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
FIRE FIGHT PROC:CONTR EXPOSED TO FLAMES W/WATER FROM SIDE UNTIL WELL
AFTER FIRE IS OUT. KEEP AWAY FROM STORAGE TANK ENDS. KEEP
UPWIND.USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . CNDTN TO AVOI
D:SPACES. RUNOFF TO SEWER MAY CREATE FIRE/EXPLOS HAZ. EFTS OF
OVEREXPOS:FOLLOWED BY VOMIT/DIARR OF DARK PRECIP (ING 2)

================== Physical/Chemical Properties ==================

Boiling Pt:B.P. Text:131F,55C
Melt/Freeze Pt:M.P/F.P Text:34.0F,1.1C
Vapor Density:2.7
Spec Gravity:1.98
Solubility in Water:REACTS VIOLENTLY
Appearance and Odor:HEAVY, FUMING, YELLOW LIQUID WITH SHARP,
PENETRATING ODOR.

================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:NO
MAY REACT VIOLENTLY W/WATER PROD FLAMM HYDROGEN GAS. OLEUM IS CORR TO
METAL. FOR OTHER MATL TO AVOID SEE ORIGINAL MSDS.
Stability Condition to Avoid:MAY IGNITE OTHER COMBUST MATLS. VIOLENT
REACTION W/H*2O. FLAMM, POISONOUS GASES MAY ACCUM IN CONFINED
(SUPDAT)
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC SO*X.

==================== Disposal Considerations ====================

Waste Disposal Methods:NEUTRALIZE TO PH-7. DISPOSE OF IN ACCORDANCE
WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

*** END OF RECORD ***
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BLUE VITRIOL 7758-98-7
P/N 1743300
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21908-53-2
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7440-66-6
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POTASSIUM TETRABORATE 1332-77-0
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FUMING SUFURIC ACID, A-304 8014-95-7
LITHIUM HYDROXIDE 1310-65-2
7732-18-5
MIL-C-22750 595-27038 PART A 108-10-1
1330-20-7
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7439-95-4
7631-99-4
110-15-6
7429-90-5
7790-98-9
7782-42-5
7440-42-8
7757-79-1
13424-46-9
479-45-8
121-82-4
STARTING FLUID CYLINDERS - AEROSOL 124-38-9
60-29-7
142-82-5
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CARTRIDGE,POWER DEVICE,30903824 7440-21-3
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SIMULANT TUBE,ORANGE 7784-46-5
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TABLET,SODIUM BICARBONATE 144-55-8
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ZINC MIX PACKET 7440-66-6
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123-31-9
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584-08-7
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