===================== Product Identification =====================
MSDS NAME:RUBINATE M (POLYMERIC MDI)
NIIN:00N011944
MSDS Number: BQNXP
=== Responsible Party ===
Company:ICI POLYURETHANES GROUP,RUBICON CHEM IS A DIV
Address:286 MANTUA GROVE ROAD
City:WEST DEPTFORD
State:NJ
ZIP:08066
Country:US
Info Phone Num:302-866-3000
Emergency Phone Num:800-327-8633;302-886-3000,24 HOURS
CAGE:ICIPO
=== Contractor Identification ===
Company:ICI POLYURETHANES GROUP,RUBICON CHEM IS A DIV
Address:286 MANTUA GROVE ROAD
Box:City:WEST DEPTFORD
State:NJ
ZIP:08066
Country:US
Phone:302-866-3000
CAGE:ICIPO
============= Composition/Information on Ingredients =============
Name:4,4'-DIPHENYLMETHANE-DIISOCYANATE (METHYLENE BISPHENYL
ISOCYANATE,MDI)
CAS:101-68-8
RTECS #:NQ9350000
Fraction by Wt: 50%
Other REC Limits:N/K
OSHA PEL:0.02 PPM C
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SIMILAR STRUCTURE OLIGOMERS (HIGHER OLIGOMERS OF MDI)
CAS:9016-87-9
RTECS #:TR0350000
Fraction by Wt: 50%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SPILL PROC:FOLLOW PRECS ON SUPPLIER'S MSDS.MAJOR SPILL,CALL
CHEMTREC 800-424-9300.WASTE DISP METH:REMOVAL TO (SEE ING 4)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 3:AREA FOR DECONTAMINATION. DRUMS MUST BE DECONTAM IN
VENTILATED AREA BY PERSONS PROTECTED FROM VAPORS. POUR (ING 5)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 4:5-15 LITERS DECONTAM SOLUTION IN DRUM, RINSING WALLS
WELL. SOAK UNSEALED 48 HR. DISPOSE OF DECONTAMINATED (ING 6)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 5:SOLN IAW REGS. MAY BE HAZARDOUS WASTE. TRIPLE RINSE
CONTAINER. PUNCTURE/DESTROY CNTNR BEFORE DISPOSAL. MDI:(ING 7)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 6: SARA TITLE III SECTION 313 LISTED. RESPIRATORY
PROT:A POS PRESS SCBA. AIR PURIFYING (CARTRIDGE) RESP (ING 8)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 7: NOT APPROVED FOR PROT FROM ISOCYANATES. OTHER PROT
EQUIP:COATED TYVEK & SOME NEOPRENES ARE VERY RESIST TO MDI.
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 RAT ORAL 10,000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHRONIC EXPOSURE MAY PERMANENTLY
DECREASE LUNG FUNCTION. PROLONGED OR REPEATED CONTACT MAY CAUSE
SENSITIZATION. MDI MAY INDUCE RESPIRATORY SENSITIZATION WITH
ASTHMA-LIKE SYMPTOMS (CHRONIC COUGH, TIGHT NESS OF CHEST WITH
DIFFICULTY BREATHING). SYMPTOMS MAY BE DELAYED UP TO SEVERAL HOURS
AFTER EXPOSURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IRRITATION.SKIN:PROLONGED/REPEATED CONTACT
MAY CAUSE IRRITATION.TOXIC CONCENTRATIONS WILL PROBABLY NOT BE
ABSORBED THROUGH SKIN.INGESTION:PRACTICALLY NONTOXIC.IRRITATION OF
MOUTH, PHARYNX,ESOPHAG US,STOMACH.INHAL:VAPORS & AEROSOLS MAY CAUSE
IRRITATION OF NOSE,RESP PASSAGES.SEVERE OVEREXPOS MAY CAUSE
PULMONARY EDEMA
Medical Cond Aggravated by Exposure:SENSITIZED INDIVIDUALS SHOULD NOT
BE EXPOSED TO PRODUCT WHICH CAUSED SENSITIZATION.THOSE W/ EXISTING
RESPIRATORY DISEASE INCL CHRONIC BRONCHITIS,EMPHYSEMA,ASTHMA SHOULD
NOT BE EXPOSED TO ISOCYANATES.
======================= First Aid Measures =======================
Eyes:IMMED FLUSH W/ PLENTY OF WATER FOR AT LEAST 15 MIN.IF
REDNESS,ITCHING,BURNING SENSATION DEVELOPS,GET MED ATTN. SKIN:WASH
MATL OFF W/ PLENTY OF SOAP & WATER.IF REDNESS,ITCHING,BURNING
SENSATION DE VELOPS,GET MED ATTN.INGEST:GIVE 1 OR 2 GLASSES
WATER.IF GI SYMPTOMS DEVELOP,CONSULT MD.NEVER GIVE ANYTHING BY
MOUTH TO UNCON PERS. INHAL:REMOVE TO FRESH AIR.GIVE ARTF
RESP/OXYGEN AS REQD.CONSULT MD.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:425F,218C
Extinguishing Media:DRY CHEM,FOAM,CO2,HALOGENATED AGENTS.IF H2O USED,
USE VERY LRG QTIES.RXN BETWEEN H2O & HOT ISOCYANATE MAY BE VIGOROUS
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:H2O CONTAM WILL PRODUCE CO2.DO NOT RESEAL
CONTAM CNTNRS,AS PRESS BUILDUP MAY RUPTURE THEM.HAZ DECOMP
PRODUCTS:CO2, CO,NITROGEN OXIDES,AMMONIA,TRACES OF HCN.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SKIN,EYE,RESP PROT.SOAK UP W/ ABSORB &
SHOVEL INTO WASTE CNTNR.COVER CNTNR,BUT DO NOT SEAL.REMOVE FROM
AREA.TREAT SPILL W/ DECONTAM SOLN OF 0.2-0.5% LIQ DETERGENT & 3-8%
CONCENTRATED NH4OH (POSS TO USE 5-10% SODIUM CARBONATE FOR
NHOH)(SEE SUP)
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY SEALED CONTAINERS AND
PROTECT FROM ATMOSPHERIC MOISTURE.STORE IN COOL AREA.
Other Precautions:PREVENT SKIN AND EYE CONTACT.AVOID BREATHING VAPORS
OR AEROSOLS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:BECAUSE LOW VAP PRESS,VENT IS USUALLY SUFF TO
KEEP VAPS BELOW TLV AT ROOM TEMP UNLESS MATL SPRAYED/HEATED.IF
CONCS EXPECTED TO EXCEED TLV USE NIOSH/MSHA APPRVD POS PRESS SUPP
AIR RESP W/ FULL FACEPIEC E/ AIR-SUPP HOOD.FOR EMER USE (SEE ING 7
Ventilation:IF NEEDED,LOC EXHST VENT TO KEEP AIR CONCS BELOW TLV AS IN
ACGIH "INDUST VENT".EXHST MAY REQ SCRUBBERS/FILTERS TO CLEAN.
Protective Gloves:IMPERVIOUS UNDER CONDITIONS OF USE.
Eye Protection:CHEM TIGHT GOG,FACEPIECE IF SPLASH POSS.
Other Protective Equipment:APRON,ARM COVERS,FULL BODY SUIT AS REQ.EYE
WASH STATION,SFTY SHOWER IN WORK AREA.BUTYL & NITRILE RUB,SARANEX
(SEE ING 8)
Work Hygienic Practices:WORKERS SHOULD SHOWER & CHANGE TO FRESH
CLOTHING AFTER EACH SHIFT.WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
BP:DECOMP @ 646F,341.1C.VP:<0.0001 MMHG. MATLS TO AVOID:@ TEMP
>122F,50C & WHEN CONT W/ ALKALIS,TERTIARY AMINES, METAL CMPDS.SOME
RXNS VIOLENT.CNDTNS (POLYM):CO2 MAY RUPTURE CLSD CNTNR. SPILL
PROC:TRE AT W/ 10 PARTS DECOMTAM SOLN TO 1 PART SPILL.LET REACT AT
LEAST 10 MIN.CO2 WILL EVOLVE,INSOL POLYUREAS REMAIN.(SEE ING
================== Physical/Chemical Properties ==================
HCC:T6
Boiling Pt:B.P. Text:SEE SUPP
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:646F,341.1C
Vapor Pres:SEE SUPP
Vapor Density:8.6,AIR=1
Spec Gravity:1.2,WATER=1
Evaporation Rate & Reference:N/K
Solubility in Water:REACTS
Appearance and Odor:DARK BROWN,VISCOUS LIQUID WITH SLIGHT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WILL REACT W/ ANY MATLS W/ ACTIVE HYDROGEN INCL H2O,
ALCOHOL,AMMONIA,AMINES,ALKALIS,ACIDS.RXN W/ H2O IS ACCEL (SEE SUP
Stability Condition to Avoid:MOISTURE
Hazardous Decomposition Products:COMBUSTION PRODUCTS:CARBON DIOXIDE,
CARBON MONOXIDE. NITROGEN OXIDES, AMMONIA, TRACE AMOUNTS OF
HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:HIGH TEMPS IN PRESENCE OF
ALKALIS,TERTIARY AMINES,& METAL CMPDS WILL ACCEL
POLYMERIZATION.POSS EVOLUTION OF (SEE SUPP)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IAW LOCAL,STATE,FED REGS .
SLOWLY STIR ISOCYANATE WASTE INTO DECONTAM SOLN ABOVE,10 PARTS SOLN
TO 1 PART ISOCYANATE.LET STAND 48 HRS,ALLOWING EVOLVED CO2 TO VENT
OFF.NEUT WASTE. DRAIN DRUM THORO TO STOR VESSEL BEFORE (SEE ING 3
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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