vent: permissible expos lim which may be listed. refer to ing 23:conference of governmental industiral hygienists. volatile organic compounds: 497 g/l (4.14 lb/gal) less efts of overexp:dioxide in a 24-mth inhal study w/rats ing 9:tumors in group exposed to 250 mg/m3 respirable tio*2 ing 10:was not observed. norm clearance mechanisms of lungs ing 11: this may have contributed to tumor form. these ing 12:occup expos lim are observed. @ tlv tio*2 mfr ing 13:studies involving rats indicate some evidence that first aid proc: trtmt that might be reqd for overexp should spill proc: use only non-sparking tools. place absorb ing 16:contam of sewers, streams, & groundwater w/spilled resp prot: vent areas a niosh/msha apprvd chem cartridge ing 18:spraying, a niosh/msha apprvd mech prefilter may ing 19: air supplied resp. if tlv's are exceeded use a ing 20:prot factor. refer to osha 29cfr1910.134 "resp acetic acid, 2-methoxy-1-methylethyl ester; (propylene xylene. vp: 5@20c. lel: 1%. uel: 7% dipropylene glycol; (methyl ether acetate) titanium oxide; (titanium dioxide) amorphous silica gel; (silica-amorphous hydrated) acetic acid, ethyl ester; (ethyl acetate). vp: 73@20c. lel: 2-butanone; (methyl ethyl ketone). vp: 70@20c. lel: 2%. msds toxicity property">
vent: permissible expos lim which may be listed. refer to ing 23:conference of governmental industiral hygienists. volatile organic compounds: 497 g/l (4.14 lb/gal) less efts of overexp:dioxide in a 24-mth inhal study w/rats ing 9:tumors in group exposed to 250 mg/m3 respirable tio*2 ing 10:was not observed. norm clearance mechanisms of lungs ing 11: this may have contributed to tumor form. these ing 12:occup expos lim are observed. @ tlv tio*2 mfr ing 13:studies involving rats indicate some evidence that first aid proc: trtmt that might be reqd for overexp should spill proc: use only non-sparking tools. place absorb ing 16:contam of sewers, streams, & groundwater w/spilled resp prot: vent areas a niosh/msha apprvd chem cartridge ing 18:spraying, a niosh/msha apprvd mech prefilter may ing 19: air supplied resp. if tlv's are exceeded use a ing 20:prot factor. refer to osha 29cfr1910.134 "resp acetic acid, 2-methoxy-1-methylethyl ester; (propylene xylene. vp: 5@20c. lel: 1%. uel: 7% dipropylene glycol; (methyl ether acetate) titanium oxide; (titanium dioxide) amorphous silica gel; (silica-amorphous hydrated) acetic acid, ethyl ester; (ethyl acetate). vp: 73@20c. lel: 2-butanone; (methyl ethyl ketone). vp: 70@20c. lel: 2%. msds toxicity property">
ing 21:indust hygiene assoc". vent: permissible expos lim which may be listed. refer to ing 23:conference of governmental industiral hygienists. volatile organic compounds: 497 g/l (4.14 lb/gal) less efts of overexp:dioxide in a 24-mth inhal study w/rats ing 9:tumors in group exposed to 250 mg/m3 respirable tio*2 ing 10:was not observed. norm clearance mechanisms of lungs ing 11: this may have contributed to tumor form. these ing 12:occup expos lim are observed. @ tlv tio*2 mfr ing 13:studies involving rats indicate some evidence that first aid proc: trtmt that might be reqd for overexp should spill proc: use only non-sparking tools. place absorb ing 16:contam of sewers, streams, & groundwater w/spilled resp prot: vent areas a niosh/msha apprvd chem cartridge ing 18:spraying, a niosh/msha apprvd mech prefilter may ing 19: air supplied resp. if tlv's are exceeded use a ing 20:prot factor. refer to osha 29cfr1910.134 "resp acetic acid, 2-methoxy-1-methylethyl ester; (propylene xylene. vp: 5@20c. lel: 1%. uel: 7% dipropylene glycol; (methyl ether acetate) titanium oxide; (titanium dioxide) amorphous silica gel; (silica-amorphous hydrated) acetic acid, ethyl ester; (ethyl acetate). vp: 73@20c. lel: 2-butanone; (methyl ethyl ketone). vp: 70@20c. lel: 2%.
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: CAN CAUSE GI IRRIT,
NAUS, & VOMIT. ASPIR OF MATL INTO LUNG MAY CAUSE CHEM PNEUM WHICH
CAN BE FATAL. INHAL: MAY CAUSE NOSE/THROAT IRRIT. HIGH CONC MAY
CAUSE ACUTE CNS DEPRESS CHARACT BY HDCH, DIZZ, NAUS & CONFUSN.
EYE: MAY CAUSE SEV IRRIT & CORNEAL DAM. SKIN: LIQ MATL MAY BE
ABSORBED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:THRU SKIN IN HARMFUL AMTS. MAY CAUSE
SEV SKIN IRRIT. CHRONIC:OVEREXP TO XYLENE MAY CAUSE INJURY TO
LIVER, KIDNEYS, & BLOOD. EXPOS TO METHYL ETHYL KETONE MAY INHANCE
NEUROTOXICITY OF N-HEXANE & METHYL-N-BUTYL KETONE. SYNERGISTIC EFT
HAS RSLTD IN PERIPHRAL NEUROPATHY IN HUMANS. RPTS HAVE ASSOC
PRLNGD/(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMIT. CALL POIS CTL CTR, HOSP EMER
ROOM/PHYS IMMED. INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED, GIVE ARTF RESP. KEEP WARM & QUIET. GET MED ATTN IMMED.
EYE: FLUSH W/L G AMTS OF WATER, LIFT LIDS OCCAS. CONTINUE FOR @ LST
15 MIN. GET MED ATTN. SKIN: REMOVE CONTAMD CLTHG. WASH AFFECTED
AREA W/SOAP/WATER. OBTAIN MED ATTN IF IRRIT PERSISTS. NOTES TO
PHYS: ANY (ING 15)
===================== Fire Fighting Measures =====================
Flash Point:24.0F,-4.4C
Lower Limits:1%
Upper Limits:11%
Extinguishing Media:USE NFPA CLASS B FIRE EXTING (CARBON DIOXIDE, ALL
PURPOSE DRY CHEM/ALCOHOL FOAM) DESIGNED TO EXTING FLAMM (SUPP DATA)
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WTER
MAY BE INEFTIVE, BUT MAY BE USED TO COOL EXPOS CONTRS TO PVNT PRESS
BUILD-UP & POSS AUTO-IGNIT/ (SUPP DATA)
Unusual Fire/Explosion Hazard:DURING EMER CNDTNS, OVEREXP TO DECOMP
PROD MAY CAUSE HLTH HAZ.SYMPTOMS MAY NOT BE IMMED APPARENT. OBTAIN
MEDICAL ATTENTION.
Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM ALL IGNIT SOURCES
(FLAMES/HOT SURF, & SOURCES OF ELEC, STATIC/FRICTIONAL SPARKS).
DIKE & CNTN SPILL W/INERT MATL (E.G. SAND, EARTH). TRANSFER LIQ TO
COVERED METAL CONTRS FOR RECOVERY/DISP/TO REMOVE W/INERT ABSORB.
(ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 115F(46C) STORE
LARGE QTY IN COMPLIANCE WITH OSHA 29CFR1910.106. CLOSE CONTR AFTER
EACH USE.
Other Precautions:DO NOT TAKE INTERNALLY. EMPTY CNTRS MUST NOT BE
WASHED & RE-USED FOR ANY PURPOSE. CONTRS SHOULD BE GROUNDED &
BONDED TO RECEIVING CONTR. DO NOT WELD/BRAZE/CUT ON EMPTY CONTR.
NEVER USE PRESS TO EMPTY. DRUM IS NOT A PRESS VESSEL.
Respiratory Protection:PROPER SELECTION OF RESP PROT DPNDS UPON MANY
FACTORS INCL DURATION/LEVEL OF EXPOS & CNDTNS OF USE. IN GEN EXPOS
TO ORG CHEM SUCH AS THOSE CNTND IN PROD MAY NOT REQ USE OF RESP
PROT IF USED IN WELL V ENTD AREAS. IN RESTRICTED (ING 18)
Ventilation:PROVIDE LOC EXHAUST VENT IN SUFFICIENT VOL & PATTERN SO AS
TO MAINTAIN EXPOS BELOW NUISANCE DUST LIM & (ING 23)
Protective Gloves:SOLVENT IMPERMEABLE GLOVES.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA: LIQ FIRES. POLYMER FOAM IS PREFERRED FOR LG FIRES. FIRE
FIGHT PROC:EXPLOS WHEN EXPOS TO EXTREME HEAT.IF WATER IS USED, FOG
NOZZ ARE PREF. EFTS OF OVEREXP: RPTD OCCUP OVEREXP TO SOLV W/PE RM
BRAIN & NERV SYS DAM. INTENTIONAL MISUSE BY DELIB CONC & INHALING
CONTENTS MAY BE HARMFUL/FATAL. DRY TITANIUM (ING 9)
HCC:F3
Boiling Pt:B.P. Text:>167F,>75C
Melt/Freeze Pt:M.P/F.P Text:-50F,-46C
Vapor Pres:73@68F
Vapor Density:HVR/AIR
Spec Gravity:1.4
pH:4-7
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT IN WATER
Appearance and Odor:LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:52
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>115F (46C)) &
SOURCES OF IGNITION.
Hazardous Decomposition Products:BURNING INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON
DIOXIDE.
Waste Disposal Methods:DISPOSE I/A/W FED, ST & LOC LAWS. INCIN ONLY IN
EPA PERMITTED FACILITY. DO NOT INCINERATE CLSD CONTRS. OBSERVE PREC
FOR DISP OF FLAMM MATLS. CONTAMD ABSORB MAY BE DISPOSED IN A HAZ
WASTE LANDFILL. DIS POSE ONLY I/A/W FED, ST & LOC REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.