spill proc:residue w/absorb such as clay, sand or other ing 7:tightly for proper disp. flush area w/water to remove ing 8:spills:take up with an absorbent material & place in other prec:use with adeq vent. cntnrs, even empty, can cntn ing 10:perform similar opers on/near cntnrs. static elec ing 11:bond and ground transfer containers and equipment. solvent naphtha (petroleum), medium aliphatic;(shell supp data:in one of the studies a low grade anemia was also first aid proc:pvnt aspir of liq into lungs. get md. note ing 3:vomit has not occured, emesis should be induced ing 4:if symps such as loss of gag reflex, convl or uncon ing 5:endotrachael tube should be considered.
LD50 LC50 Mixture:LD50:(ORAL RAT):> 8 ML/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:LIQ IS MODERATELY IRRITATING. VAPS
PRESUMED TO BE IRRITATING. SKIN:LIQ IS MODERATELY IRRIT.
PRLNGD/RPTD LIQ CNTCT CAN RSLT IN DEFAT & DRYING WHICH MAY RESULT
IN IRRITATION & DERM. INHAL:MAY CAUSE IRRIT TO NOSE, THROAT, &
RESP TRACT. HIGH VAP CONC MAY RSLT IN CNS DEPRESS. INGEST:MAY RSLT
IN VOMIT; (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:ASPIR (BRTHG) OF VOMIT INTO LUNGS MUST
BE AVOIDED AS EVEN SMALL QTYS MAY RSLT IN ASPIR PNEUMIT.
SIGNS/SYMPS:IRRIT AS NOTED. EARLY TO MOD CNS DEPRESS MAY BE
EVIDENCED BY GIDDINESS, HDCH, DIZZ & NAUS; IF EXTREME CASES, UNCON
& DEATHMAY OCCUR. ASPIR PNEUMIT MAY BE EVIDENCED BY COUGHING,
LABORED BRTHG & (SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS WHILE
HOLDING EYELIDS OPEN. GET MD. SKIN:REMOVE CONTAM CLTHG/SHOES. FLUSH
SKIN W/WATER. FOLLOW BY WASHING W/SOAP & WATER. IF IRRIT OCCURS GET
MD. DO NO T REUSE CLTHG UNTIL CLEANED. INHAL:MOVETO FRESH AIR &
GIVE O*2 IF BRTHG DFCLT. GIVE ARTF RESP IF NOT BRTHG. INGEST:DO NOT
INDUCE VOMIT. IF VOMIT OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS
TO (ING 3)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:108F,42C
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:WATER FOG, FOAM, DRY CHEM/CO*2. DO NOT USE DIRECT
STREAM OF WATER. PRODUCT WILL FLOAT & CAN BE REIGNIT ON SURF OF
WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT. COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:CNTNRS EXPOSED TO INTENSE HEAT FROM FIRES
SHOULD BE COOLED W/WATER TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT
IN CNTNR RUPTURE. CNTNR AREAS EXPOSED TO (SUPDAT)
Spill Release Procedures:CAUTION. COMBUSTIBLE. LRG SPILLS:ELIM PONTNTL
IGNIT SOURCES. WEAR NIOSH/MSHA APPROVED RESP & OTHER PROT CLTHG.
SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE/CNTN. REMOVE
W/VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP (ING
7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP LIQUID AND VAPOR AWAY FROM HEAT,
SPARKS & FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN
LIQ PRODUCT IN ABSENCE OF SPARKS OR FLAME.
Other Precautions:EXTING PILOT LIGHTS, CIGARETTES & TURN OFF OTHER
IGNIT SOURCES PRIOR TO USE & UNTIL ALL VAPS ARE GOVE. VAPS MAY
ACCULULATE & TRAVEL TO IGNIT SOURCES DISTANT FROM HNDLG SITE;
FLASH-FIRE CAN RSLT. KEEP CNTNRS CLSD WHEN NOT IN USE. (ING 10)
Respiratory Protection:AVOID PRLNGD/RPTD BRTHG OF VAPS. IF EXPOS
MAY/DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS USE NIOSH/MSHA APPRVD
RESPIRATOR TO PREVENT OVEREXPOSURE; I/A/W 29 CFR 1910.134 USE
EITHER ATOMSPHERE-SUPPLYING R ESP OR AIR-PURIFYING RESP FOR ORG
VAPS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:OTHER CLOTHING AS REQUIRED TO MINIMIZE
CONTACT. TEST DATA INDICATE NITRILE MATERIAL PROVIDES THE BEST
PROTECTION.
Work Hygienic Practices:AIR-DRY CONTAMINATED CLOTHING IN A WELL
VENTILATED AREA THEN LAUNDER BEFORE REUSING.
Supplemental Safety and Health
SPEC GRAV:0.76-0.78 (H*2O=1). EXPLO HAZ:DIRECT FLAME CNTCT SHOULD ABE
COOLED W/LRG QTYS OF WATER AS NEEDED TO PVNT WEAKENING OF CNTNR
STRUCTURE. EFTS OF OVEREXP:CYANOSIS. MALE RATS EXPOSED FOR 90 DAYS
BY INHAL TO VAPS OF SIMILAR SOLVS SHOWED EVIDENCE OF KIDNEY DMG.
THE RELEVANCE OF THIS EFT TO MAN IS UNKNOWN. (ING 2)
Boiling Pt:B.P. Text:>325F,>163C
Vapor Pres:7 @ 100F
Vapor Density:4.8
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:<0.2 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID, HYDROCARBON ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, & FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.