| MSDS | : | VOC MIX-2, 1ML, 48777 | | CAS | : | 100-41-4
100-42-5
108-38-3
99-87-6
104-51-8
108-86-1
87-61-6
95-63-6
67-56-1
71-43-2
108-88-3
108-67-8
91-20-3
120-82-1 | | NAME | : | benzene, ethyl-; (ethylbenzene) (sara iii).
styrene; (benzene, ethenyl-) (sara iii)
m-xylene; (benzene, 1,3-dimethyl-) (sara iii). ld50:(oral,
p-cymene; (benzene, 1-methyl-4-(1-methylethyl)-p-cymene).
benzene, butyl- (butylbenzene)
benzene, bromo-; (bromobenzene). ld50:(oral,rat) 2699
benzene, 1,2,3-trichloro-; (1,2,3-trichlorobenzene)
benzene, 1,2,4-trimethyl; (1,2,4-trimethylbenzene) (sara
methanol (sara iii). ld50:(oral,rat) 5628 mg/kg.
benzene (sara iii). ld50:(oral,rat) 4894 mg/kg.
toluene; (benzene, methyl-) (sara iii). ld50:636 mg/kg.
mesitylene; (benzene, 1,3,5-trimethyl-mesitylene)
naphthalene (sara iii). ld50:(oral,rat) 1780 mg/kg.
benzene, 1,2,4-trichloro-; (1,2,4-trichlorobenzene) (sara
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===================== Product Identification =====================
MSDS NAME:VOC MIX-2, 1ML, 48777
NIIN:00N043078
MSDS Number: BRRDC
=== Responsible Party ===
Company:SUPELCO INC
Address:SUPELCO PARK
City:BELLEFONTE
State:PA
ZIP:16823-0048
Country:US
Info Phone Num:814-359-3441
Emergency Phone Num:814-359-3441
CAGE:54968
=== Contractor Identification ===
Company:SIGMA-ALDRICH INC.
Address:3050 SPRUCE STREET
Box:14508
City:ST. LOUIS
State:MO
ZIP:63103
Country:US
Phone:314-771-5765/414-273-3850X5996
CAGE:54968
============= Composition/Information on Ingredients =============
Name:BENZENE, ETHYL-; (ETHYLBENZENE) (SARA III).
LD50:(ORAL,RAT) 3500 MG/KG.
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 0.2%
OSHA PEL:100 PPM;125 PPM STEL
ACGIH TLV:100 PPM;125 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:STYRENE; (BENZENE, ETHENYL-) (SARA III)
CAS:100-42-5
RTECS #:WL3675000
Fraction by Wt: 0.2%
OSHA PEL:100 PPM
ACGIH TLV:S,50PPM/100STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:M-XYLENE; (BENZENE, 1,3-DIMETHYL-) (SARA III). LD50:(ORAL,
RAT) 5000 MG/KG.
CAS:108-38-3
RTECS #:ZE2275000
Fraction by Wt: 0.2%
OSHA PEL:100 PPM;150 PPM STEL
ACGIH TLV:100 PPM;15O PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:P-CYMENE; (BENZENE, 1-METHYL-4-(1-METHYLETHYL)-P-CYMENE).
LD50:(ORAL,RAT) 4750 MG/KG.
CAS:99-87-6
RTECS #:GZ5950000
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BENZENE, BUTYL- (BUTYLBENZENE)
CAS:104-51-8
RTECS #:CY9070000
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BENZENE, BROMO-; (BROMOBENZENE). LD50:(ORAL,RAT) 2699
MG/KG.
CAS:108-86-1
RTECS #:CY9000000
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:0.5 PPM (MFR)
Name:BENZENE, 1,2,3-TRICHLORO-; (1,2,3-TRICHLOROBENZENE)
CAS:87-61-6
RTECS #:DC2095000
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BENZENE, 1,2,4-TRIMETHYL; (1,2,4-TRIMETHYLBENZENE) (SARA
III)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 0.2%
OSHA PEL:25 PPM
ACGIH TLV:25 PPM
Name:METHANOL (SARA III). LD50:(ORAL,RAT) 5628 MG/KG.
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 97.4%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:BENZENE (SARA III). LD50:(ORAL,RAT) 4894 MG/KG.
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 0.2%
OSHA PEL:1 PPM;5 PPM STEL
ACGIH TLV:10 PPM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:TOLUENE; (BENZENE, METHYL-) (SARA III). LD50:636 MG/KG.
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 0.2%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:MESITYLENE; (BENZENE, 1,3,5-TRIMETHYL-MESITYLENE)
CAS:108-67-8
RTECS #:OX6825000
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:NAPHTHALENE (SARA III). LD50:(ORAL,RAT) 1780 MG/KG.
CAS:91-20-3
RTECS #:QJ0525000
Fraction by Wt: 0.2%
OSHA PEL:10 PPM;15 PPM STEL
ACGIH TLV:10 PPM;15 PPM STEL
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:BENZENE, 1,2,4-TRICHLORO-; (1,2,4-TRICHLOROBENZENE) (SARA
III). LD50:(ORAL,RAT) 756 MG/KG.
CAS:120-82-1
RTECS #:DC2100000
Fraction by Wt: 0.2%
OSHA PEL:5 PPM, C
ACGIH TLV:5 PPM, C
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. LOW BLOOD PRESSURE (HYPOTENSION), DERMATITIS, BREATHING
DIFFICULTY, HEADACHE, NAUSEA, DIZZINESS, GASTROINTESTINAL
DISTURBANCES, DEPRESSES CENTRAL NERVOUS SYSTEM, NARCOSIS,
LIVER/KIDNEY DAMAGE,RESPIRATORY FAILURE, BLINDNESS. MAY CAUSE
CORNEAL INJURY. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC MONOGRAPHS, SUPP, VOL 7, PG
120, 1987:GRP 1. NTP 6TH ANNUAL RPT ON CARCINS, 1991:KNOWN TO BE
(SUPDAT)
Effects of Overexposure:HLTH HAZ:TOLUENE (108-88-3) APPEARS ON THE NAVY
LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK
CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING
LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE
INFORMATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes:FLUSH W/WATER FOR AT LST 15 MINS. CONT MD. SKIN:FLUSH
W/LG VOLS OF WATER. WASH CLTHG & SHOES BEFORE REUSING. INHAL:IMMED
MOVE TO FRESH AIR. GIVE OXYGEN IF BRTHG IS LABORED. IF BRTHG STOPS,
GIVE A RTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERS. NEVER TRY TO MAKE UNCON PERS VOMIT. GIVE 2 TBSPS OF
BAKING SODA IN GLASS OF WATER. PRESS FINGER TO BACK OF TONGUE TO
(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:50.0F,10.0C
Lower Limits:6%
Upper Limits:36.5%
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION; CARBON MONOXIDE,
CARBON DIOXIDE, FORMALDEHYDE.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINERS. KEEP
AWAY FROM OXIDIZERS & IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:NONE
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:CARCINOGENIC. 29 CFR 1910.1028,02 JUL '92.
:OSHA-CANCER HAZARD. STYRENE:IARC MONOGRAPHS, SUPP, VOL 7, PG 345,
1987:GRP 1. FIRST AID PROC:INDUCE VOMITING. IMMEDIATELY CONTACT MD.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79 (H2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100%
Appearance and Odor:COLORLESS LIQUID.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE,
PERCHLORIC ACIDS, ALUMINUM & MAGNESIUM METALS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE OR LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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