phosphoric acid, tributyl ester; (tributyl phosphate) hexahydrophthalic anhydride silane, 3-(2,3-epoxypropoxy) propyltrimethoxy-; (silane spill proc: standard: 29 cfr part 1910.120 hazardous waste waste disp: render the resulting matl hazardous. contact ing 5: consult 40 cfr part 261 identification and listing other prec: and for controlling the fire/explosion hazard. ing 7: if the existing concentrations are within the
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION, INFLAMMATION. SKIN:
IRRITATION, DERMATITIS. INHAL: DIZZINESS, LOSS OF CONSCIOUSNESS,
IRRITATION, SENSITIZER WITH ASTHMATOID EFFECTS, WHEEZING, COUGHING,
SORE THROAT. INGEST: NAUSEA, VOMITING, ABDOMINAL PAIN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: FLUSH W/WATER FOR @ LST 15 MIN. CALL A PHYSICIAN IMMED.
SKIN: WASH W/SOAP & WATER. LAUNDER CONTAM CLOTHING BEFORE REUSE.
GET MED ATTN. INHAL:REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF
BREATHING I S DIFFICULT. BEGIN RESUSCITATION IF BRTHG HAS STOPPED.
KEEP PERSON WARM & QUIET. GET MEDICAL ATTN. INGEST: DO NOT INDUCE
VOMITING. GET MEDICAL ATTN IMMED. NOTE TO MD: TRIBUTYL PHOSPHATE
(SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point:>200F,>93C
Extinguishing Media:DRY CHEMICAL, CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND AND MAY BE IGNITED AT DISTANT LOCATIONS.
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. ABSORB
SPILLED MATL WITH VERMICULITE OR FLOOR ABSORBENT. DISPOSE OF CONTAM
MATL PROPERLY. USE SAFETY GOGGLES OR GLASSES W/SIDE SHIELDS,
APPROPRIATE NIOSH/MSHA APPROV ED MASK, & GLOVES. REFER TO OSHA (ING
4)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CNTNRS OF THESE MATLS MAY BE HAZARDOUS
WHEN EMPTIED, SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES WHICH CAN
GENERATE VAPS WITHIN THE FLAMMABLE LIMITS.
Other Precautions:FOR FLAMM OR COMBUSTIBLE PRODS FOLLOW STORAGE &
HANDLING GUIDELINES PRESENTED IN NFPA 30 FLAMMABLE & COMBUSTIBLE
LIQUIDS CODE. THE USE OF A HAZARDOUS CHEMICAL MAY REQUIRE
SUPPLEMENTAL VENTILATION FOR THE PROTECTION OF PERSONNEL (ING 7)
Respiratory Protection:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW
APPLICABLE OCCUPATIONAL EXPOSURE STANDARDS. ENGINEERING OR
ADMINISTRATIVE CONTROLS OR NIOSH/MSHA APPRVD RESPS CAN BE USED TO
REDUCE EXPOSURE. ENGINEERING CONTROLS ARE PREFERRED BY OSHA.
Ventilation:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW APPLICABLE
OCCUPATIONAL EXPOSURE STANDARDS.
Protective Gloves:CHEMICALLY RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES W/SIDESHIELDS OR GOGGLES.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: POSSESSES ONLY WEAK ANTICHOLINESTERASE ACTIVITY WHICH
SHOULD NOT REQUIRE SPECIFIC TREATMENT. LARGE DOSES HAVE BEEN
REPORTED TO CAUSE DYSPNEA, WEAKNESS, PULMONARY EDEMA, AND TWITCHING
I N RATS. CHRONIC INHALATION OF LARGE DOSES CAN LEAD TO GENERAL
POISONING WITH PARALYSIS.
Vapor Pres:VERY LOW
Evaporation Rate & Reference:VERY SLOW
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID OR SEMI-SOLID INK AS COLOR ABOVE, MILD ODOR.
Percent Volatiles by Volume:APPROX
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS AND BASES. WATER.
Stability Condition to Avoid:HEAT AND FLAME.
Hazardous Decomposition Products:CO, CO*2, SILICON OXIDES.
Waste Disposal Methods:UNDER RCRA, IT IS THE RESPONSIBILITY OF THE
GENERATOR OF THE WASTE TO DETERMINE, AT THE TIME OF DISPOSAL,
WHETHER THE WASTE GENERATED MEETS THE FEDERAL OR STATE HAZAROUS
WASTE CRITERIA. USES, TRANSFOR MATIONS, MIXTURES, PROCESSES, ETC.
MAY (ING 5)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.