MSDS NAME:LEAD-ACID BATTERY 4D-3668
NIIN:01-081-5907
MSDS Number: BSDSH
=== Responsible Party ===
Company:FOURDEE INC. (CO OUT OF BUSINESS)
Address:CO OUT OF BUSINESS
City:TAMPA
State:FL
Country:US
Emergency Phone Num:CO OUT OF BUSINESS
Preparer's Name:DGSC-SSH
CAGE:MO858
=== Contractor Identification ===
Company:BOLLE METAL FABRICATING INC.
CAGE:07761
Company:FOURDEE (OUT OF BUSINESS)
Box:City:SANFORD
State:FL
ZIP:32773-6062
Country:US
CAGE:5L487
Company:FOURDEE INC. (CO OUT OF BUSINESS)
Address:CO OUT OF BUSINESS
Box:City:TAMPA
State:FL
Country:US
CAGE:MO858
============= Composition/Information on Ingredients =============
LD50 LC50 Mixture:LD50 ORAL RAT IS 2140 MG/KG (SULF. ACID)
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SEVERE BURNS AND ULCERATION OF
SKIN, EYES, MOUTH, THROAT, ESOPHAGUS AND STOMACH. INFLAMMATION OF
BRONCHIAL MEMBRANES. LEAD MAY CAUSE GASTROINTESTINAL DISORDERS AND
CNS EFFECTS. CHRONIC: EROSION OF TEETH, INFLAMMATION OF NOSE,
THROATAND BRONCHIAL TUBES. LEAD MAY CAUSE ANEMIA, DAMAGE TO KIDNEYS
AND CNS.
Explanation of Carcinogenicity:LEAD IS LISTED UNDER IARC.
Effects of Overexposure:IF CONTACTED, SEVERE BURNS AND ULCERATION OF
SKIN AND EYES. IF INHALED, SEVERE RESPIRATORY IRRITATION. IF
INGESTED, SEVERE BURNS AND ULCERATION.
Medical Cond Aggravated by Exposure:SULFURIC ACID MAY AGGRAVATE SKIN
DISEASES SUCH AS ECZEMA AND DERMATITIS. LEAD CAN AGGRAVATE CHRONIC
FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASES.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH WITH PLENTY OF WATER. SEE DOCTOR
IMMEDIATELY. REMOVE CONTAMINATED CLOTHING AND SHOES. INHALATION:
REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED. SEE DOCTOR.
INGESTION: DO NOT INDUCE VOMITING. GIVE MILK OR WATER, FOLLOWED BY
2 OUNCES OF MILK OF MAGNESIA (NO CARBONATES). SEE DOCTOR
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:4.0(HYDROGN)
Upper Limits:75(HYDROGEN)
Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:EVACUATE AREA. REMOVE ALL IGNITION SOURCES.
WEAR SULFURIC ACID RESISTANT CLOTHING AND A FULL FACED SCBA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:HYDROGEN GAS MAY BE PRODUCED AND MAY
EXPLODE IF IGNITED. REMOVE ALL IGNITION SOURCES. VENTILATE AREA.
WATER GENERATES HEAT AND CAUSES ACID TO SPLATTER.
Spill Release Procedures:WEAR APPROPIATE PROTECTIVE EQUIPMENT. DILUTE
CAUTIOUSLY WITH WATER. COVER WITH SODA ASH OR QUICKLIME. SCOOP UP
AND PLACE IN APPROPIATE DISPOSAL CONTAINER. FLUSH AREA WITH LARGE
AMOUNTS OF WATER.
Neutralizing Agent:SODA ASH (SODIUM CARBONATE), BAKING SODA OR
QUICKLIME (CALCIUM OXIDE).
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE AWAY FROM
FLAMES, IGNITION SOURCES, COMBUSTIBLE AND ORGANIC MATERIALS. AVOID
PROLONGED OVERCHARGING. WEAR PROTECTIVE EQUIPM.
Other Precautions:DO NOT CARRY BATTERY BY TERMINALS. DO NOT DROP
BATTERY, PUNCTURE OR ATTEMPT TO OPEN BATTERY CASE. KEEP TERMINALS
COVERED IN PLASTIC CASE. AVOID SHORTING BATTERIES. PLACE BROKEN
BATTERIES IN PLASTIC CO NTAINERS AND DELIVER TO BATTERY RECYCLER
Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED
CARTRIDGE RESPIRATOR FOR ACIDS OR FULL FACE MASK AS APPROPIATE FOR
EXPOSURE OF CONCERN WHEN TLV IS EXCEEDED.
Ventilation:GENERAL (MECHANICAL) VENTILATION. LOCAL EXHAUST IN CONFINED
AREAS.
Protective Gloves:RUBBER GLOVES IF CONTACT IS EXPECTED.
Eye Protection:GOGGLES IF CONTACT IS EXPECTED.
Other Protective Equipment:RUBBER APRON AND BOOTS IF CONTACT IS
EXPECTED. EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
CLEAN TERMINALS WITH MILD BAKING SODA SOLUTION AND WASH WITH WATER.
WHEN BRUSHING BATTERY POSTS, USE MASK APPROVED FOR LEAD DUST,
SAFETY GLASSES AND GLOVES.
HCC:C1
pH:ACIDIC
Solubility in Water:COMPLETE
Appearance and Odor:ACID SOLUTION IN PLASTIC CASE WITH TOP TERMINALS
AND FILLING CAPS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS, CHLORATES, CARBIDES, FULMINATES, WATER, POWDERED
METALS, SOME NON-ACID-RESISTANT PLASTICS.
Stability Condition to Avoid:AVOID SHORTING, USE ONLY APPROVED CHARGING
METHODS. AVOID HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:SULFURIC ACID FUMES, SULFUR DIOXIDE,
SULFUR TRIOXIDE, HYDROGEN GAS.
Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGUALTIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.