ing 11: stored for excess periods. post "no smoking/open ing 12: be no sources of ignit in stor/use area. for ing 13: pamphlets p-1,p-14 & safety bulletin sb-2. never ing 14: cryogenic liquid form in an enclosed space such as ing 15: in a fire, explosion, asphyxiation or toxic ing 16: mappolene system. elect equip should be ing 17: non-sparking/explo-proof. compress gas cylinders ing 18: of compressed gases. shipments of compressed gas ing 19: written consent is a violation of federal law propane propene; (propylene) (sara iii) supp data: liquid, do not wash eyes w/hot/tepid water! ing 3: allow liquid to evap. if pain is present, refer ing 4: victim cannot tolerate light, protect eyes with a disp meth: with any valve outlet plugs/caps secured & valve msds toxicity property">
other precs: increase discharge rate of prod from cylinder. ing 7: back flow into the cylinder. prot cylinders from ing 8: non-combust construction away from heavily ing 9:cylinders are stored to exceed 130f(54c). cylinders ing 10:falling/being knocked over. use a "first in-first ing 11: stored for excess periods. post "no smoking/open ing 12: be no sources of ignit in stor/use area. for ing 13: pamphlets p-1,p-14 & safety bulletin sb-2. never ing 14: cryogenic liquid form in an enclosed space such as ing 15: in a fire, explosion, asphyxiation or toxic ing 16: mappolene system. elect equip should be ing 17: non-sparking/explo-proof. compress gas cylinders ing 18: of compressed gases. shipments of compressed gas ing 19: written consent is a violation of federal law propane propene; (propylene) (sara iii) supp data: liquid, do not wash eyes w/hot/tepid water! ing 3: allow liquid to evap. if pain is present, refer ing 4: victim cannot tolerate light, protect eyes with a disp meth: with any valve outlet plugs/caps secured & valve msds toxicity property">
MSDS
:
MAPPOLENE, G-55
CAS
:
74-98-6 115-07-1
NAME
:
eye prot: welding or cutting. other precs: increase discharge rate of prod from cylinder. ing 7: back flow into the cylinder. prot cylinders from ing 8: non-combust construction away from heavily ing 9:cylinders are stored to exceed 130f(54c). cylinders ing 10:falling/being knocked over. use a "first in-first ing 11: stored for excess periods. post "no smoking/open ing 12: be no sources of ignit in stor/use area. for ing 13: pamphlets p-1,p-14 & safety bulletin sb-2. never ing 14: cryogenic liquid form in an enclosed space such as ing 15: in a fire, explosion, asphyxiation or toxic ing 16: mappolene system. elect equip should be ing 17: non-sparking/explo-proof. compress gas cylinders ing 18: of compressed gases. shipments of compressed gas ing 19: written consent is a violation of federal law propane propene; (propylene) (sara iii) supp data: liquid, do not wash eyes w/hot/tepid water! ing 3: allow liquid to evap. if pain is present, refer ing 4: victim cannot tolerate light, protect eyes with a disp meth: with any valve outlet plugs/caps secured & valve
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: ASPHYX. MAINTAIN O2 LEVELS
>19.5% AT SEA LEVEL. TOXIC, CNS DEPRESSANT & IRRIT. INHAL OF GAS
WILL LEAD TO DIZZ, DROW & UNCON, NARCOTIC EFFECT;HOWEVER MAJOR HAZ
IS EXCLUSION OF ADEQUATE SUPPLY OF OXYGEN TO LUNGS. SKIN: CONT
W/LIQUEFIED PROD WILL CAUSE "COLD BURN", FROSTBITE/BLINDNESS.
FROSTBITE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: EFFECTS APPEAR AS CHANGE IN COLOR OF
SKIN TO GRAY-WHITE POSSIBLY FOLLOWED BY BLISTERING. EYES: CONT
W/LIQUID MAY CAUSE "COLD BURN", FROSTBITE OR BLINDNESS. INGEST:
CONTACT WITH LIQUID MAY CU ASE FROSTBITE OR "COLD BURNS". MAPPOLENE
DISPLACES OXYGEN IN CONFINED AREAS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP. RESUCE
PERS SHOULD BE EQUIPPED W/NIOSH/MSHA APPRVD SCBA.INHAL: REMOVE TO
FRESH AIR. QUICK REMOVAL FROM CONTAMD AREA IS MOST IMPORTANT. UNCON
PERS SHOULD BE MOVED TO UNCONTAMD AREA, GIVEN ARTF RESP & SUPP O2.
FURTHER TREATMENT SHOULD BE SYMPTO & SUPPORTIVE. SKIN: REMOVE
CONTAMD CLTHG & FLUSH AFFECTED AREAS W/LUKEWARM WATER. DO NOT (SUPP
DATA)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-162F,-108C
Lower Limits:2.0%
Upper Limits:11.1%
Extinguishing Media:WATER FOG, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
IF POSS, STOP FLOW OF GAS & ALLOW FIRE TO BURN OUT. USE WATER SPRAY
TO COOL ALL EXPOSED SURFS (SUPP DATA)
Unusual Fire/Explosion Hazard:PRODUCT WILL IGNITE AT AMBIENT TEMPS &
CAN BE EXPECTED TO FORM FLAMMABLE MIX UPON RELEASES TO ATMOSPHERE.
MAY BURN W/ AN ALMOST INVISIBLE FLAME IN BRIGHT LIGHT.
Spill Release Procedures:EVAC ALL PERS FROM AFFECTED AREAS. ELIMINATE
ALL IGNITION SOURCES. REMOVE CYLINDER TO OUTDOORS & SHUT OFF LEAK
IF POSS. PREVENT ESCAPING LIQUID FROM POOLING/SETTLING INTO SEWERS
OR LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY IN WELL-VENTED AREAS. VALVE
PROT CAPS MUST REMAIN IN PLACE UNLESS CNTNR IS SECURED W/VALVE PROT
OUTLET PIPED TO USE POINT.
Other Precautions:DO NOT DRAG, SLIDE OR ROLL CYLINDERS. USE A SUITABLE
HAND TRUCK FOR CYLINDER MOVEMENT. USE A PRESS REDUCING REGULATOR
WHEN CONNECTING CYLINDER TO LOWER PRESS (<3000 PSIG)
PIPING/SYSTEMS. DO NOT HEAT C YLINDER BY ANY MEANS TO (ING 7)
Respiratory Protection:NIOSH/MSHA POSITIVE PRESS AIR LINE W/MASK/SCBA
SHLD BE AVAILABLE WHEN WELDING/CUTTING IN CONFINED AREAS, WHERE THE
EXPOS LIMITS ARE EXCEEDED OR WHERE O2 LEVELS ARE REDUCED TO BELOW
19.5%.
Ventilation:LOC EXHAUST AS RECOMM BY ACGIH-"INDUSTRIAL VENTILATION
MANUAL" & NIOSH"REPORT ON ENGINEERING CONTROLS OF WELDING FUMES".
Protective Gloves:LEATHER GLOVES.
Eye Protection:#4/DARKER FILTER LENS WHEN (ING 21)
Other Protective Equipment:LEATHER APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: BUT DO NOT EXTING FLAME DUE TO POSS OF EXPLOS. FIRST
AID PROC: USE HOT WATER. SEE MD IMMED IF CRYOGENIC "BURN" HAS RSLTD
IN BLISTERING OF DERMAL SURF/DEEP TISS FREEZING. EYES: NEVER I
NTRODUCE OINTMENT/OIL INTO EYES W/OUT MD ADVICE! IN CASE OF
FREEZING/CRYOGENIC "BURNS" CAUSED BY RAPIDLY EVAP (ING 3)
Waste Disposal Methods:CYLINDERS SHOULD BE VENTED TO BURNING FLARE &
DEPRESSURIZED IN OPEN REMOTE AREA. REMOVE VALVE & FUSE PLUGS &
ALLOW CYLINDER TO VENT FOR 24 HOURS. DO NOT ATTEMPT TO DISPOSE OF
WASTE/UNUSED QTYS. RETURN TO SHIPPING CNTNR PROPERLY LABELED
W/(ING 6)
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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.