| MSDS | : | FORMULASHELL PREMIUM GASOLINE | | CAS | : | 108-88-3
71-43-2
110-54-3
1634-04-4
95-63-6
110-82-7
100-41-4
91-20-3
100-42-5
1330-20-7 | | NAME | : | toluene (sara iii)
benzene (sara iii)
hexane (n-hexane)
methyl tert-butyl ether (sara iii)
pseudocumene (1,2,4-trimethylbenzene (sara iii))
cyclohexane (sara iii)
ethyl benzene (sara iii)
naphthalene (sara iii)
styrene monomer (sara iii)
alkanes, cycloalkanes, alkanes & aromatic hydrocarbons
xylenes (o-,m-,p- isomers) (sara iii)
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===================== Product Identification =====================
MSDS NAME:FORMULASHELL PREMIUM GASOLINE
NIIN:00D003327
MSDS Number: BTVTD
=== Responsible Party ===
Company:SHELL OIL COMPANY
Address:1 SHELL PLAZA
Box:2463
City:HOUSTON
State:TX
ZIP:77001
Country:US
Info Phone Num:713-241-4819
Emergency Phone Num:713-473-9461 (24 HOUR EMERGENCY)
Preparer's Name:J.C. WILLETT
CAGE:54527
=== Contractor Identification ===
Company:SHELL OIL COMPANY
Box:2463
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:800-231-6950
CAGE:54527
============= Composition/Information on Ingredients =============
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <25%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM; A2; 9394
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: <3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: <15%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:PSEUDOCUMENE (1,2,4-TRIMETHYLBENZENE (SARA III))
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9394
Name:CYCLOHEXANE (SARA III)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM, 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: <3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/125STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:NAPHTHALENE (SARA III)
CAS:91-20-3
RTECS #:QJ0525000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL; 9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:STYRENE MONOMER (SARA III)
CAS:100-42-5
RTECS #:WL3675000
Fraction by Wt: <4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:S,50PPM/100STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ALKANES, CYCLOALKANES, ALKANES & AROMATIC HYDROCARBONS
Fraction by Wt: >14%
Other REC Limits:NONE RECOMMENDED
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <25%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EXPOSURE MAY CAUSE EYE,SKIN &
RESPIRATORY TRACT IRRITATION.HARMFUL OR FATAL IF
SWALLOWED.ASPIRATION MAY CAUSE ASPIRATION PNEUMONITIS.INHALATION
MAY CAUSE CNS EFFECTS,LIVER & KIDNEY DAMAGE.CHRON IC:PROLONGED OR
REPEATED EXPOSURE MAY CAUSE CANCER; DERMATITIS.
Explanation of Carcinogenicity:IARC HAS LISTED GASOLINE VAPOR AS
POSSIBLY CARCINOGENIC (2B) TO HUMANS.
Effects of Overexposure:INHALATION MAY CAUSE EUPHORIA, LUNG IRRITATION
AND EDEMA, HEADACHE, DIZZINESS, DROWSINESS, CONVULSIONS, COMA,
CYANOSIS, GENERALIZED DEPRESSION. INGESTION MAY CAUSE GENERAL
DEPRESSION, SEDATION, RESPIR ATORY DEPRESSION, COMA.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE, AND
RESPIRATORY DISORDERS; IMPAIRED LIVER AND KIDNEY DISORDERS MAY BE
AGGRAVATED.
======================= First Aid Measures =======================
Eyes: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH
SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. FOR RESPIRATORY
DISTRESS, GIVE AIR, OXYGEN, OR CPR IF NECESSARY. INGESTION: DO NOT
INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT
ASPIRATION INTO LUNGS. GET MEDICAL ATTENTION IF REQUIRED IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL. DO NOT USE DIRECT STREAM OF WATER; PRODUCT WILL
FLOAT/REIGNITE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:DANGER EXTREMELY FLAMMABLE. VAPORS ARE
HEAVIER THAN AIR, ACCUMULATING IN LOW AREAS & TRAVELING TO DISTANT
IGNITION SOURCE & IGNITING.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. USE
NON-SPARKING TOOLS. STOP & CONTAIN SPILL. REMOVE WITH PUMP TO
SALVAGE VESSEL. ABSORB WITH INERT MATERIAL & PLACE IN NON-LEAKING
CONTAINERS FOR DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID HEAT, SPARKS, OPEN FLAMES AND
STRONG OXIDIZING AGENTS. FOR USE AS A MOTOR FUEL ONLY. DO NOT USE
AS A CLEANING SOLVENT OR OTHER NON-FUEL USES.
Other Precautions:ALL HANDLING EQUIPMENT MUST BE BONDED & GROUNDED TO
PREVENT SPARKING. DO NOT SIPHON BY MOUTH. HARMFUL OR FATAL IF
SWALLOWED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR EMERGENCY
OCCURS; USE NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR,SUPPLIED
AIR,OR SELF-CONTAINED BREATHING APPARATUS (SCBA),AS REQUIRED.USE
IAW 29 CFR 1910.134.
Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR
LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV.
Protective Gloves:NITRILE, PVA, VITON/NEOPRENE
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING TO
MINIMIZE SKIN CONTACT. EYE BATH AND SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH HANDS AFTER USE & BEFORE EATING, DRINKING,
SMOKING, OR USING TOILET. LAUNDER CONTAMINATED CLOTHES BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F2
Melt/Freeze Pt:M.P/F.P Text:-72F,-58C
Vapor Pres:7-14.5 PSI
Vapor Density:3.5
Spec Gravity:0.72-0.76
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, BRIGHT LIQUID; HYDROCARBON ODOR
Corrosion Rate:UNKNOWNU
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, SPARKS AND STRONG
OXIDIZING AGENTS. PREVENT VAPOR ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. EPA/RCRA WASTE NUMBER D001 MAY APPLY TO
UNUSED/UNCONTAMINATED PRODUCT.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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