acrylic resin acetic acid, butyl ester; (butyl acetate) (sara iii). vp: 2-butanone; (methyl ethyl ketone). vp: 71 @ 20c. quinacridone; (quinacridone pigment) pigment; (quinophthalone yellow pigment) vm&p naphtha hexane, 1,6-diisocyanato-; (1,6 hexamethylene diisocyanate) supp data: anyone w/out protection in painting area. follow efts of overexp: ing 2: may cause abnormal liver func. ing 9: inconclusive. has been tox to fetus in lab animals ing 10: rats have shown that petro distillates cause kidney ing 11: similar studies w/guinea pigs, dogs, or monkeys. ing 12: significant incr of kidney dmg/an incr in ing 13: w/cough, dfclt brthg, or shortness of brth. ing 3: ing 14: methyl ethyl ketone has been demonstrated to ing 15: neuropathy caused by either n-hexane/methyl n-butyl ing 16: cause peripheral neuropathy. liquid splashes in
MSDS NAME:CENTARI 5000 ENAMEL, 513H
NIIN:00N053244
MSDS Number: BVPPJ
=== Responsible Party ===
Company:E I DU PONT DE NEMOURS & CO
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
CAGE:B0589
=== Contractor Identification ===
Company:DU PONT E I DE NEMOURS & CO FABRICATED PROD DEPT
Address:1007 MARKET ST BRANDYWINE BLDG 3332
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-3637
CAGE:90227
Company:E I DU PONT DE NEMOURS & CO
Address:RAKETSTRAAT, 100, RUE DE LA FUSEE
City:BRUSSEL
Country:BE
Phone:32-(0)15-401.505
CAGE:B0589
============= Composition/Information on Ingredients =============
Name:EFTS OF OVEREXP: ING 2: MAY CAUSE ABNORMAL LIVER FUNC.
TESTS FOR EMBRYOTOXIC ACTIVITY IN ANIMALS HAS BEEN (ING 10)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 9: INCONCLUSIVE. HAS BEEN TOX TO FETUS IN LAB ANIMALS
AT DOSES THAT ARE TOX TO MOTHER. ING 6: LAB STUDIES W/(ING 11)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 10: RATS HAVE SHOWN THAT PETRO DISTILLATES CAUSE KIDNEY
DMG & KIDNEY/LIVER TUMORS. EFTS WERE NOT SEEN IN (ING 12)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 11: SIMILAR STUDIES W/GUINEA PIGS, DOGS, OR MONKEYS.
SEVERAL STUDIES EVALUATING PETRO WORKERS HAVE NOT SHOWN(ING 13)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 12: SIGNIFICANT INCR OF KIDNEY DMG/AN INCR IN
KIDNEY/LIVER TUMORS. MAY CAUSE TEMP UPPER RESP &/OR LUNG IRRIT(ING
14)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 13: W/COUGH, DFCLT BRTHG, OR SHORTNESS OF BRTH. ING 3:
HIGH CONC HAVE CAUSE EMBRYOTOXIC EFTS IN LAB ANIMALS.(ING 15)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 14: METHYL ETHYL KETONE HAS BEEN DEMONSTRATED TO
POTENTIATE (I.E., SHORTEN TIME OF ONSET) PERIPHERAL (ING 16)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 15: NEUROPATHY CAUSED BY EITHER N-HEXANE/METHYL N-BUTYL
KETONE. MEK BY ITSELF HAS NOT BEEN DEMONSTRATED TO (ING 17)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 16: CAUSE PERIPHERAL NEUROPATHY. LIQUID SPLASHES IN
EYES MAY RESULT IN CHEMICAL BURNS.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST: GI DISTRESS. INHAL: MAY CAUSE
NOSE & THROAT IRRIT. RPTD & PRLNGD OVEREXP TO SOLVS MAY LEAD TO
PERM BRAIN & NERV SYS DMG. EYE WATERING, HDCHS, NAUS, DIZZ & LOSS
OF COORD ARE SIGNS THAT SOLV LEV S ARE TOO HIGH. EXPOS TO
ISOCYANATES MAY CAUSE RESP SENSIT. EFT MAY BE PERM. EFT MAY BE
DELAYED FOR (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SEVERAL HRS AFTER EXPOS. RPTD OVEREXP
TO ISOCYANTES MAY CAUSE DECREASE IN LUNG FUNC WHICH MAY BE PERM.
INDIVS W/BRTHG PROBLEMS/PRIOR RXN TO ISOCYANTES MUST NOT BE EXPOS
TO VAPS/SPRAY MIST OF PROD. SKIN/EYE: MAY CAUSE IRRIT/BURNING OF
EYES. RPTD/PRLNGD LIQ CONT MAY CAUSE SKIN IRRIT W/DISCOMFORT &
DERM. (ING 9)
Medical Cond Aggravated by Exposure:PRE-EXISTING BREATHING
PROBLEMS/PRIOR ISOCYANATE REACTION.
======================= First Aid Measures =======================
First Aid:INGESTION: CALL PHYSICIAN IMMEDIATELY AND HAVE NAMES OF
INGREDIENTS AVAILABLE. INHALATION: REMOVE TO FRESH AIR. IF
BREATHING DIFFICULTY PERSISTS, OR OCCURS LATER, CONSULT PHYSICIAN.
EYE: IMMEDIATELY F LUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES; CALL PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. IF
IRRITATION OCCURS, CONTACT PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:100F,38C
Lower Limits:0.9%
Upper Limits:23%
Extinguishing Media:WATER SPRAY, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL
CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS
FLAMMABLE VAPS WHICH, WHEN MIXED W/AIR, CAN BURN OR BE EXPLOSIVE.
FINE MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW FLASHPOINT.
Spill Release Procedures:DO NOT BRTH VAPS. DO NOT GET IN EYES/ON SKIN.
WEAR NIOSH/MSHA APPRVD POS PRESS SUPP AIR VAP/PARTICULATE RESP
(NIOSH/MSHA TC-19C),EYE PROT, GLOVES & PROT MATLS.REMOVE SOURCES OF
IGNIT. ABSORB W/INERT M ATL. VENT AREA.POUR LIQ DECONTAMINATE
SOLN(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING.
Other Precautions:DO NOT STORE ABOVE 120F. DO NOT SAND, FLAME CUT,
BRAZE OR WELD DRY COATING WITHOUT A NIOSH/MSHA APPROVED RESPIRATOR
OR APPROPRIATE VENTILATION.
Respiratory Protection:DO NOT BRTH VAPS/MISTS. WEAR NIOSH/MSHA APPRVD
POS PRESS SUPP AIR RESP (NIOSH/MSHA (TC-19C) WHILE MIXING ACTIVATOR
W/ANY PAINT/CLEAR ENAMEL, DURING APPLIC & UNTIL ALL VAPS & SPRAY
MISTS ARE EXHAUSTED. INDIVS W/HISTORY OF LUNG/BRTHG (SUPDAT)
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGG .
Other Protective Equipment:NEOPRENE COVERALLS ARE RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
% VOLAT: 7.3-100% (VOL); 6.34%-100% (WT). SPILL PROC: OVER SPILL &
ALLOW TO SIT 10 MINS, MIN. TYPICAL DECONTAMINATION SOLNS ARE: 20%
SURFACTANT (TERGITOL TMN 10) & 80% WATER;OR 0-10% AMMONIA, 2-5% DET
ERGENT, BALANCE WATER. RESP PROT: PROBLEMS/PRIOR RXN TO ISOCYANATE
SHOULD NOT USE/BE EXPOS TO PROD. DO NOT PERMIT(ING 8)
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS. DISP I/A/W FED ERAL, STATE AND LOCAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.