msds toxicity property">
4-vinyl cyclohexene; (4-vinylcyclohexene) % wt: <500 ppm 1,3-butadiene (sara iii) % wt: <5 ppm supdat: term (2 yr) studies on efts of oral admin of vch to ing 4: among the male & female rats & male mice that ntp ing 5: an incr in ovarian tumors was observed in female ing 6: induced ovarian efts is demonstrated by their ing 7: metabolite, vch-1,2-epoxide. no efts were seen on ing 8: vch orally. reduction in body wts & numbers of ing 9: tests using bacterial cells. vent: to draw dusts & fumes from worker brthg zones. ing 11: "industrial ventilation, a manual of recommended msds toxicity property">
MSDS
:
POLY BD R-45 HT RESIN, S01102
CAS
:
69102-90-5 100-40-3 106-99-0
NAME
:
hydroxy terminated 1,3-butadiene homopolymer 4-vinyl cyclohexene; (4-vinylcyclohexene) % wt: <500 ppm 1,3-butadiene (sara iii) % wt: <5 ppm supdat: term (2 yr) studies on efts of oral admin of vch to ing 4: among the male & female rats & male mice that ntp ing 5: an incr in ovarian tumors was observed in female ing 6: induced ovarian efts is demonstrated by their ing 7: metabolite, vch-1,2-epoxide. no efts were seen on ing 8: vch orally. reduction in body wts & numbers of ing 9: tests using bacterial cells. vent: to draw dusts & fumes from worker brthg zones. ing 11: "industrial ventilation, a manual of recommended
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES:DIRECT CTNCT/VAPS MAY CAUSE
SLIGHT IRRIT. SKIN:LIQ MAY CAUSE SLIGHT IRRIT. INGEST/INHAL:NO DATA
CONCERNING ACUTE HLTH EFTS HAS BEEN IDENTIFED. CHRONIC:NO EFTS FROM
CHRONIC EXPOS ARE KNOWN. THIS P ROD CNTNS TRACE AMTS OF ODOROUS
MATL IDENTIFIED AS 4-VINYLCYCLOHEXENE (VCH). UNDER AGRESSIVE CNDTNS
OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: PHYSICAL HNDLG OR W/HEATING, THERE IS
POTNTL FOR RELS OF VCH AT CONCS NEAR ACGIH TLV-TWA OF 0.1 PPM. IN
RUSSIAN WORKERS EXPOSED TO HIGH VCH CONCS (271-677 PPM), EYE & NOSE
IRRIT, HDCH, SOME WHITE BLOOD CELL REDUCTIONS & IMPAIRED
CARBOHYDRATE METABOLISM WERE REPORTED. RPTD ADMIN OF VCH TO RATS &
MICE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
Eyes: IMMED FLUSH W/FLOWING WATER FOR AT LEAST 15 MIN. SEE MD
IF IRRIT PERSISTS. SKIN: REMOVE CONTAMD CLTHG & WASH EXPOSED SKIN
W/LG AMTS OF WATER. SEE MD IF IRRIT PERSISTS. INGEST: NO HARMFUL
EFTS AN TIC IF PWDR IS SWALLOWED. SEE MD IF IRRIT PERSISTS. INHAL:
NO HARMFUL EFTS ARE ANTIC FROM BRTHG LOW CONC OF VAPS. IF PROBLEM
DEVELOPS, REMOVE TO FRESH AIR & SUPPLY OXYGEN IF NECESSARY.
===================== Fire Fighting Measures =====================
Flash Point Method:OC
Flash Point:>400F,>204C
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MOVE CNTNR FROM FIRE AREA IF POSS. COOL
FIRE EXPOSED CNTNRS W/WATER WELL AFTER FIRE IS OUT TO PVNT POSS
EXPLOS. HEAT FROM FIRE CAN GENERATE A FLAMM VAP (SUPDAT)
Spill Release Procedures:VENTILATE AREA & REMOVE ALL IGNITION SOURCES.
CONTAIN SPILL BY BUILDING A DIKE USING ABSORBENT MATERIAL. COLLECT
REMAINDER OF SPILL WITH ABSORBENT MATERIAL & PLACE MATERIAL INTO
DRUM APPROVED FOR WAST E DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:MINIMIZE VAPORIZATION BY SEALING IN A
TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, WELL-VENTILATED
AREA.
Other Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND STRONG
OXIDIZING AGENTS. PROTECT FROM FREEZING. IF FROZEN, THAW AND MIX
THOROUGHLY BEFORE USE. AVOID OVERHEATING. AVOID SKIN AND EYE
CONTACT.
Respiratory Protection:FOR CNDTNS WHERE EXPOS TO DUST & FUMES IS
APPARENT, A NIOSH/MSHA APPRVD RESP FOR DUST MISTS & FUMES APPROP TO
AIRBORNE CONC MAY BE WORN. WHERE VAPS ARE GENERATED, A NIOSH/MSHA
APPRVD ORGANIC RESP SUIT ABLE TO AIRBORNE CONCS IS RECOM.
Ventilation:PROVIDE LOC EXHST VENT WHERE HEAT CAN CAUSE POLYMER
BREAKDOWN, E.G. EXTRUSION, MOLDING & WHERE THERE IS A NEED (ING 11)
Protective Gloves:USE NITRILE (NBR) OR NATURAL RUBBER.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:WEAR IMPERVIOUS BODY COVERING AND BOOTS
WHERE SPILLS OR SPLASHING OCCUR.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: THAT IS HVR/AIR. EFTS OF OVEREXP: BY INHAL (4 MOS) WAS
REPORTED TO PRDCE SOME WHITE BLOOD CELL REDUCTIONS & TO EFT BLOOD
CIRCULATION, WHILE RPTD ORAL DOSING (3 MO) OF RATS & MICE PRDCED
KID NEY TOX IN MALE RATS & OVARIAN EFTS IN FEMALE MICE AT DOSE THAT
PRDCED MANY ANIMAL DEATHS. NTP CONDUCTED LONG- (ING 4)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, OPEN FLAME, PROLONGED STORAGE AT
ELEVATED TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF CARBON AND BUTADIENE.
Waste Disposal Methods:DISPOSE OF SOLID WASTE AT PROPERLY PERMITTED
LANDFILLS OBSERVING ALL LOCAL, STATE & FEDERAL REGS. CONTAMINATED
LIQUIDS SHOULD BE CONCENTRATED & INCINERATED AT A PROPERLY
PERMITTED DISPOSAL SITE AGAIN OBSERVING ALL LOCAL, STATE & FEDERAL
REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.