===================== Product Identification =====================
MSDS NAME:LEAD-ACID BATTERY
NIIN:01-031-6876
MSDS Number: BYDKB
=== Responsible Party ===
Company:EXIDE CORP
Address:9176 RED BRANCH RD
City:COLUMBIA
State:MD
ZIP:21045-2059
Country:US
Info Phone Num:301-381-8500
Emergency Phone Num:301-381-8500 OR 215-378-0757
CAGE:90660
=== Contractor Identification ===
Company:BATTERY OUTLET INC
Address:1608 CAMPOSTELLA RD
Box:City:CHESAPEAKE
State:VA
ZIP:23324
Country:US
Phone:757-545-4442
CAGE:0FGN2
Company:ENERSYS INC
Address:8306PATUXENT RANGE RS SUITE 103
Box:City:JESSUP
State:MD
ZIP:20794-8609
Country:US
Phone:301-381-8500 OR 215-378-0757
CAGE:90660
Company:EXIDE CORP
Address:645 PENN STREET
Box:14205
City:READING
State:PA
ZIP:19612-4205
Country:US
Phone:610-378-0500/0798
CAGE:20038
Company:YUASA EXIDE INC
Address:257 SPRING VALLEY RD
Box:City:LAURELDALE
State:PA
ZIP:19605
Country:US
Phone:215-921-4480
CAGE:0RN21
============= Composition/Information on Ingredients =============
Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 60%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1025
ACGIH TLV:0.15 MG/M3,DUST;9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ANTIMONY (SARA III)
CAS:7440-36-0
RTECS #:CC4025000
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG (SB)/M3; 9394
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ARSENIC (SARA III)
CAS:7440-38-2
RTECS #:CG0525000
Fraction by Wt: 0.2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1018
ACGIH TLV:0.01 MG/M3, A1; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:CALCIUM
CAS:7440-70-2
RTECS #:EV8040000
Fraction by Wt: 0.2%
Other REC Limits:NONE RECOMMENDED
Name:TIN
CAS:7440-31-5
RTECS #:XP7320000
Fraction by Wt: 0.2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9394
Name:SULFURIC ACID (SARA III) (ELECTROLYTE)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 10-30%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:PROPENE POLYMERS (POLYPROPPYLENE)
CAS:9003-07-4
RTECS #:UD1842000
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:POLYSTYRENE
CAS:9003-53-6
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:STYRENE ACRYLONITRILE
CAS:9003-54-7
RTECS #:AT6978000
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:ACRYLONITRILE BUTADIENE STYRENE
CAS:9003-56-9
RTECS #:AT6970000
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:STYRENE BUTADIENE
CAS:9003-55-8
RTECS #:WL6478000
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:POLYVINYL CHLORIDE
CAS:9002-86-2
RTECS #:KV0350000
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:POLYCARBONATE
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:HARD RUBBER
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:POLYETHYLENE
CAS:9002-88-4
RTECS #:TQ3325000
Fraction by Wt: SEE #16%
Other REC Limits:NONE RECOMMENDED
Name:CASE MATERIAL, TOTAL OF INGREDIENTS #7 THRU 15.
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
Name:SILICON DIOXIDE (GEL BATTERIES ONLY) (SEE INGRED #19)
CAS:60676-86-0
RTECS #:VV7328000
Fraction by Wt: 10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 RDUST; Z-3
ACGIH TLV:0.1 MG/M3 RDUST;9394
Name:SHEET MOLDING COMPOUND (GLASS-REINFORCED POLYESTER) (SEE
INGRED #19)
Fraction by Wt: 10%
Other REC Limits:NONE RECOMMENDED
Name:OTHER(INORG PB & ELECTROLYTE PRIM CMPNTS OF EVERY BATTERY
MFG BY YUASA-EXIDE.OTHER INGRED MAY BE PRESENT DEPENDS ON TYP)
RTECS #:9999999ZZ
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT KNOWN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:H2SO4:INHAL:SEVER RESP
IRRIT.INGEST:IRRT MOUTH/THROAT/ESOPHAGUS/STOMACH.SKIN/EYE:SEVE
IRRIT,BURNS,ULCERATION,BURNS, CORNEA DAMAGE,BLINDNESS.PB
CMPDS:INHAL:IRRT UPPER RESP TRACT & LUNGS. INGEST:SYS TOX
ICITY.EYE:IRRIT.CHRONIC:TOOTH ENAMEL,INFLAMM OF NOSE/THROAT/
BRONCHIAL TUBES.ANEMIA,NEUROPATHY(MOTOR NERVES)KID/REPROD D
Explanation of Carcinogenicity:PER MSDS:H2SO4 MIST FROM MISUSE OF
PRODUCT. LEAD CMPDS. ARSENIC.
Effects of Overexposure:SKIN IRRIT, DAMAGE TO CORNEA, UPPER RESP IRRIT.
SYMPTOMS OF TOXICITY OF LEAD CMPDS WHEN PRODUCT HEATED, OXIDIZED OR
OTHERWISE PROCESSED OR DAMAGED TO CREATE DUST/VAPOR/FUME:HEADACHE,
FATIGUE, ABDOMINA L PAIN, LOSS OF APPETITE, MUSCULAR ACHES &
WEAKNESS, SLEEP DISTURBANCES & IRRITABILITY.
Medical Cond Aggravated by Exposure:OVEREXPOSURE TO H2SO4 MIST MAY
CAUSE LUNG DAM,AGGRAVATE PULM CONDITIONS.H2SO4 CONTACT W/SKIN MAY
AGGRAVATE SKIN DISEASES(ECZEMA & CONTACT DERM).PB & CMPDS CAN
AGGRAVATE SOME FORMS OF KID/ LIV/NEURO DI
======================= First Aid Measures =======================
First Aid:INHAL:ACID:REMOVE TO FRESH AIR IMMED. IF BREATH DIFFI GIVE
OXY.PB:GARGLE,WASH NOSE/LIPS.CALL DR.INGEST:ACID:GIVE LG QUANTITIES
OF H2O.DON'T INDUCE VOMIT.CALL DR.SKIN:ACID:FLUSH W/LOTS AMTS OF
H2O FOR @ LEAST 15MINS.REMOVE CONTAMIN CLOTH/SHOE.PB:WASH IMMED
W/SOAP & WATER.EYE:ACID/PB:FLUSH IMMED W/LG AMTS OF H2O FOR @ LEAST
15MINS.SEE DR.
===================== Fire Fighting Measures =====================
Lower Limits:4.1 H2 GAS
Upper Limits:74.2
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:IF BATTERIES ARE ON CHARGE, SHUT OFF POWER.
USE + PRES SCBA. WATER APPLIED TO ELECTROLYTE GENERATES HEAT &
CASUES IT TO SPATTER. WEAR ACID-RESISTANT CLOTHING.
Unusual Fire/Explosion Hazard:HIGHLY FLAMM H2 GAS GENERATED DURING
CHARG/ OPER OF BATTERY.KEEP SPARKS OR OTHER SOURCES OF IGN
AWAY.DON'T ALLOW METALLIC MATLS TO CONTACT -/+ TERMINALS.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW.CONTAIN/ABSORB SM SPILLS W/DRY
SAND,EARTH,VERMI.DON'T USE COMBUST MATLS.CAREFULLY NEUTRALIZE
ELECTROLYTE W/SODA ASH,SODIUM BICARBONATE,LIME,ETC.WEAR
ACID-RESISTANT CLOTH,BOOT,GLOV, FACESHIEL D.DON'T ALLOW DISCHARGE
OF UNTREATED ACID TO SEWER
Neutralizing Agent:SODA ASH, SODIUM BICARBONATE, LIME.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE BATTERIES IN COOL,DRY,WELL-VENTI
AREAS W/IMPERVIOU SURFACES & ADEQUATE CONTAINMENT IN EVENT OF
SPILLS.SEPARATE FROM INCOMP MATLS,SPARKS,HEAT,FIR
Other Precautions:BATTERIES SHOULD ALSO BE STORED UNDER ROOF FOR
PROTECTION AGAINST ADVERSE WEATHER CONDITIONS.STORE & HANDLE ONLY
IN AREAS W/ADEQUATE H2O SUPPLY & SPILL CONTROL.AVOID DAMAGE TO
CONTAINERS.FOLLOW MFG'S INSTRUCTIONS FOR INSTALLATION & SERVICE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITONS. WHEN
CONCENTRATION OF H2SO4 MIST ARE KNOWN TO EXCEED PEL USE NIOSH OR
MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:STORE & HANDLE IN WELL-VENTILATED AREA. IF MECHANICAL
VENTILATION IS USED COMPONENTS MUST BE ACID-RESISTANT.
Protective Gloves:RUB,PLASTIC ACID RESISTANT W/ELBOW LENGT
Eye Protection:CHEMNICAL GOGGLES OR FACE SHIELD.
Other Protective Equipment:ACID-RESIS APRON.UNDER SEVERE EXPOSURE OR
EMERG CONDITIONS WEAR ACID-RESIS CLOTH/BOOTS.EYEWASH & SHOWERS
W/UNLIM H2O SUP
Work Hygienic Practices:HANDLE CAUTIOUSLY TO AVID SPILLS.MAKE CERTAIN
VENT CAPS ON SECURLEY.AVOID CONTACT W/INTERNAL COMPONENTS.
Supplemental Safety and Health
CONSULT STATE ENVIRONEMNTAL AGENCY &/OR FED EPA FOR DISPOSAL. WEAR
PROTECTIVE CLOTHING WHEN FILLING OR HANDLING BATTERIES.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:203F,95C
Vapor Pres:10
Vapor Density:>1
Spec Gravity:1.215-1.350
Evaporation Rate & Reference:<1, BUAC=1
Solubility in Water:COMPLETE, ELECTROLYT
Appearance and Odor:ARTICLE;NO APPARENT ODOR.ELECTROLYTE:CLEAR LIQ W/
SHARP,PENETRATING PUNGENT ODO
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRG REDUCING AGENTS;METALS(SO2,H2);SO3;STRG OXIDIZERS;H2O;STR
ACIDS,BASES,HALIDES,HALOGENATES,KNO3,NASCENT H,PERM PEROX
Stability Condition to Avoid:PROLONGED OVERCHARGE, SOURCES OF IGNITION.
Hazardous Decomposition Products:SO3,CO,H2SO4 MIST,SO2,H2.TOXIC METAL
FUME/ VAPOR/DUST.ARSINE GAS FROM CONTACT W/STRONG OR BASE OR
PRESENCE OF NASCENT H2
==================== Disposal Considerations ====================
Waste Disposal Methods:SEND SPENT BATTERIES TO SECONDARY LEAD SMELTER
FOR RECYCLING.NEUTRALIZED SLURRY INTO SEALED CONTAINERS & DISPOSE
OF AS HAZ WASTE AS APPLICABLE.LG H2O-DILUTED SPILLS AFT
NEUTRALIZATION & TESTING SHOULD BE MANAGED IAW APPROVED
LOC/STA/FED REQMTS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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