===================== Product Identification =====================
MSDS NAME:PLLA2-3X 10,000 PPM OF LANTHANUM IN 5% NITRIC ACID
NIIN:00F042977
MSDS Number: CCZRB
=== Responsible Party ===
Company:SPEX INDUSTRIES/INSTRUMENTS INC
Address:3880 PARK AVE
City:EDISON
State:NJ
ZIP:08820-3012
Country:US
Info Phone Num:800-522-7739/908-549-7144
Emergency Phone Num:800-522-7739/908-549-7144
Preparer's Name:VANAJA SIVAKUMAR
CAGE:FO447
=== Contractor Identification ===
Company:SPEX CERTIPREP INC
Address:203 NORCROSS AVE
Box:City:METUCHEN
State:NJ
ZIP:08840
Country:US
Phone:732-549-7144
CAGE:07977
Company:SPEX INDUSTRIES/INSTRUMENTS INC
Address:3880 PARK AVE
City:EDISON
State:NJ
ZIP:08820-3012
Country:US
Phone:800-522-7739/908-549-7144
CAGE:FO447
============= Composition/Information on Ingredients =============
Name:NITRIC ACID, HYDROGEN NITRATE *96-4*
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: 2-5%
OSHA PEL:5 MG/CUM
ACGIH TLV:5.2 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:LANTHANUM OXIDE *96-4*
CAS:1312-81-8
Fraction by Wt: 0.1-1%
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 90-97%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED, INGESTED/CONTACTED
W/SKIN & EYES. LANTHANUM-ANTICOAGULANT EFFECTS ON THE BLOOD.
CONCENTRATED NITRIC ACID-FATAL IF INHALED/ABSORBED THROUGH THE
SKIN. IRRITATION TO EYES, MUCOUS MEMB RANES & SKIN. SKIN:
PENETRATING BURNS. INGESTION: BURNS OF THE MOUTH, ESOPHAGUS & GI
TRACT. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, VISUAL IMPAIRMENT, BURNS, DEEP
ULCERS, STAIN, TEETH EROSION, INFLAMMATION, BURNING SENSATION,
COUGH, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA,
VOMITING.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO
FRESH AIR. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, GIVE
LARGE QUANTITIES OF MILK. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING AREAS.
Fire Fighting Procedures:CONCENTRATED NITRIC ACID REACTS EXPLOSIVELY
W/COMBUSTIBLE ORGANIC/READILY OXIDIZABLE MATERIALS.
Unusual Fire/Explosion Hazard:ELEVATED TEMP MAY CAUSE CONTAINERS TO
BURST & LIBERATE TOXIC OXIDES OF NITROGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. DILUTE W/WATER & NEUTRALIZE
W/SODA ASH, LIMESTONE. WIPE UP & PUT INTO A SEALED CONTAINER FOR
PROPER DISPOSAL. WASH SITE OFF W/WATER AFTER MATERIAL PICK UP IS
COMPLETE. WEAR CHEMICAL RE SISTANT GLASSES, GLOVES & CLOTHING. (SEE
SUPP)
Neutralizing Agent:SODA ASH, LIMESTONE
====================== Handling and Storage ======================
Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMP. KEEP
TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:AVOID INHALATION, INGESTION & CONTACT W/EYES & SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD.
Protective Gloves:REQUIRED
Eye Protection:GOGGLES
Other Protective Equipment:LAB COAT, EYE WASH STATION.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
HEALTH HAZARDS CONT'D: INHALATION: FATAL CAUSING SPASM, EDEMA OF THE
LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA. SPILLS
CONT'D: WEAR NIOSH/MSHA APPROVED RESPIRATOR.
================== Physical/Chemical Properties ==================
Spec Gravity:1
Solubility in Water:COMPLETE
Appearance and Odor:TRANSPARENT W/ACRID ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYDROGEN SULFIDE, STRONG
BASES.
Stability Condition to Avoid:ELEVATED TEMP
Hazardous Decomposition Products:NITROGEN OXIDES FUMES & VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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