===================== Product Identification =====================
MSDS NAME:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE,T-180
NIIN:01-325-5586
MSDS Number: CDZYX
=== Responsible Party ===
Company:FISHER SCIENTIFIC, CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100/703-527-3887 INTERNAT.
Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC
Box:UNKNOW
CAGE:26370
Company:FISHER SCIENTIFIC CO
Address:2000 PARK LN
Box:City:PITTSBURGH
State:PA
ZIP:15275
Country:US
Phone:412-490-8586
CAGE:22527
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA
313)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000PPM/1250STEL; 96
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 43,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:HEART, CENTRAL NERVOUS
SYSTEM. ACUTE- EYES/SKIN:MAY CAUSE IRRITATION, PAIN.
INHALE:OVEREXPOSURE MAY CAUSE ASPHYXIATION, CNS & NARCOTIC EFFECTS,
HEART DISTURBANCES, POSSIBLY LEADING TO DE ATH. ORAL:MAY CAUSE
GASTROINTESTINAL TRACT IRRITATION. CHRONIC- MAY CAUSE DRY SKIN &
DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, ABDOMINAL PAIN,
HEADACHE, DROWSINESS, DIZZINESS, TEARING, BLURRED VISION, DRYNESS
OF SKIN, DERMATITIS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED CNS, HEART OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:IF
CONSCI OUS, DRINK 2-4 CUPFULS OF MILK/WATER. GET MEDICAL ATTENTION
IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SMALL FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:CONCENTRATED VAPORS MAY BE IGNITED BY
HIGH INTENSITY IGNITION SOURCE. MAY FORM HIGHLY TOXIC AND
IRRITATING GASES. CONTAINER MAY RUPTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. REMOVE OPEN FLAMES.
VENTILATE AREA. STOP LEAK IF POSSIBLE. ABSORB SPILLS WITH INERT
MATERIAL SUCH AS SAND/VERMICULITE OR USE PUMP. PLACE IN SUITABLE
CONTAINERS FOR DISPOSAL OR RECYCLING. DO NOT FLUSH TO SEWER OR
WATERWAYS.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, VENTILATED PLACE
AWAY FROM OPEN FLAMES AND INCOMPATIBLES. KEEP CONTAINER TIGHTLY
CLOSED. DO NOT STORE IN ALUMINUM CONTAIENRS.
Other Precautions:VAPORS HEAVIER THAN AIR AND WILL COLLECT IN LOW
AREAS. WEAR RESPIRATOR BEFORE ENETERING LOW AREAS. DO NOT CUT OR
WELD ON EMPTY OR FULL CONTAINERS. WASH THOROUGHLY AFTER HANDLING
AND BEFORE EATING, DRI NKING. KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NORMALLY NOT REQUIRED. WEAR NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS IF A LARGE SPILL OCCURS.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:VITON, POLYVINYL ALCOHOL(REPEAT CONTACT)
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
NOTE TO PHYSICIAN: CHLORINATED SOLVENT. INCREASED CARDIAC SENSITIVITY
AND POSSIBLE ARRHYTHMIA MAY RESULT FROM OVEREXPOSURE. DO NOT
ADMINISTER EPINEPHRINE OR OTHER STIMULATING DRUGS FOLLOWING
OVEREXPOS URE UNLESS ABSOLUTELY NECESSARY. NO SPECIFIC ANTIDOTE.
SUPPORTIVE CARE. TREATMENT BASED ON DOCTOR'S JUDGEMENT.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:55.8F,13.2C
Vapor Pres:273 @ 68F
Vapor Density:6
Spec Gravity:1.6
Evaporation Rate & Reference:0.45 (ACETONE=1)
Solubility in Water:0.028%
Appearance and Odor:COLORLESS LIQUID - SLIGHT ETHEREAL ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI, ALKALINE EARTH METALS, POWDER OF ALUMINUM, ZINC, BERYLLIUM,
MAGNESIUM, PLASTIC, RUBBER, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:OPEN FLAME, ELECTRIC ARCS, HOT SURFACES
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CARBON MONOXIDE,
CARBON DIOXIDE, CHLORINE, FLUORINE, HYDROGEN FLUORIDE, CARBONYL
HALIDE MAY BE FORMED
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. AVOID CONTAMINATION OF GROUND AND SURFACE
WATER.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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