===================== Product Identification =====================
MSDS NAME:L2129 (+)-LIMONENE
NIIN:00F054090
MSDS Number: CFGLS
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:-1-METHYL-4-(1-METHYLETHENYL)CYCLOHEXENE, CARVENE, CINENE,
D-LIMONE (ANIMAL LIMITED EVIDENCE, NTP & IARC GROUP 3) *97-2*
CAS:5989-27-5
RTECS #:GW6360000
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 4400 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL BY INGESTION, INHALATION/SKIN
ABSORPTION. MAY CAUSE EYE, MUCOUS MEMBRANES, UPPER RESPIRATORY
TRACT & SKIN IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, ALLERGIC SKIN REACTION, NAUSEA,
VOMITING, DIARRHEA.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NEEDED. INGESTION: IF CONSCIOUS, WASH MOUTH OUT W/WATER. OBTAIN
MEDICAL ATTENTI ON IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:119F
Lower Limits:0.7
Upper Limits:6.1
Extinguishing Media:CO2, DRY CHEMICAL POWDER, APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR A SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. VAPOR MAY TRAVEL TO DISTANT
IGNITION SOURCE & FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR A SCBA, RUBBER BOOTS &
HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS & DISCARD THEM AFTER
USE. ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR
DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS
COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
TIGHTLY CLOSED. KEEP AWAY FROM HEAT & OPEN FLAME. DON'T BREATHE
VAPOR. DON'T GET IN EYES, ON SKIN/CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:SAFETY SHOWER & EYE BATH
Work Hygienic Practices:REMOVE & DISCARD CONTAMINATED CLOTHING & SHOES.
WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:347.9-349F
Vapor Pres:<3
Vapor Density:4.7
Spec Gravity:0.84
Appearance and Odor:LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, OPEN FLAME & OTHER IGNITION SOURCES.
Hazardous Decomposition Products:CO & CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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