=====================  Product Identification  =====================

MSDS NAME:33628-9 TITANUUM BROMIDE,POWDER, CA 10 MICRON
NIIN:01-446-5219
MSDS Number: CFLHR
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO INC./SUB OF SIGMA-ALDRICH CORP
Address:1001 W. ST. PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Country:US
Info Phone Num:414-273-3850/FAX -4979
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928

=============  Composition/Information on Ingredients  =============

Name:TITANIUM BORIDE
CAS:12045-63-5
Other REC Limits:NONE RECOMMENDED

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHAL/INGEST/SKIN
    ABSORTPION.MAY CAUSE EYE IRRIT.MAY CAUSE SKIN IRRIT.TO THE BEST OF
    OUR KNOWLEDGE CHEM/PHSY/TOXICOLOGICAL PROPERTIES HAVE NOT BEEN
    THOROUGHLY INVESTIGATED.
Effects of Overexposure:HARMFUL BY INHAL/INGEST/SKIN
    ABSORPTION.EYE/SKIN IRRIT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:IN CASES OF CONTACT IMMED FLUSH EYES W/COPIOUS AMTS OF WATER
    FOR @LEAST 15MINS.IN CASE OF CONTACT IMMED WASH SKIN W/SOAP &
    COPIOUS AMTS OF WATER.IF INHAL REMOVE TO FRESH AIR.IF NOT BREATHING
    GIVE ARTI FICIAL RESPIRATION.IF BREATHING IS DIFFICULT GIVE
    OXYGEN.IF SWALLOWED WASH OUT MOUTH W/WATER PROVIDED PERSON IS
    CONSC.CALL PHYSICIAN.

=====================  Fire Fighting Measures  =====================

Flash Point:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
    FOAM,WATER SPRAY.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
    PROTECTIVE CLOTHING TO PREVENT CONTCT W/SKIN/EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR RESPIRATOR,CHEM SAF GOGGLES,RUBBER BOOTS
    & HEAVY RUBBER GLOVES.SWEEP UP PLACE IN BAG & HOLD FOR WASTE
    DISPOSAL.AVOD RAISING DUST.VENTILATE AREA & WASH SPILL SITE AFTER
    MATERIAL PICKUP IS COMPLETE .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID INHAL.AVOID CONTACT
    W/EYE/SKIN/CLOTHING.AVOID PROL/REP EXPO.HARMFUL SOLID.KEEP TIGHTLY
    CLOSED.STORE IN COOL DRY PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEM-RESISTANT GLOVES
Eye Protection:CHEM SAFETY GOGGLES
Other Protective Equipment:SAFETY SHOWER & EYE BATH.
Work Hygienic Practices:WASH CONTAM CLOTH BEFORE REUSE.WASH THOROUGHLY
    AFTER HNDLG.
Supplemental Safety and Health

==================  Physical/Chemical Properties  ==================

HCC:N1
Boiling Pt:B.P. Text:NP
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:NP
Vapor Density:NP
Spec Gravity:4.520
pH:NP
Evaporation Rate & Reference:NP
Solubility in Water:NP
Appearance and Odor:GREY POWDER
Percent Volatiles by Volume:NP
Corrosion Rate:NP

=================  Stability and Reactivity Data  =================

STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TITIANIUM/ITITANIUM OXIDES,BORON
    OXIDES

====================  Disposal Considerations  ====================

Waste Disposal Methods:OBSERVE ALL LOCAL, STATE AND FEDERAL ENVIRO
    REGULATIONS.BURY IN LANDFILL SITE APPROVED FOR DISPOSAL OF CHEMICAL
    & HAZARDOUS WASTES.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***