===================== Product Identification =====================
MSDS NAME:BARIUM CHROMATE
NIIN:00N012831
Status Code:A
MSDS Number: CHWCW
=== Responsible Party ===
Company:BARIUM AND CHEMICALS INC
Address:COUNTY RD 44
City:STEUBENVILLE
State:OH
ZIP:43952
Country:US
Info Phone Num:614-282-9776
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:20865
=== Contractor Identification ===
Company:BARIUM AND CHEMICALS INC
Address:COUNTY RD 44
Box:218
City:STEUBENVILLE
State:OH
ZIP:43952
Country:US
Phone:740-282-9776
CAGE:20865
============= Composition/Information on Ingredients =============
Name:BARIUM CHROMATE; (BARIUM COMPOUNDS)
CAS:10294-40-3
RTECS #:CQ8760000
OSHA PEL:0.5 MG/M3 (CR)
ACGIH TLV:0.5 MG/M3 (CR)
Name:BARIUM (SARA 313)
CAS:7440-39-3
RTECS #:CQ8370000
Fraction by Wt: 54.2%
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG/M3 (BA) (MFR)
Name:CHROMIUM (SARA 313) (CERCLA)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 39.5%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:SYMPS OF EXPOS:VOMIT, VIOLENT
DIARR, ABDOM PAIN, DFCLTY IN BRTHG, SLOW PULSE & IRREG HEARTBEAT.
MAY CAUSE BLEEDING & ULCERATION OF NASAL SEPTUM, SORE THROAT, COUGH
& POSS LIVER DMG. IN LG DOSES WILL CAUSE CARD & RESP FAILURE &
HEMORRS IN GI TRACT & KIDNEYS. SKIN/EYE CONT:IRRIT. CAL PROP
65:BARIUM(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BARIUM CHROMATE:IARC MONOGRAPHS, VOL 49,
PG 49, 1990:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE
CARCIN.
Effects of Overexposure:HLTH HAZ:CHROMATE CONTAINS HEXAVALENT CHROMIUM.
HEXAVALENT CHROMIUM IS ON CALIFORNIA GOVERNOR'S LIST, "CHEMS KNOWN
TO CAUSE CANCER/REPRO TOX". USE CARE WHEN HNDLG THIS CHEM.
TOX:WORKERS MAY EXPER INCR INCIDENCE OF LUNG CANCER. POISONING MAY
AFFECT BLOOD, CNS, LIVER & KIDNEYS. MATL IS CARCINOGENIC.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN
PROBLEMS.
======================= First Aid Measures =======================
First Aid:INHAL:MOVE VICTIM TO FRESH AIR, IF VICTIM HAS DFCLTY BRTHG
GIVE OXYG. IF VICTIM HAS STOPPED BRTHG GIVE ARTF RESP & CALL FOR
PROMPT MED ATTN. SKIN:REMOVE CONTAM CLTHG & WASH CONT POINTS THORO
W/SOAP & WATER. WASH CONTAM CLTHG BEFORE REUSE. EYES:HOLD LIDS
OPEN & FLUSH W/CLEAN WATER FOR AT LST 15 MINS. GET PROMPT MED ATTN.
INGEST:CALL FOR PROMPT MED ATTN. REMOVE CHROMATES FROM STOM BY
GASTRIC LAVAGE.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE OR WATER SPRAY. LARGER
FIRES; USE FOG.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . IN
STOR AREA USE UNMANNED HOSE HOLDER & W/DRAW FROM AREA UNTIL FIRE IS
OUT. RUNOFF IS TOX; AVOID CONT & (SUPDAT)
Unusual Fire/Explosion Hazard:NON-FLAMMABLE. REDUCING AGENTS MAY REACT
VIOLENTLY. RUNOFF AND WASTE ARE TOXIC, PREVENT FROM ENTERING
NATURAL WATERWAYS.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP COMBUSTIBLES AWAY FROM SPILLED MATL.
SHOVEL UP SPILLED MATL INTO CLEAN DRY CONTAINERS & COVER. REMOVE
CONTAINERS FROM SPILL AREA. RUNOFF & WASTE ARE TOXIC, PREVENT FROM
ENTERING NATURAL WATERWAYS .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT W/REDUCING AGENTS.
PREVENT CONTACT W/SKIN. PREVENT RUNOFF FROM SPILL OR FIRE FROM
REACHING NATURAL WATERWAYS.
Other Precautions:NON-FLAMMABLE. REDUCING AGENTS MAY REACT VIOLENTLY.
KEEP AWAY FROM FOODS. USE CARE WHEN HANDLING THIS CHEMICAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED HIGH EFFICIENCY PARTICULATE
RESPIRATOR FULL FACE MASK. WHERE EXPOSURE LIMIT MAY BE EXCEEDED USE
NIOSH APPROVED DUST RESPIRATOR.
Ventilation:USE ADEQUATE VENTILATION TO MEET EXPOSURE LIMITS.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . USE FULL COVERAGE IMPERVIOUS CLOTHING TO PREVENT ANY
(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EYE PROT:& FULL LENGTH FACESHIELD . OTHER PROT EQUIP:POSSIBLE CONTACT
W/MATERIAL.
================== Physical/Chemical Properties ==================
Spec Gravity:4.5
Solubility in Water:NOT SOLUBLE
Appearance and Odor:YELLOW POWDER; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/REDUCING AGENTS.
Stability Condition to Avoid:MAY REACT VIGOROUSLY W/REDUCING AGENTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . CONTAMINATED SWEEPINGS & RESIDUE ARE CONSIDERED A
TOXIC WASTE. THIS RESIDUE MUST BE DISPOSED OF AT A LICENSED TOXIC
WASTE DUMP.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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