=====================  Product Identification  =====================

MSDS NAME:DURSBAN (R) 4E INSECTICIDE
NIIN:00-402-5411
MSDS Number: BDXSY
=== Responsible Party ===
Company:DOW CHEMICAL USA
Address:2020 DOW CENTER
City:MIDLAND
State:MI
ZIP:48460-6030
Info Phone Num:517-636-4400
Emergency Phone Num:517-636-4400
CAGE:EO044
=== Contractor Identification ===
Company:DOW CHEMICAL CO
Address:100 LARKIN CENTER
Box:City:MIDLAND
State:MI
ZIP:48674
Country:US
Phone:800-258-2436
CAGE:96717
Company:DOW CHEMICAL USA
Address:2020 DOW CENTER
City:MIDLAND
State:MI
ZIP:48640-6030
Country:US
CAGE:EO044

=============  Composition/Information on Ingredients  =============

Name:CHLORPYRIFOS  (SARA III)
CAS:2921-88-2
RTECS #:TF6300000
Fraction by Wt: 44.4%
OSHA PEL:S, 0.2 MG/M3
ACGIH TLV:S, 0.2 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Name:XYLENES (O-,M-,P- ISOMERS)	(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:PROPRIETARY EMULSIFIERS

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:940 MG/KG=LD50 ORAL RAT
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE MODERATE CORNEAL
    INJURY. SKIN:PROLONGED OR REPEATED EXPOSURE MAY CAUSE SEVERE
    IRRITATION, EVEN A BURN. A SINGLE PROLONGED EXPOSURE MAY RESULT IN
    MATERIAL BEING ABSORBED IN HARMFUL AMOUN TS. INGESTION: SINGLE DOSE
    ORAL TOXICITY IS LOW, NOT LIKELY TO CAUSE INJURY.
    INHALATION:CHOLINESTERASE INHIBITION.
Effects of Overexposure:EYE & RESPIRATORY TRACT IRRITATION, FEELING OF
    INCREASED BODY HEAT, CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS
    HEADACHE, DIZZINESS, INCOORDINATION, DROWSINESS, UNCONSCIOUSNESS.
    EXCESSIVE EXPOSURE MAY PROD UCE ORGANOPHOSPHATE TYPE
    CHOLINESTERASEINHIBITION WITH NAUSEA, DIARRHEA, SWEATING, BLURRED
    VISION, TEARING&CONVULSIONS.
Medical Cond Aggravated by Exposure:NONE

=======================  First Aid Measures  =======================

Eyes: FLUSH WITH WATER FOR 15 MINUTES. CONSULT MEDICAL
    PERSONNEL. SKIN: WASH SKIN WITH PLENTY OF SOAP & WATER WHILE
    REMOVING CONTAMINATED CLOTHING AND SHOES. CALL PHYSICIAN IF
    IRRITATION PERSISTS. ING ESTION: DO NOT INDUCE VOMITING. CALL A
    PHYSICIAN IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. IF NOT
    BREATHING, GIVE MOUTH-TO-MOUTH RESUSCITATION. IF BREATHING IS
    DIFFICULT, GIVE OXYGEN. GET MED HELP

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:106F, 41C
Lower Limits:1
Upper Limits:6
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:FOAM EXTINGUISHING SYSTEM IS PREFERRED BECAUSE
    UNCONTROLLED WATER CAN SPREAD POSSIBLE CONTAMINATION. USE
    POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:TOXIC IRRITATING GASES MAY BE FORMED
    UNDER FIRE CONDITIONS. VIOLENT RUPTURE DUE TO OVER PRESSURIZATION
    MAY OCCUR AT TEMPERATURES GENERATED DURING A FIRE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:ABSORB SPILLS WITH AN ABSORBENT MATERIAL SUCH
    AS HAZORB, ZORBALL, OR DIRT. THOROUGHLY WASH BODY AREAS WHICH COME
    INTO CONTACT WITH THIS PRODUCT. CONTAIN SPILL TO KEEP OUT OF
    SEWERS. FOR LARGE SPILLS,  CONSULT MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:SEE LABLE. KEEP OUT OF REACH OF
    CHILDREN. DO NOT SWALLOW. DO NOT GET IN EYES, ON SKIN OR ON
    CLOTHING. AVOID BREATHING MIST OR VAPORS.
Other Precautions:KEEP AWAY FROM HEAT AND OPEN FLAME. HANDLE
    CONCENTRATE IN VENTILATED AREA.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
    THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR
    CERTAIN OPERATIONS, USE AN APPROVED AIR-PURIFYING RESPIRATOR. USE
    AN APPROVED POSITIVE -PRESSURE SCBA FOR EMERGENCY CONDITIONS.
Ventilation:CONTROL AIRBORNE CONCENTRATIONS BELOW THE EXPOSURE
    GUIDELINE. USE ONLY WITH ADEQUATE VENTILATION. LOCAL MAY BE
    REQUIRED.
Protective Gloves:IMPERVIOUS.
Eye Protection:CHEMICAL GOGGLES OR FULLFACE RESPIRATOR.
Other Protective Equipment:PERMEATION-RESISTANT CLOTHING. BOOTS, APRON
    OR FULL-BODY SUIT AS REQUIRED. EYE WASH & SAFETY SHOWER IN WORK
    AREA.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DEPENDING ON
    DEGREE OF EXPOSURE OF PERSONNEL. CONSIDER MONITORING BLOOD
    CHOLINESTERASE.
Supplemental Safety and Health
KEEP AWAY FROM FLOOD, FEEDSTUFFS AND DOMESTIC WATER SUPPLIES. FOR
    HEALTH & SAFETY INFORMATION ON END-USE DILUTIONS OF UP TO 1% OF
    DURSBAN INSECTICIDES, SEE THE HEALTH & SAFETY FACT SHEET, FORM
    #135-12 70-88, AVAILABLE FROM THE DOW CHEMICAL COMPANY.

==================  Physical/Chemical Properties  ==================

HCC:T4
Boiling Pt:B.P. Text:290F/143C
Decomp Temp:Decomp Text:320-392F
Vapor Pres:<10
Spec Gravity:1.079
Solubility in Water:EMULSIFIABLE
Appearance and Odor:YELLOW LIQUID, SOLVENT-TYPE ODOR

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:AVOID HEATING ABOVE 122F(50C). UNDERGOES
    EXOTHERMIC DECOMPOSITION AT APPROXIMATELY 266F(130C) FOLLOWED BY.
Hazardous Decomposition Products:UNDER FIRE CONDITIONS, HYDROGEN
    CHLORIDE, ETHYL SULFIDE, DIETHYL SULFIDE AND NITROGEN OXIDES CAN BE
    FORMED.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DO NOT CONTAMINATE FOOD, FEED, OR WATER BY
    STORAGE OR DISPOSAL. PESTICIDE WASTES ARE TOXIC. IMPROPER DISPOSAL
    OF EXCESS PESTICIDE, SPRAY MIXTURE, OR RINSATE IS A VIOLATION OF
    FEDERAL LAW. DISPOSE OF W ASTE IN ACCORDANCE WITH LABEL
    INSTRUCTIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

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