===================== Product Identification =====================
MSDS NAME:IODINE, 2208
Status Code:A
MSDS Number: CKDMQ
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151;800-424-9300
Resp. Party Other MSDS Num.:I2680
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:IODINE
CAS:7553-56-2
RTECS #:NN1575000
= Wt:100.
OSHA PEL:C1 MG/M3;C0.1 PPM
ACGIH STEL:C1.0 MG/M3;C0.1 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 14 GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: CORR. VAPS SEVERELY
IRRITATE & CAN BURN MUC MEMB & RESP TRACT. EXCESS TEARS, RHINITIS,
TIGHTNESS IN CHEST, SORE THROAT, HEADACHE AND DELAYED PULMONARY
EDEMA CAN RESULT. INHAL OF CONCENTR ATED VAPS MAY BE FATAL. INGEST:
CORR. CAN CAUSE SEV BURNS OF MOUTH, THROAT & STOM. CAUSES ABDOM
PAIN, DIARR FEVER, VOMIT, STUPOR & SHOCK. PROBABLE LETHAL DOSE IS
2-4 GM OF FREE IODINE. SKIN CONT: CORR . LIQ CONT MAY CAUSE
BLISTERING BURNS, IRRIT, & PAIN. VAPS MAY BE SEVERLY IRRITATING.
EYE CONT: CORR! VAPS ARE SEVERELY IRRITATING & MAY CAUSE DMG TO
EYES. CONT MAY CAUSE SEVERE (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: BURNS & PERM EYE DMG. CHRONIC:
CHRONIC EXPOSURE TO IDODINE MAY CAUSE INSOMNIA, CONJUNCITIVITIS,
INFLAMMATION OF THE NASAL MUCOUS, BRONCHITIS, TREMOR, RAPID HEART
BEAT, DIARRHEA AND WEIGHT L OSS. ALLERGIC SENSITIZATION MAY OCCUR.
Medical Cond Aggravated by Exposure:PERSON W/PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS, IMPAIRED RESP FUNCTION, OR DISEASE OF THE
THYROID, LUNGS, OR KIDNEY MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF
THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. GET MED ATTN IMMED. OBSERVE FOR
DEVELOPMENT OF PULM EDEMA. INGEST: INDUCE VOMIT IMMED AS DIRECTED
BY MED PERSO NNEL. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.
GET MED ATTN IMMED. SKIN CONT: WIPE OFF EXCESS MATL FROM SKIN THEN
IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LST 15 MINS WHILE
REMOVING CONTAMD CLTH G & SHOES. GET MED ATTN IMMED. WASH CLTHG
BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. IODINE STAINS
CAN BE REMOVED BY IMMED WASHING SKIN W/5% SODIUM THIOSULFATE SOLN.
(SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED
CONTAINERS COOL
Fire Fighting Procedures:USE NIOSH APPRVD SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTACT WITH OXIDIZABLE SUBSTANCES &
INCOMPATIBLES MAY CAUSE EXTREMELY VIOLENT COMBUSTION. FIRE: NOT
COMBUSTIBLE, BUT SUBSTANCE IS A STRONG OXIDIZER AND ITS HEAT OF
REACTION WITH REDUCING AGENTS OR CO MBUSTIBLES MAY CAUSE IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:NOTIFY SFTY PERSONNEL OF IODINE SPILL/LEAKS.
VENTILATE AREA OF LEAK/SPILL. WEAR PROT EQUIP AS SPECIFIED IN EXPOS
CTLS/PERSONAL PROT SECTION 8. ISOLATE HAZ AREA. KEEP UNNEC &
UNPROTECTED PERSONNEL FROM ENTERING. COLLECT & CONTAINERIZE AS
MUCH SOLID IODINE AS POSS. COVER SPILL AREA W/EXCESS OF REDUCING
AGENT (SODIUM THIOSULFATE, BISULFATE/FERROUS SALTS IN 3M SULFURIC
ACID) AND (SUPDAT)
Neutralizing Agent:SODA ASH.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR. STORE IN
COOL, DRY, VENTD AREA AWAY FROM SOURCES OF HEAT/IGNIT. PROTECT
AGAINST PHYSICAL DMG. STORE SEPARATELY FROM REACTIVE/COMBUST MATLS,
& OUT OF DIRECT SUNLIGHT. POISON ! DANGER! CORR. DO NOT BREATHE VAP
OR MIST. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
Other Precautions:CNTNRS OF MATL MAY BE HAZ WHEN EMTPY SINCE THEY
RETAIN PROD RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECS
LISTED FOR PROD. USE ONLY W/ADEQ VENT. DO NOT STORE NEAR COMBUST
MATLS. KEEP FROM CONT W/CLTHG & OTHER COMBUST MATLS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE LIMIT IS EXCEEDED, WEAR SUPPLIED
AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED HOOD, OR FULL FACEPIECE
SELF-CONTAINED BREATHING APPARATUS. THIS SUBSTANCE HAS UNKNOWN
WARNING PROPERTIES.
Ventilation:SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOSURE LIMITS. LOC EXHST VENT IS GENERALLY
PREFERRED (OTHER INFO)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGS & FULL LENGTH
FACESHILED .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT, APRON
OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE & WASH
CONTAMD CLOTHING PROMPTLY.
Supplemental Safety and Health
FIRST AID PROC: EYE CONT: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15
MINS, LIFTING LOWER & UPPER EYELIDS OCCASNLY. GET MED ATTN IMMED.
SPILL PROC: THEN NEUT W/SODA ASH. COLLECT SLURRY INTO APPRVD CNT
NRS. WASTE DISP: MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOC
DISP REGS MAY DIFFER FROM FED DISP REGS. (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=183.9C, 363.F
B.P. Text:184C(363F)(SUBLIMES)
Melt/Freeze Pt:=113.9C, 237.F
Vapor Pres:0.3 @ 20C (68F)
Vapor Density:8.8(AIR=1)
Spec Gravity:4.98
pH:OTHER INFO
Evaporation Rate & Reference:NO INFORMATION FOUND
Solubility in Water:OTHER INFO
Appearance and Odor:BLUISH-BLACK CRYSTALS; METALLIC LUSTER.
Percent Volatiles by Volume:<1
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPAT W/AMMONIA, POWDERED METALS, ALKALI METALS/STRONG REDUCING
AGENTS. RXN CAN BE VIOLENT/EXPLO W/ACETALDEHYDE & ACETYLENE. REACTS
W/AMMONIUM HYDROXIDE TO FORM SHOCK-SENSITIVE IODIDES ON DRYING.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. HEAT, SUNLIGHT, AND POOR VENTILATION.
Hazardous Decomposition Products:TOXIC GASES AND VAPORS MAY BE RELEASED
IF INVOLVED IN A FIRE.
=================== Toxicological Information ===================
Toxicological Information:ORAL RAT LD50: 14 GM/KG; HUMAN LDLO: 28
MG/KG; INVESTIGATED AS REPRODUCTIVE EFFECTOR. CANCER LISTS. INGRED:
IDODINE (U553-56-2). NTP CARCIN: NONE KNOWN, NONE ANTICIPATED OR
NONE IARC CATEGORY.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROP & APPRVD WASTE FACILITY. ALTHOUGH NOT
LISTED RCRA HAZ WASTE, THIS MATL MAY EXHIBIT ONE/MORE
CHARACTERISTICS OF HAZ WASTE & R EQ APPROP ANALYSIS TO DETERM
SPECIFIC DISP REQUIREMENTS. PROCESSING, USE/CONTAM OF THIS PROD
(SUPDAT )
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC(LAND, D.O.T.). PROPER SHIPPING NAME:
CORROSIVE SOLID, N.O.S. (IODINE). HAZARD CLASS: 8. UN/NA: UN1759.
PACKING GROUP: III. INFO RPTD FOR PROD/SIZE: 100LB.
INTERNATIONAL(WATER, I.M.O.). PROPER SHIPPING NAME: CORROSIVE
SOLIDS, N.O.S. (IODINE). HAZARD CLASS: 8. UN/NA: UN1759. PACKING
GROUP: III. INFO RPTD FOR PROD/SIZE: 100LB. INTERNATIONAL (AIR,
I.C.A.O.). PROPER SHIPPING NAME: CORROSIVE SO LID, N.O.S. (IODINE).
HAZARD CLASS: 8. UN/NA: UN1759. PACKING GROUP: III. INFO RPTD FOR
PROD/SIZE: 100LB.
===================== Regulatory Information =====================
SARA Title III Information:FED, STATE & INTERNATIONAL REGS - PART 1.
INGRED: IODINE (7553-56-2) SARA 302-RQ-NO, TPQ-NO. SARA 313:
LIST-NO, CHEMICAL CATG.-NO. FED, STATE & INTERNATION REGS - PART 2.
INGRES: IODINE (7553-56-2). C ERCAL-NO, RCRA-261.33-NO, TSCA 8(D) -
NO. CHEMICAL WEAPONS CONVENTION: NO, TSCA 12(B): NO. CDTA: NO. SARA
311,312: ACUTE: YES. CHRONIC: YES. FIRE: YES. PRESSURE: NO.
REACTIVITY: NO. (PURE/SOLID).
Federal Regulatory Information:CHEM INVENTORY STATUS - PART 1. INGRED:
IODINE (7553-56-2). TSCA-YES, EC-YES, JAPAN-NO, AUSTRALIA-YES.
CHEMICAL INVENTORY STATUS - PART 2. INGRED: IODINE (7553-56-2)
CANADA. KOREA-YES, DSL-YES, NDSL-N O, PHIL-YES.AUSTRALIAN HAZCHEM
CODE:NO INFO FOUND. POISON SCHEDULE: S6. SHMIS: THIS MSDS HAS BEEN
PREPARED ACCORD TO HAZARD CRITERIA OF CONTROLLED PRODS REGS (CPR)
AND MSDS CONTAINS ALL OF INFO REQD B Y CPR.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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