===================== Product Identification =====================
MSDS NAME:194 6938, KODAK RETOUCHING COLOR, BROWN
Status Code:A
MSDS Number: CKMMZ
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716 722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
============= Composition/Information on Ingredients =============
Name:POLYETHYLENE GLYCOL
CAS:25322-68-3
RTECS #:TQ3500000
Minumum % Wt:80.
Maxumum % Wt:85.
Other REC Limits:NOT PROVIDED
Name:CROCEINE ORANGE
CAS:1934-20-9
Minumum % Wt:10.
Maxumum % Wt:15.
Other REC Limits:NOT PROVIDED
Name:ANTHRAQUINONE BLUE
CAS:6408-80-6
Code:F
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
Name:AZO RUBINE
CAS:3567-69-9
RTECS #:QK1925000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD-50 (RAT): >3200 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: GENERAL: THE
TOXICOLOGICAL PROPERTIES OF ANTHRAQUINONE BLUE, A MINOR COMPONENT
OF THIS MIXTURE, HAVE NOT BEEN INVESTIGATED AND ITS HANDLING AND
USE MAY PRESENT ADDITIONAL HAZARDS. THE TOXICOLOGICAL PROPERTIES
OF CROCEINE ORANGE, A MINOR COMPONENT OF THIS MIXTURE, HAVE NOT
BEEN INVESTIGATED AND ITS HANDLING AND USE MAY PRESENT ADDITIONAL
HAZARDS. INHALATION: EXPECTED TO BE A LO W HAZARD FOR RECOMMENDED
HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT
IRRITATION. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION:
EXPECTED TO BE A LOW INGESTION HAZARD.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE):- AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE - INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER (IARC) (3): AZO RUBINE- NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE- OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE.
Effects of Overexposure:EYES: MAY CAUSE TRANSIENT IRRITATION.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS
THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES
OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIO US PERSON.
===================== Fire Fighting Measures =====================
Flash Point:COMBUSTIBL SOLID
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
Unusual Fire/Explosion Hazard:ELEVATED TEMPERATURE CAN CAUSE
DECOMPOSITION.
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT UP AND PUT IN A SUITABLE CONTAINER.
AVOID GENERATION OF DUST. CLEAN SURFACE THOROUGHLY TO REMOVE
RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
HEAT. POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES.
MINIMIZE DUST GENERATION AND ACCUMULATION. USE WITH ADEQUATE
VENTILATION. KEEP AWAY FROM SOURCES OF IGNITION. KEEP FROM CONTACT
WITH OXIDIZING MATERIALS.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT, IMPERVIOUS
GLOVES SHOULD BE WORN.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT. EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:NOT RELEVANT
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Decomp Temp:>280.C, 536.F
Vapor Pres:NEGLIGIBLE
Spec Gravity:NOT AVAILABLE
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:APPRECIABLE
Appearance and Odor:PHYSICAL FORM: SOLID (WAXY)COLOR: BROWN ODOR:
ODORLESS
Percent Volatiles by Volume:NEGLIGIBLE
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE; HOWEVER, MATERIAL CAN DECOMPOSE
ABOVE 280C (536F). AVOID TEMPERATURES ABOVE 180C (356F).
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ACUTE TOXICITY DATA FOR ANTHRAQUINONE BLUE :
(KAN 905944) ORAL LD-50 (RAT): >3200 MG/KG. DERMAL LD-50: >1.0
G/KG. SKIN IRRITATION: SLIGHT ACUTE TOXICITY DATA FOR CROCEINE
ORANGE : (KAN 905937) ORAL LD-50 (RAT): >3200 MG/KG DERMAL
LD-50: >1.0 G/KG SKIN IRRITATION: SLIGHT
===================== Ecological Information =====================
Ecological:DATA FOR THE MAJOR COMPONENTS OF THIS MATERIAL HAVE BEEN
USED TO ESTIMATE THE ENVIRONMENTAL IMPACT OF THIS MATERIAL.
HOWEVER, THIS MATERIAL, ITSELF, HAS NOT BEEN TESTED FOR
ENVIRONMENTAL EFFECTS. IT I S EXPECTED TO HAVE THE FOLLOWING
PROPERTIES: A MODERATE BIOCHEMICAL OXYGEN DEMAND AND MAY CAUSE
OXYGEN DEPLETION IN AQUEOUS SYSTEMS, A LOW POTENTIAL TO AFFECT
AQUATIC ORGANISMS, A LOW POTENTIAL TO AFF ECT SECONDARY WASTE
TREATMENT MICROBIAL METABOLISM, A LOW POTENTIAL TO BIOCONCENTRATE.
AFTER DILUTION WITH A LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY
WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE
ENVIRONMENTAL EFFECTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. INCINERATE. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN
AFTER CONTAINER IS EMPTIED .
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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