Permectrin WS
Material Safety Data Sheet
DOT HCS Risk Phrases Protective Clothing
Not regulated in US if transported by Insecticide Signal Word 鈥淐aution鈥?
highway, rail or aircraft in non-bulk
packaging.
Section 1: Product Identification and Uses
Common/Trade name
Permectrin WS
CI# Not applicable
EPA Reg. No#: 4691-123
8.5% Permethrin with PBO, Goat Lice
Synonyms TSCA TSCA: None listed
Remover/Barn and Premise Spray
Chemical name Not available CAS# Not applicable
Chemical formula
MSDS ID#: 4691-123
Not available Code
Chemical family Pyrethroid mixture Molecular weight Not available
Manufacturer Boehringer Ingelheim Vetmedica, Inc.
Supplier Boehringer Ingelheim Vetmedica, Inc. 2621 North Belt Hwy
2621 North Belt Hwy St. Joseph MO 64506-2002
St. Joseph MO 64506-2002 816-233-2571
Material uses Antiparasitic
Section 2: Hazardous Ingredients
Name CAS# % by Weight TLV/PEL LC50 / LD 50
LD50, Oral, Rat 3800
Permethrin 52645-53-1 8.5 Not available
mg/kg
Piperonyl Butoxide 51-03-6 4.25 Not available Oral (LD50): Acute:
Technical 7500 mg/kg [Rat]; 2500
mg/kg [Rabbit]; 7500
mg/kg [Dog]; Dermal
(LD50): Acute: 7950
mg/kg [Rat]
鈮?10
D-Limonene 5989-27-5 Not available Acute oral LD50 (rat) > 5
g/kg; Acute dermal LD50
(rabbit) > 5 g/kg
鈮?5
Ninate 401-A Mixture Not available Not available
Section 3: First Aid Measures
Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after
the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Skin contact If the chemical contacts a clothed portion of the body, remove the contaminated clothing as quickly as possible,
protecting the hands and body. Rinse skin immediately with plenty of water for 15-20 minutes. If chemical contacts
the skin, immediately wash with soap and water. Call a poison control center or doctor for treatment advice. Wash
contaminated clothing separately from normal laundry.
Hazardous skin No additional information
contact
Slight inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,
preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.
Hazardous inhalation No additional information
Permectrin WS
Slight ingestion If ingested, immediately call a poison control center or doctor immediately for treatment advice. Have person sip a
glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor.
Do not give anything by mouth to an unconscious person.
Hazardous ingestion No additional information
Section 4: Physical Data
White opaque
Physical state and
appearance
Odor Light citrus
PH (1% soln/water) 4.4 Taste Not available
Odor threshold Not available Color Milky white
Volatility Not available
Melting/Sublimation point Not available
Boiling/Condensation point Not available
Specific gravity (Water=1) 8.21 lbs/gal
Vapor density (Air=1) Not available
Vapor pressure Not available
Water/oil dist. Coeff. Not available
Ionicity (surface active Not available
agent)
Critical temperature Not available
Instability temperature Not available
Conditions of instability Not available
Dispersion properties Not available
Solubility Not available
Section 5: Fire and Explosion Data
The product is: Combustible
Auto-ignition Not available
temperature
Fire degradation Not available
products
Flash points 145掳F TCC
Flammable limits Not available
Fire extinguishing Small Fire: Use dry chemical, CO2, water spray or foam
procedures
Large Fire: Use water spray, fog or foam. Do not use water jet. NIOSH approved SCBA and full protective
gear is recommended for fire fighters.
Flammability Combustible
Risks of explosion Non-explosive
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Permectrin WS
Section 6: Reactivity Data
Stability The product is stable
Hazardous decomp. None known
products
Degradability Not available
Product of Not available
degradation
Corrosivity Non-corrosive
Reactivity Not available
Section 7: Toxicological Properties
Routes of entry Skin and eye contact, absorption, inhalation, ingestion
TLV Not available
Toxicity for animals LD50: Oral, male rats: >5,050 mg/kg; Oral female rats: >2,936 mg/kg; Dermal, rabbits: >2,020 mg/kg
LC50: Inhalation, rats: >3.6 mg/L
Extremely toxic to fish and other invertebrates. Do not add directly to water or to areas where surface
Environmental hazards
waters are present or to intertidal areas below the mean high water mark. Do not contaminate water when
disposing of equipment wash waters. Apply this product only as specified on the label.
Chronic effects on human Carcinogenic Effects: Piperonyl butoxide classified as group 3 carcinogen
Mutagenic Effects: Not available
Teratogenic Effects: Not available
Developmental Toxicity: Not available
Acute effects on
May be harmful if swallowed, inhaled or absorbed through the skin. Reversible tingling or numbness, skin
humans irritation and sensitivity, CNS depression, respiratory irritation, nausea, dizziness, intoxication and narcosis
are some of the adverse health effects reported for ingredients contained in this product.
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Permectrin WS
Section 8: Preventive Measures
Waste information Triple rinse container then offer for recycling or reconditioning or puncture and dispose of in a sanitary
landfill or incineration or, if allowed by state and local authorities, by burning. If burned, stay out of
smoke.
Waste stream Universal waste pesticide
Storage Keep container sealed when not in use. Do not store near food or feed. Keep away from heat and
ignition sources. Store upright at room temperature. Avoid exposure to extreme temperatures. Do
not freeze.
Extremely toxic to fish and other invertebrates. Do not add directly to water or to areas where surface
Environmental hazards
waters are present or to intertidal areas below the mean high water mark. Do not contaminate water
when disposing of equipment wash waters. Apply this product only as specified on the label.
Precautions Keep out of reach of children. Keep away from heat and sources of ignition. Do not breathe fumes,
vapor or spray. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel
unwell, seek medical attention and show the label when possible. Causes moderate eye irritation.
Harmful if swallowed or absorbed through skin. Avoid contact with eyes, skin or clothing. Wash
thoroughly with soap and water after handling. Remove contaminated clothing and wash clothing
before reuse. When applying indoors as a space spray or fog wear a respirator with an organic vapor
removing cartridge with a pre-filter approved for pesticides (MSHA/NIOSH approval number prefix TC-
23C), or a canister approved for pesticides (MSHA/NIOSH approval number prefix TC-14G), or a
NIOSH approved respirator with an organic vapor (OV) cartridge or canister with any N, R, P, or HE
pre-filter.
Small spill and leak Absorb with inert material. Place in appropriate container and remove from the area. When cleaning
up spills, wear goggles, boots, gloves, apron and vapor respirator if necessary to keep material from
contacting the skin or clothing or being inhaled. Keep product away from heat and ignition sources.
Large spill and leak No additional information
Protective Clothing Goggles and gloves are recommended to avoid skin and eye contact. When applying indoors as a
space spray or fog wear a respirator with an organic vapor removing cartridge with a pre-filter
approved for pesticides (MSHA/NIOSH approval number prefix TC-23C), or a canister approved for
pesticides (MSHA/NIOSH approval number prefix TC-14G), or a NIOSH approved respirator with an
organic vapor (OV) cartridge or canister with any N, R, P, or HE pre-filter.
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Permectrin WS
Section 9: Classification
Not regulated in US if transported by highway, rail or aircraft in non-bulk packaging.
DOT
Maritime Consumer Commodity, ORM-D (Dipentene)
transportation
Shipping name: Environmentally hazardous substance, liquid, N.O.S. (Dipentene), 9, UN3082, PG III
Insecticide Signal Word 鈥淐aution鈥?
HCS
Federal and No additional information
State
Regulations
HMIS (U.S.A.)
National Fire Protection
Health Hazard 1
Fire Hazard
2
Association (U.S.A.)
Fire Hazard 2
1 0
Reactivity 0
Reactivity
H
Personal Protection
Specific hazard
Section 10: Protective Measures
Protective Splash goggles and gloves are recommended to avoid skin and eye contact, apron and vapor
clothing respirator if necessary. When applying indoors as a space spray or fog wear a respirator with an
organic vapor removing cartridge with a pre-filter approved for pesticides (MSHA/NIOSH approval
number prefix TC-23C), or a canister approved for pesticides (MSHA/NIOSH approval number prefix
TC-14G), or a NIOSH approved respirator with an organic vapor (OV) cartridge or canister with any N,
R, P, or HE pre-filter.
Engineering Local exhaust sufficient under normal use conditions. Additional ventilation may be necessary in the
controls event of a spill.
Section 11: Other Information
References Not available
Validated by Company: 9/6/05
Permectrin WS
CALL 1(800) 821-7467
Emergency Medical: (800)530-5432
Chemtrec: (800)424-9300
_________________________________________________________________________________________________________
The information provided herein is offered by Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) in good faith as accurate as of the date hereof, but
without guarantee. This information includes information which has been generated by other parties and provided to BIV, and which BIV has
not independently verified. The information provided herein relates only to the specific product designated, and may not be valid where such
product is used in combination with any other materials or in any process. The information provided herein is offered solely for your
consideration, investigation and verification, and Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) expressly disclaims all liability for reliance
thereon. BIV EXPRESSLY DISCLAIMS ALL WARRANTIES OF EVERY KIND AND NATURE (INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE) WITH RESPECT TO THE USE OR SUITABILITY OF THE
PRODUCT. In addition, since the conditions of use and suitability of the product for particular uses are beyond BIV鈥檚 control, ALL RISKS OF
USE OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER, AND BIV EXPRESSLY
DISCLAIMS ANY AND ALL LIABILITY AS TO ANY RESULTS OBTAINED OR ARISING FROM ANY USE OF THE PRODUCT. Use or
retransmission of the information contained herein in any other format than the format as presented is strictly prohibited. Nothing herein shall
be construed as a permission or recommendation for the use of the product in a manner that might infringe an existing patent. BIV neither
represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country
except the United States of America.
漏 Copyright 2001 Boehringer Ingelheim Vetmedica, Inc. All rights reserved.
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