MATERIAL SAFETY DATA SHEET
VigorOx庐 Citrus XA
MSDS Ref. No.: 79-21-0-13
Date Approved: 11/10/2006
Revision No.: 10
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the Canada鈥檚 Workplace Hazardous Materials Information System (WHMIS)
and, the EC Directive, 2001/58/EC.
1. PRODUCT AND COMPANY IDENTIFICATION
VigorOx庐 Citrus XA
PRODUCT NAME:
Peroxyacetic Acid Solution, Peracetic Acid Solution
SYNONYMS:
EPA Registration No. 65402-6
GENERAL USE:
VigorOx Citrus XA has been formulated for sanitizing surfaces such
as packinghouse conveyers and harvesting equipment and containers.
It is effective against plant pathogens such as Xanthomonas
campestris (axonopodis) pathovars citrumelo (citrus canker
surrogate).
VigorOx Citrus XA is for sanitizing of inanimate, non-food contact
surfaces (general environmental surfaces).
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION (303) 595-9048 (Medical - U.S. - Call Collect)
FMC Peroxygens
1735 Market Street For leak, fire, spill, or accident emergencies, call:
Philadelphia, PA 19103 (800) 424-9300 (CHEMTREC - U.S.A. & Canada)
(215) 299-6000 (General Information)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
鈥? Clear liquid with a sharp, pungent, vinegar-like odor.
鈥? Oxidizer.
鈥? Stabilized peracetic acid, an ingredient in this product, decomposes under fire conditions to release
oxygen that intensifies the fire.
鈥? Use water to keep fire exposed containers cool.
鈥? Severely irritating to skin and eyes.
Page 1 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
POTENTIAL HEALTH EFFECTS: Liquid and mist are corrosive (causing burns); direct
contact could cause irreversible damage to eyes including blindness and/or irreversible destruction of skin
tissue. Vapor/mist will irritate nose, throat and lungs but will usually subside when exposure ceases.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Wt.% EC No. EC Class
Peroxyacetic Acid 79-21-0 5-6 201-186-8 O, C; R7-10-34; S1/2-3/7-
14-36/37/39-45-61
Hydrogen Peroxide 7722-84-1 22 - 23 231-765-0 Xn, R22-4; S1/2-3-17-26-
28-36/37/39-45
Acetic Acid 64-19-7 10 - 11 200-580-7 R10-34-35-36/38; S1/2-23-
26-45
Water 7732-18-5 63 - 65 231-791-2 Not classified
4. FIRST AID MEASURES
EYES: Immediately flush with water for at least 15 minutes, lifting the upper and lower eyelids
intermittently. See a medical doctor immediately.
SKIN: Remove contaminated clothing and thoroughly wash with soap and water. If irritation occurs and
persists, contact a medical doctor.
INGESTION: Rinse mouth with water. Dilute by giving 1 or 2 glasses of water. Do not induce
vomiting. Never give anything by mouth to an unconscious person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing discomfort occurs and persists, see a medical
doctor. If breathing has stopped, give artificial respiration and see a medical doctor immediately.
NOTES TO MEDICAL DOCTOR: This product can be corrosive to skin, eyes and mucous
membranes. Consideration should be given to careful endoscopy as stomach or esophageal burns,
perforations or strictures may occur. Careful gastric lavage with an endotracheal tube in place should be
considered. Observation may be warranted. Treatment is controlled removal of exposure followed by
symptomatic and supportive care.
Page 2 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Use water spray to keep fire exposed containers cool.
Extinguish fire using agents suitable for nearby fires.
FIRE / EXPLOSION HAZARDS: Oxygen that can initiate or promote combustion.
FIRE FIGHTING PROCEDURES: Use flooding quantities of water only. Use water spray
to keep fire exposed containers cool. Fight fire from protected location or maximum distance. Chemical
type extinguishers are not effective with peracetic acid or hydrogen peroxide, which are ingredients in this
product. Use proper personal protective equipment and positive pressure self contained breathing apparatus.
FLAMMABLE LIMITS: Not available
SENSITIVITY TO IMPACT: Not available
SENSITIVITY TO STATIC DISCHARGE: Not available
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Approach release from upwind. Stop or control leak using special protective
clothing and positive pressure self-contained breathing apparatus. Control run off and isolate discharged
material for proper disposal. Do not allow undiluted material to enter storm or sanitary sewer systems.
Combustible materials exposed to hydrogen peroxide, an ingredient in this product, should be immediately
submerged in, or rinsed with, large amounts of water to ensure that all hydrogen peroxide is removed.
Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can concentrate)
on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the
material to ignite and result in a fire.
7. HANDLING AND STORAGE
HANDLING: Transfer product from drums to process in closed system (hermetically) and if not
possible use effective local exhaust ventilation. Empty drum as thoroughly as possible. Triple rinse before
disposal. Avoid contamination; impurities accelerate decomposition. Never return product to original
container. Use airless spray to minimize mist generation.
STORAGE: Do not store near reducing agents, fuels or other non-compatible materials. Store in a
cool, dry, well ventilated area. For quality purposes, avoid temperatures above 86潞 F. Higher temperatures
will accelerate decomposition resulting in a loss of assay. Do not store in direct sunlight, or near sources of
ignition or heat. Do not double stack. Use first in, first out storage system. Containers must be vented.
Expected shelf life - 1 year.
Page 3 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
COMMENTS: VENTILATION: Provide mechanical local exhaust ventilation to prevent release of
mist into the work area. If ventilation is inadequate or not available use acid gas cartridge or canister with
full face-piece.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name ACGIH OSHA Supplier
Hydrogen Peroxide 1 ppm (TWA) 1 ppm (PEL)
Acetic Acid 15 ppm (STEL) 10 ppm (PEL)
ENGINEERING CONTROLS: Provide mechanical local exhaust ventilation to prevent
release of mist into the work area. If release is expected use respiratory protection. Ventilate all transport
vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Use cup type chemical goggles. Full face shield may be used.
RESPIRATORY: For normal use as directed, respiratory protection is not required.
However, if exposures are anticipated to be above the limits as indicated in the "Exposure Limit"
table, an approved full-face acid/gas cartridge or canister respirator should be used. If
concentrations are unknown (e.g., significant spill or other emergencies), or if they are anticipated
to be above 5 ppm for hydrogen peroxide or 50 ppm for acetic acid, the use of a full-face airline
supplied respirator or self-contained breathing apparatus (SCBA) is recommended.
PROTECTIVE CLOTHING: Rubber or neoprene footwear and aprons, or full
protective clothing. Hydrogen peroxide is an ingredient in this product; completely submerge
hydrogen peroxide contaminated clothing or other materials in water prior to drying. Residual
hydrogen peroxide, if allowed to dry on materials such as paper, fabrics, cotton, leather, wood or
other combustibles can cause the material to ignite and result in a fire.
GLOVES: Rubber or neoprene gloves. Thoroughly wash the outside of gloves with soap and
water prior to removal. Inspect regularly for leaks.
9. PHYSICAL AND CHEMICAL PROPERTIES
Sharp, pungent, vinegar like odor
ODOR:
Colorless liquid
APPEARANCE:
270 掳C (518 掳F)
AUTOIGNITION TEMPERATURE:
About 99 掳C (210 掳F)
BOILING POINT:
Page 4 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
Not available
COEFFICIENT OF OIL / WATER:
9.17 lbs./gal
DENSITY / WEIGHT PER VOLUME:
Above 1 (Butyl Acetate = 1)
EVAPORATION RATE:
Approximately 83 掳C (181 掳F) (CC)
FLASH POINT:
-25.9 掳C (-15 掳F)
MELTING POINT:
Not available
ODOR THRESHOLD:
Oxidizer
OXIDIZING PROPERTIES:
Less than 1
pH:
100 % @ 25 掳C (by wt.)
SOLUBILITY IN WATER:
(H2O=1): 1.10 @ 20潞C
SPECIFIC GRAVITY:
Not available (Air = 1)
VAPOR DENSITY:
22 mm Hg @ 25 掳C (77 掳F)
VAPOR PRESSURE:
COMMENTS:
pH (1% solution) @ 25掳C: 2-3
Self Accelerating Decomposition Temperature (SADT) > 55掳C (55 gallon drum)
10. STABILITY AND REACTIVITY
Open flames, elevated temperatures, any source of
CONDITIONS TO AVOID:
heat, combustibles such as paper and wood and
contamination. For quality purposes, avoid
temperatures above 86潞F. Higher temperatures will
accelerate decomposition resulting in a loss of
assay.
Stable (expected shelf life - 1 year, when stored at
STABILITY:
temperatures below 86潞F).
Will not occur
POLYMERIZATION:
Dirt, alkali, reducing agents, organics and heavy
INCOMPATIBLE MATERIALS:
metals such as iron, copper, chromium, aluminum,
cobalt and caustic.
Acetic acid and oxygen that supports combustion.
HAZARDOUS DECOMPOSITION PRODUCTS:
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Severely irritating [FMC Study I95-2036]
Page 5 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
SKIN EFFECTS: Severely irritating [FMC Study I95-2036]
DERMAL LD50: No data available for the product.
17% Peracetic Acid: > 200 mg/kg (rabbit) [FMC I83-721]
ORAL LD50: 1,922 mg/kg (rat)
INHALATION LC50: No data available for the product.
5% Peracetic Acid: 4,080 mg/m3 (4157 ppm) (4 h) (rat) [FMC Study I96-2138]
100% Peracetic Acid: 204 mg/m3 (66 ppm) (4 h) (rat) [FMC Study I96-2138]
TARGET ORGANS: Eyes, skin, nose, throat, lungs
ACUTE EFFECTS FROM OVEREXPOSURE: Liquid may cause severe burns and
irreversible tissue damage to eyes, including blindness. Product contains peracetic acid. Inhalation of
peracetic acid vapors causes lacrimation and irritation of the mucous membranes, eyes and nasal passages.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the
product. Product contains hydrogen peroxide. The International Agency for Research on Cancer (IARC)
has concluded that there is inadequate evidence for carcinogenicity of hydrogen peroxide in humans, but
limited evidence in experimental animals (Group 3 - not classifiable as to its carcinogenicity to humans).
The American Conference of Governmental Industrial Hygienists (ACGIH) has concluded that hydrogen
peroxide is a 'Confirmed Animal Carcinogen with Unknown Relevance to Humans' (A3).
CARCINOGENICITY:
Chemical Name IARC NTP OSHA Other
Hydrogen Peroxide Listed Not listed Not listed (ACGIH) Listed (A3,
Animal Carcinogen)
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION:
96-hour LC50 = 1.6 mg/L (Rainbow trout) [FMC I95-2023]
96-hour LC50 = 1.1 mg/L (Bluegill sunfish) [FMC I95-2029]
48-hour EC50 = 0.73 mg/L (Daphnia magna) [FMC I95-2021]
120-hour EC50 = 0.18 mg/L (Selenastrum, green algae) [FMC I95-2027]
CHEMICAL FATE INFORMATION: No data available for the product. Peracetic acid is
completely miscible with water. Aqueous solutions of peracetic acid hydrolyze to acetic acid and hydrogen
peroxide.
Page 6 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Discharge as a hazardous waste into a suitable treatment system in
accordance with local, state and federal governmental agencies.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
Hydrogen Peroxide and Peroxyacetic Acid
PROPER SHIPPING NAME:
Mixtures, Stabilized with Acids, Water and
not more than 6% Peroxyacetic Acid
5.1 (Oxidizer)
PRIMARY HAZARD CLASS / DIVISION:
8 (Corrosive)
HAZARD CLASS, SUBSIDIARY:
UN 3149
UN/NA NUMBER:
II
PACKING GROUP:
5.1 Oxidizer and Subsidiary Risk: 8
LABEL(S):
(Corrosive)
Bulk: 5.1 Oxidizer
PLACARD(S):
Hydrogen Peroxide and Peroxyacetic Acid
MARKING(S):
Mixtures, Stabilized with Acids, Water and
not more than 6% Peroxyacetic Acid, UN
3149
Not applicable
REPORTABLE QUANTITY (RQ):
49 STCC Number: Not required - no rail
ADDITIONAL INFORMATION:
shipments
Material is shipped in 5 gal. (45 lb.), 30 gal.
(250 lb.) and 55 gal. (450 lb.) vented linear
(not cross linked) polyethylene drums and
IBCs.
Do not ship on wooden pallets.
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
Hydrogen Peroxide and Peroxyacetic Acid
PROPER SHIPPING NAME:
Mixtures, Stabilized with Acids, Water and
not more than 6% Peroxyacetic Acid
Page 7 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
Hydrogen Peroxide and Peroxyacetic Acid
PROPER SHIPPING NAME:
Mixtures, Stabilized with Acids, Water and
not more than 6% Peroxyacetic Acid
NOTE: Venting of packages is not
ADDITIONAL INFORMATION:
permitted for air transport.
OTHER INFORMATION:
Protect against physical damage. Use proper personal protective equipment and positive pressure self-
contained breathing apparatus when handling spills or leaks. Dike any spills.
If this material is ever shipped via vessel, the container requires subsidiary placarding in addition to main
hazard class placards.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Listed
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Fire Hazard, Immediate (Acute) Health Hazard
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
500 lb
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
Peracetic acid
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
5% Peracetic Acid (Unlisted), RQ = 100 lbs., Corrosivity, Reactivity
Listed
Chemical Name RQ
Acetic Acid 5,000 lb Category D
Page 8 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261):
Waste Number: D001 (ignitability), D002 (corrosivity)
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Product Identification Number: 9183
Hazard Classification / Division: Class D, Div. 2, Subdiv. B. (Toxic), Class E (Corrosive), Class
C (Oxidizer)
Ingredient Disclosure List: Listed
INTERNATIONAL LISTINGS
Peroxyacetic acid:
Australia (AICS): Listed
China: Listed
Japan (ENCS): (2)-689
Philippines (PICCS): Listed
Hydrogen peroxide:
China: Listed
Japan (ENCS): (1)-419
Korea: KE-20204
Philippines (PICCS): Listed
Acetic acid:
Australia (AICS): Listed
China: Listed
Japan (ENCS): (2)-688
Korea: KE-00013
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
Peroxyacetic acid:
EC Symbols: O (Oxidizer)
C (Corrosive)
Page 9 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
EC Risk Phrases: R7 (May cause fire)
R10 (Flammable)
R34 (Causes burns)
EC Safety Phrases: S1/2 (Keep locked up and out of reach of children.)
S3/7 (Keep in a cool place and keep container tightly closed)
S14 (Keep away from: see Incompatible Materials in Section 10
above)
S36/37/39 (Wear suitable protective clothing, gloves and eye/face
protection.)
S45 (In case of accident or if you feel unwell, seek medical advice
immediately - show the label where possible.)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
Hydrogen Peroxide, (Index #008-003-00-9):
EC Symbols: Xn (Harmful)
EC Risk Phrases: R22 (Harmful if swallowed.)
R41 (Risk of serious damage to eyes.)
EC Safety Phrases: S1/2 (Keep locked up and out of reach of children.)
S3 (Keep in a cool place.)
S17 (Keep away from combustible material.)
S26 (In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice)
S28 (After contact with skin, wash immediately with plenty of water
and soap.)
S36/37/39 (Wear suitable protective clothing, gloves and eye/face
protection.)
S45 (In case of accident or if you feel unwell, seek medical advice
immediately - show the label where possible.)
Acetic acid:
EC Symbols: C (Corrosive)
Xi (Irritant)
Page 10 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
EC Risk Phrases: R10 (Flammable)
R35/34 (Causes severe burns / causes burns)
R36/38 (Irritating to eyes and skin.)
EC Safety Phrases: S1/2 (Keep locked up and out of reach of children.)
S23 (Do not breathe gas, fumes, vapor, or spray)
S26 (In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice)
S45 (In case of accident or if you feel unwell, seek medical advice
immediately - show the label where possible.)
16. OTHER INFORMATION
HMIS
Health 3
Flammability 1
Physical Hazard 2
Personal Protection (PPE) H
Protection = H (Safety goggles, gloves, apron and a vapor respirator)
HMIS = Hazardous Materials Identification System
Degree of Hazard Code:
4 = Severe
3 = Serious
2 = Moderate
1 = Slight
0 = Minimal
NFPA
Health 3
Flammability 1
Reactivity 2
Special OX
SPECIAL = OX (Oxidizer)
NFPA = National Fire Protection Association
Degree of Hazard Code:
4 = Extreme
3 = High
2 = Moderate
1 = Slight
0 = Insignificant
Page 11 of 12
VigorOx庐 Citrus XA (79-21-0-13) Date: 11/10/2006
REVISION SUMMARY:
This MSDS replaces Revision #9, dated June 15, 2006.
Changes in information are as follows:
Section 14 (Transport Information)
Section 16 (Other Information)
VigorOx and FMC Logo - Trademarks of FMC Corporation
漏 2006 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. It is a violation of Federal law to
use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use
are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as
to any results obtained or arising from any use of the product or reliance on such information.
Page 12 of 12
|