Material Safety Data Sheet
MSDS ID NO.: 0137MAR019
Revision date: 07/25/2006
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon Anionic Emulsified Asphalt
Synonym: Anionic Emulsified Asphalt; AE-P; AE-PL; AE-T; AE-3; AE-60; AE-90; AE-90G; AE-
150; AE-200; AE-300; EA-90; EA-150; EA-300; HFE-90; HFE-150; HFE-300; HFMS-
2; HFP; HFRS-1; HFRS-2; HFRS-2P; L1P; MS-2; MS-3; MWS-90; MWS-150; MWS-
300; PEA; PEP; RS-1; RS-2; RS-2L; RS-2P; RS-3; SS-1; SS-1H; SS-1HL;SS-1M;
Shellycote; Shellycote Plus; Performac 鈩? AE Series; Performac鈩? HF Series;
Performac鈩? L1P; Performac鈩? MS Series; Performac鈩? MWS Series; Performac鈩?
PEA; Performac鈩? RS Series; Performac鈩? SS Series; Performac鈩? Shellycote
Series
Chemical Family: Asphalt
Formula: Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information: 419-421-3070
Emergency telephone number: 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
This product is an Anionic Emulsified Asphalt mixed with varying proportions of No. 2 fuel oil and/or heavy paraffinic
distillate with an anionic emulsifier. May contain polymer modifiers. Composition varies depending on source of crude
and specifications of final product. May contain minor amounts of sulfur, nitrogen and oxygen containing compounds.
Product information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
=0.5 mg/m3 TWA
Marathon Anionic Emulsified Asphalt Mixture 100
Component Information:
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 1 of 13
Asphalt
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Asphalt 8052-42-4 30-80 =0.5 mg/m鲁 TWA
(inhalable fraction, as
benzene-soluble
aerosol)
Water 7732-18-5 5-60
No. 2 Fuel Oil 64741-44-2 0-40
Petroleum Distillates, Solvent 64742-65-0 0-5 Mineral Oil Mist
Dewaxed Heavy Paraffinic (MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
Sulfur Compounds Mixture 0-5
Polymer Modifier (SBS or SBR) Mixture 0-5
Anionic Emulsifier Mixture 0.1-4
Naphthalene 91-20-3 0.01-0.2 Skin - potential = 10 ppm TWA
= 50 mg/m3 TWA
significant contribution
to overall exposure by = 15 ppm STEL
= 75 mg/m3 STEL
the cutaneous route
= 10 ppm TWA
= 15 ppm STEL
Hydrogen Sulfide 7783-06-4 0-0.5 = 10 ppm TWA = 10 ppm TWA
= 15 ppm STEL = 14 mg/m鲁 TWA
= 15 ppm STEL
= 21 mg/m鲁 STEL
Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 2 of 13
Asphalt
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
EMULSIFIED ASPHALT IS A DARK BROWN TO BLACK LIQUID EMULSION. ASPHALT IS LIQUID AT 150-200
DEGREES F AND SKIN CONTACT WILL CAUSE THERMAL BURNS. WHEN HEATED THIS MATERIAL MAY VENT
TOXIC LEVELS OF HYDROGEN SULFIDE (H2S) VAPORS THAT ACCUMULATE IN THE VAPOR SPACES OF
STORAGE AND TRANSPORT COMPARTMENTS. H2S VAPORS CAN CAUSE EYE, SKIN, AND RESPIRATORY
TRACT IRRITATION AND ASPHYXIATION. AVOID SKIN CONTACT. LONG TERM SKIN EXPOSURE TO
COMPONENTS OF THIS PRODUCT HAS CAUSED CANCER IN LABORATORY ANIMALS. THIS PRODUCT IS
NEITHER A FLAMMABLE NOR COMBUSTIBLE MATERIAL PER THE OSHA HAZARD COMMUNICATION STANDARD
BUT WILL BURN WHEN HEATED TO EXTREMELY HIGH TEMPERATURES.
OSHA WARNING LABEL:
WARNING.
HOT ASPHALT
MAY PRODUCE SEVERE BURNS.
MAY VENT HARMFUL CONCENTRATIONS OF HYDROGEN SULFIDE (H2S) GAS WHICH CAN CAUSE
RESPIRATORY IRRITATION AND ASPHYXIATION.
LONG-TERM SKIN EXPOSURE TO COMPONENTS OF THIS PRODUCT HAS CAUSED CANCER IN LABORATORY
ANIMALS.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation: Vapors and fumes can cause respiratory and nasal irritation. Significant
concentrations of hydrogen sulfide gas can be present in the vapor space of storage
tanks and bulk transport compartments (See Sections 7, 8 & 11).
Ingestion: Product would be expected to have a low order of acute toxicity.
Skin contact: Hot product causes severe burns. Frequent or prolonged contact with cold material
may cause irritation.
Eye contact: Hot product causes severe burns.
Carcinogenic Evaluation:
Product information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon Anionic Emulsified Asphalt NE
Mixture
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is sufficient evidence for the carcinogenicity of extracts of steam-refined bitumens
(asphalts), air-refined bitumens and pooled mixtures of steam- and air-refined
bitumens in experimental animals. IARC has determined that there is inadequate
evidence that bitumens alone are carcinogenic to humans.
Component Information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Asphalt Supplement 7, 1987; A4 - Not Classifiable as a
8052-42-4 Monograph 35, 1985; Human Carcinogen (as
(extracts of steam and air benzene-soluble aerosol)
refined bitumens)
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 3 of 13
Asphalt
Naphthalene Monograph 82, 2002 Reasonably Anticipated To A4 - Not Classifiable as a Present
91-20-3 Be A Carcinogen Human Carcinogen
Listed
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is inadequate evidence for the carcinogenicity of diesel fuel/fuel oil in humans. IARC
determined that there was limited evidence for the carcinogenicity of marine diesel
fuel in animals. Distillate (light) diesel fuels were not classifiable as to their
carcinogeniicty to humans (Group 3A)
The International Agency for Reserch on Cancer (IARC) has determined that there is
no evidence that severely solvent-refined oils are carcinogenic to experimental
animals.
The International Agency for Research on Cancer (IARC) and the Environmental
Protection Agency (EPA) have determined that naphthalene could be a possible
human carcinogen.
4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact: For contact with hot molten material, immerse or flush skin with cold water for at least
15 minutes. Call a physician. Do not attempt to remove solidified material since
removal may cause further tissue injury. Cold material over a burn should not be
removed except by a physician. Remove cold material (not associated with a burn)
with waterless handcleaner and then wash with soap and water. If symptoms or
irritation occur, call a physician.
Ingestion: Ingestion not likely. If large amounts are swallowed, immediately call a physician.
Eye contact: For contact with hot molten material, flush with large amounts of tepid water for at
least 15 minutes. Immediately call a physician.
For contact with vapors or dust, flush with large amounts of tepid water for at least 15
minutes. If symptoms or irritation occur, call a physician.
Notes to physician: Recommended practice is to not attempt to remove hot material associated with a
burn. Allow the solidified material to remain in place until cooled so it can naturally
fall off. Natural separation will occur in 48-72 hours. If removal is attempted, mineral
oil may be used to remove asphalt once it is cooled. For best results, work it into the
skin around the material and allow the material to "float" off.
Medical conditions aggravated Preexisting skin, eye and respiratory disorders may be aggravated by exposure to
by exposure: components of this product.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 4 of 13
Asphalt
Specific hazards: This product is neither a flammable nor combustible
material, but will burn when heated to extremely high
temperatures. For additional fire related information, see
NFPA 30 or the North American Emergency Response
Guide 128.
Special protective equipment for firefighters: Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Keep run-off water out of sewers and
water sources.
Flash point: >200 F
Autoignition temperature: No data available.
Flammable limits in air - lower (%): 1.0
Flammable limits in air - upper (%): 6.0
NFPA rating: HMIS classification:
Health: 2 Health: 2
Flammability: 1 Flammability: 1
Reactivity: 1 Reactivity: 1
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Notify local health and pollution control agencies, if
appropriate. Contain liquid with sand or soil. Recover and return product to source.
7. HANDLING AND STORAGE
Handling:
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Do not cut, drill, grind or weld on
empty containers since they may contain explosive residues.
Significant concentrations of hydrogen sulfide (H2S) gas can be generated and accumulate in storage tanks and bulk
transport compartments which may require additional precautions and procedures during loading/unloading. When
opening covers and outlet caps on storage tanks, use face shield and gloves to avoid possible injury from pressurized
product. Stay upwind and vent open hatches before unloading. Keep heating coils and flues in storage tanks, trucks and
kettles covered with product (8"). Do not overheat.
Avoid skin contact. Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap
and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures: Local or general exhaust required in an enclosed area or when there is inadequate
ventilation.
Respiratory protection: Not required under normal conditions and adequate ventilation. When H2S vapors
exceed permissible limits, i.e., in confined spaces or bulk transport
loading/unloading, a positive-pressure atmosphere supplying respirator is
recommended. Self-contained breathing apparatus should be used for fire fighting.
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 5 of 13
Asphalt
Skin and body protection: Insulated gloves when handling hot material.
Eye protection: Goggles and faceshield when handling hot material.
Hygiene measures: Rubberized suits or coats may be needed for some maintenance operations with hot
material.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Black-brown Liquid Emulsion
Physical state (Solid/Liquid/Gas): Liquid
Substance type (Pure/Mixture): Mixture
Color: Black-Brown
Odor: Tar
Molecular weight: Not determined.
pH: Neutral
Boiling point/range (5-95%): >212 F
Melting point/range: 60 F
Decomposition temperature: Not applicable.
Specific gravity: Not determined
Density: 7.5-8.7 lbs/gal
Bulk density: No data available.
Vapor density: No data available.
Vapor pressure: Negligible @ 77 F
Evaporation rate: No data available.
Solubility: Negligible
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): No data available.
VOC content(%): No data available.
Viscosity: No data available.
10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.
Polymerization: Will not occur.
Hazardous decomposition products: Combustion produces toxic oxides of sulfur, carbon
monoxide, sulfur dioxide, hydrogen sulfide and
hydrocarbons.
Materials to avoid: Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid: Excessive heat, sources of ignition, open flame.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name CAS Number Inhalation: Dermal: Oral:
Marathon Anionic Emulsified Asphalt Mixture No data available No data available No data available
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 6 of 13
Asphalt
Some epidemiologic studies conducted on workers exposed to asphalt fume have shown no increased incidence of
cancer while other studies have reported a slightly increased incidence of lung, other respiratory tract or gastrointestinal
cancers. In those studies in which elevated cancer incidences were reported, concurrent or previous exposure to coal-tar
products have been documented. therefore, it cannot be concluded that cancer incidence is related to exposure to
asphalt fume.
Although early studies have some technical shortcomings, long term inhalation exposures to asphalt aerosols or fumes
did not produce evidence of carcinogenicity even though chronic inflammatory changes similar to those produced by
nonspecific respiratory irritants were observed. Inhalation of 150 mg/m3 asphalt fume (particulate + vapor) 6 hours/day, 5
days/week for 13 weeks, did not produce toxicity except for reduced body weight and irritation in nasal passages in
exposed rats.
Laboratory animals administered subcutaneous or intramuscular injections of asphalt preparations or repeated skin
applications of hot (212 F) undiluted asphalt have occasionally produced a low incidence of skin tumors at the site of
application. These findings are of questionable validity since repeated tissue trauma (and/or burns) at the application site
can induce tumors. Solvent dilutions of different types of asphalts have been tested in chronic skin painting studies. Some
of the studies have reported a low incidence of skin tumors. The use of diluents may enhance bioavailability or metabolic
activation of chemicals in the mixture in a fashion not representative of occupational exposure. Skin painting studies in
mice have been conducted using condensates from fumes generated at temperatures >450 F diluted in solvent. Asphalt
fume condensate preparations have produced skin tumors. Experimental conditions (temperature and dose) were grossly
exaggerated over that likely to occur in humans.
Extracts of whole asphalts tested in a modified Ames assay gave negative or slightly positive findings (mutagenicity index
<1.5). Fume condensates derived from heating asphalts to high temperatures (>450 F) were moderately active (MI 4-9).
Fumes generated from coal tar pitch were >1000 times more active. Asphalt fume samples collected under actual field
conditions did not show any significant mutagenic activity.
Summary of health effect data on asphalt components:
This product can contain a toxicologically significant concentration of hydrogen sulfide (H2S). Hydrogen sulfide gas (H2S)
is toxic by inhalation. Prolonged breathing of 50-100 ppm H2S vapors can produce eye and respiratory tract irritation.
Higher concentrations (250-600 ppm) for 15-30 minutes can produce headache, dizziness, nervousness, nausea and
pulmonary edema or bronchial pneumonia. Concentrations of >1000 ppm will cause immediate unconsciousness and
death through respiratory paralysis. Rats and mice exposed to 80 ppm H2S, 6 hrs/day, 5 days/week for 10 weeks, did not
produce any toxicity except for irritation of nasal passages. H2S did not affect reproduction and development (birth
defects or neurotoxicity) in rats exposed to concentrations of 75-80 ppm or 150 ppm H2S, respectively. Over the years a
number of acute cases of H2S poisonings have been reported. Complete and rapid recovery is the general rule.
However, if the exposure was sufficiently intense and sustained causing cerebral hypoxia (lack of oxygen to the brain),
neurologic effects such as amnesia, intention tremors or brain damage are possible.
This product may contain No. 2 fuel oil at a level of >1.0%. Lifetime skin painting studies in animals with similar middle
distillate fuel oils and gas oils have produced tumors following prolonged and repeated skin contact. Some middle
distillates and/or light gas oils, when tested at nonirritating dose levels, did not show any significant carcinogenic activity
indicating that this tumorigenic response may be related to chronic irritation and not to dose. Repeated dermal
application has produced severe irritation and systemic toxicity in subacute toxicity studies. Some components of this
product, i.e., paraffins and olefins, have been shown to produce a species specific sex hormonal dependent kidney lesion
in male rats from repeated oral or inhalation exposure. Subsequent research has shown that the kidney damage
develops via the formation of alpha-2u-globulin, a mechanism unique to the male rat. Humans do not form alpha-2u-
globulin, therefore, the kidney effects resulting from this mechanism are not relevant in humans. Some components were
found to be positive in a few mutagenicity tests while negative in the majority of others. The exact relationship between
these results and human health is not known.
This product may contain >0.1% naphthalene. Exposure to naphthalene at 30 ppm for two years caused lung tumors in
female mice. Male mice with the same exposure did not develop tumors. Exposure to 10-60 ppm naphthalene for 2 years
caused tumors in the tissue lining of the nose and respiratory tract in male and female rats. Oral administration of 133-
267 mg/kg/day of naphthalene in mice for up to 90 days did not produce mortality, systemic toxicity, adversely affect
organ or body weight or produce changes in blood. Repeated oral administration of naphthalene produced an anemia in
dogs. Repeated intraperitoneal doses of naphthalene produced lung damage in mice. Repeated high doses of
naphthalene has caused the formation of cataracts and retinotoxicity in the eyes of rats and rabbits due to accumulation
of 1,2-naphthoquinone, a toxic metabolite. Effects in human eyes is uncertain and not well documented. Pregnant rats
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 7 of 13
Asphalt
administered intraperitoneal doses of naphthalene during gestation gave birth to offspring that had delayed heart and
bone development. Pregnant mice given near lethal doses of naphthalene showed no significant maternal toxicity and a
reduction in the number of pups per litter, but no gross abnormalities in offspring. Suppressed spermatogenesis and
progeny development have been reported in mice, rats and guinea pigs after exposure to high concentrations of
naphthalene in their drinking water. Certain groups or individuals, i.e., infants, Semites, Arabs, Asians and Blacks, with a
certain blood enzyme deficiency (glucose-6-phosphate dehydrogenase) are particularly susceptible to hemolytic agents
and can rapidly develop hemolytic anemia and systemic poisoning from ingestion or inhalation of naphthalene.
This product many contain >1% highly solvent refined heavy paraffinic distillate. Chronic skin painting studies with
severely solvent refined neutral oils did not produce evidence of skin cancer in mice.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects: If spilled, hot product and/or the coating action of the oil components could harm
plant life. This product does not concentrate or accumulate in the food chain. This
product is not expected to cause any acute or chronic toxicity to aquatic organisms
due to its extremely low water solubility.
13. DISPOSAL CONSIDERATIONS
Cleanup Considerations: This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information: This material when transported via US commerce is NOT REGULATED by DOT
regulations.
Packing group: Not applicable.
DOT reportable quantity (lbs): Not applicable.
TDG (Canada):
Packing group: Not applicable.
Regulated substances: Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
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Asphalt
SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Asphalt NA
Water NA
No. 2 Fuel Oil NA
Petroleum Distillates, Solvent NA
Dewaxed Heavy Paraffinic
Sulfur Compounds NA
Polymer Modifier (SBS or SBR) NA
Anionic Emulsifier NA
Naphthalene NA
Hydrogen Sulfide hydrogen sulfide
SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Asphalt NA
Water NA
No. 2 Fuel Oil NA
Petroleum Distillates, Solvent NA
Dewaxed Heavy Paraffinic
Sulfur Compounds NA
Polymer Modifier (SBS or SBR) NA
Anionic Emulsifier NA
Naphthalene = 0.454 kg final RQ
= 1 lb final RQ
= 100 lb final RQ
= 45.4 kg final RQ
Hydrogen Sulfide = 100 lb final RQ
= 45.4 kg final RQ
SARA Section 311/312: The following EPA hazard categories apply to this product:
Acute Health Hazard
Chronic Health Hazard
SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
Asphalt None
Water None
No. 2 Fuel Oil None
Petroleum Distillates, Solvent None
Dewaxed Heavy Paraffinic
Sulfur Compounds None
Polymer Modifier (SBS or SBR) None
Anionic Emulsifier None
Naphthalene = 0.1 % de minimis concentration
Hydrogen Sulfide None
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Asphalt
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 0170
Pennsylvania Right-To-Know: [present]
Massachusetts Right-To Know: Present
Florida substance List: Not Listed.
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Asphalt
Rhode Island Right-To-Know: Toxic, Flammable
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Water
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
No. 2 Fuel Oil
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 2452
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Petroleum Distillates, Solvent Dewaxed Heavy Paraffinic
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
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Asphalt
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Sulfur Compounds
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Polymer Modifier (SBS or SBR)
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 11 of 13
Asphalt
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Anionic Emulsifier
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Naphthalene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Hydrogen Sulfide
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 1017
Pennsylvania Right-To-Know: environmental hazard
Massachusetts Right-To Know: Extraordinarily hazardous
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Toxic, Flammable
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous extraordinarily hazardous
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
MSDS ID NO.: 0137MAR019 Product name: Marathon Anionic Emulsified Page 12 of 13
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New Jersey - Special Hazardous Substances: flammable - fourth degree
New Jersey - Environmental Hazardous SN 1017
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - = 100 lbs Air RQ
List of Hazardous Substances: = 100 lbs Land/Water RQ
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure:
Water Uncontrolled product according to WHMIS classification
criteria.
Naphthalene B4, D2A 1%
Hydrogen Sulfide A; B1; D1A; D2B 1% (English Item 851, French Item 1550)
16. OTHER INFORMATION
Additional Information: The pronounced and easily-recognized rotten egg odor of hydrogen sulfide gas
(H2S) can be detected at concentrations as low as 0.003-0.13 ppm. Since higher
H2S concentrations (100-200 ppm) cause olfactory fatigue and other hydrocarbon
odors can "mask" H2S, the sense of smell cannot be used as a reliable indicator of
H2S exposure.
Prepared by: Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
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