MATERIAL SAFETY DATA SHEET
Product Name: Instant Cold Compress
Product Code: VARIOUS 1 of 9
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Instant Cold Compress
Product Code: B503,FAO-ICE 4X5/JR,FAO-ICE6X9,ICP,ICP JR
For further information contact MSDS Coordinator
8am - 6pm Pacific Time, Mon - Fri: 888-88-Basic (22742)
EMERGENCY OVERVIEW
Emergency Telephone Numbers:
888-88-Basic (22742)
909-548-4828
Health Hazards: Dry chemical of cold compress is an eye and skin
irritant. Avoid contact with eyes, skin and clothing. Wash
thoroughly after handling.
Physical Hazards: Dry chemical is an oxidizer. Oxidizers can support
combustion. Contact may increase flammability of other materials.
Avoid contact with clothing and other combustible material.
< Physical Form: Solid/Liquid
< Appearance: White solid in water bag
< Odor: None
NFPA HAZARD CLASS: Health: 1 (Slight)
Flammability: 0 (Least)
Reactivity: 3 (High)
Other: OXY (Oxidizer)
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 2 of 9
2. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS % Weight EXPOSURE GUIDELINE
Limits Agency Type
Ammonium Nitrate 40-70 Not Established
CAS# 6484-52-2
OTHER COMPONENTS % Weight EXPOSURE GUIDELINE
Limits Agency Type
Water 30-60 Not Established
CAS# 7732-18-5
Note: State, local or other agencies or advisory groups may have
established more stringent limits. Consult an industrial hygienist or
similar professional, or you local agencies, for further information.
3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS:
Eye: Eye irritant. Contact may cause stinging, watering, redness, and
swelling.
Skin: Skin irritant. Contact may cause redness, itching, burning and
skin damage. No harmful effects from skin absorption have been
reported.
Inhalation (Breathing): Low to moderate degree of toxicity by
inhalation.
Ingestion (Swallowing): Low to moderate degree of toxicity by
ingestion.
Signs and Symptoms: Effects of overexposure may include irritation of
the nose, throat and digestive tract; coughing, nausea, vomiting,
diarrhea, abdominal pain, breathing difficulties, and blood
disorders (methemoglobinemia).
Cancer: No data available.
Target Organs: No data available.
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 3 of 9
Developmental: Inadequate data available for this material.
Other Comments: This material contains nitrate salts. Nitrates may be
reduced by intestinal bacteria to nitrite. When absorbed,
nitrites may result in effects on the blood (methemoglobinemia)
and blood vessels (vasodilating and a fall in blood pressure).
Symptoms of toxicity may include headache, fainting, fatigue,
cyanosis, confusion, irregular heartbeats, and possible
respiratory paralysis. Pre-existing heart disease may be
aggravated by exposure to nitrates.
Pre-Existing Medical Conditions: Conditions aggravated by exposure may
include heart, blood vessel and skin disorders.
4. FIRST AID MEASURES
Eye: Move victim away from exposure and into fresh air. If irritation
or redness develops, flush eyes with clean water and seek
immediate medical attention. For direct contact, immediately hold
eyelids apart and flush the affected eye(s) with clean water for
at least 15 minutes. Seek medical attention.
Skin: Remove contaminated shoes and clothing, and flush affected
area(s) with large amounts of water. If skin surface is damaged,
apply a clean dressing and seek medical attention. If skin
surface is not damaged, cleanse affected area(s) thoroughly by
washing with mild soap or water. If irritation or redness
develops, seek medical attention.
Inhalation (Breathing): If respiratory symptoms or other symptoms of
exposure develop, move victim away from source of exposure and
into fresh air. If symptoms persist, seek medical attention. If
victim is not breathing, clear airway and immediately begin
artificial respiration. If breathing difficulties develop, oxygen
should be administered by qualified personnel. Seek immediate
medical attention.
Ingestion (Swallowing): If swallowed, seek emergency medical attention.
If victim is drowsy or unconscious and vomiting, place on left
side with the head down and do not give anything by mouth. If
victim is conscious and alert and ingestion occurred within the
last hour, vomiting should be induced for ingestion of large
amounts (more than 5 ounces in an adult) under direction from a
physician or poison center. If possible, do not leave victim
unattended and observe closely for adequacy of breathing.
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 4 of 9
Note to Physicians: Nitrates in large doses may cause significant
vasodilation and hypotension. Pre-existing ischemic heart disease
may be aggravated by these effects. In large ingestions nitrates
may cause methemoglobinemia. Methemoglobinemia should be
suspected if cyanosis occurs. Methylene blue (1-2 mg/kg I.V. over
several minutes) is an effective antidote for symptomatic
methemoglobinemia.
5. FIRE FIGHTING MEASURES
Flammable Properties: Flash Point: None
OSHA Flammability Class: Not applicable
LEL/UEL: No data
Autoignition Temperature: No data
Unusual Fire & Explosion Hazards: Oxidizer. The dry chemical of this
material is an oxidizer and may increase inflammability of any
combustible substance. It is the nature of oxidizers to provide
their own oxygen source; smothering a fire may be ineffective.
Nitrate salts support combustion under certain conditions.
Ammonium nitrate is capable of detonation if heated under
confinement or if subjected to strong shocks. Organic or other
easily oxidizable matter can sensitize it to a more readily
explodable state. Do not allow product to evaporate to dryness,
especially in contact with combustible materials.
Extinguishing Media: Use water only. Do not use dry chemical, carbon
dioxide or foam.
Fire Fighting Instructions: For fires beyond the incipient stage,
emergency responders in the immediate hazard area should wear
bunker gear. When the potential chemical hazard is unknown, in
enclosed or confined spaces, or when explicitly required by DOT, a
self-contained breathing apparatus should be worn. In addition,
wear other appropriate protective equipment as conditions warrant
(see Section 8). Isolate immediate hazard area and keep
unauthorized personnel out. Stop spill/release if it can be done
with minimal risk. Move undamaged containers from immediate
hazard area if it can be done with minimal risk. Water spray may
be useful in minimizing or dispersing vapors. Cool equipment
exposed to fire with water, if it can be done with minimal risk.
6. ACCIDENTAL RELEASE MEASURES
The dry chemical of this material is an oxidizer. Keep all sources of
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 5 of 9
ignition and hot metal surfaces away from spill/release. The use of
explosion-proof equipment is recommended.
Stay upwind and away from spill/release. Notify person down wind of
spill/release, isolate immediate hazard area and keep unauthorized
personnel out. Stop spill/release if it can be done with minimal risk.
Wear appropriate protective equipment including respiratory protection
as conditions warrant (see Section 8). Prevent spilled material from
entering sewers, storm drains, other unauthorized treatment drainage
systems, and natural waterways. Dike far ahead of spill for later
recovery or disposal. Spilled material may be absorbed into an
appropriate absorbent material. Notify appropriate federal, state, and
local agencies. Immediate cleanup of any spill is recommended.
7. HANDLING AND STORAGE
Handling: Do not enter confined spaces such as tanks or pits without
following proper entry procedures such as ASTM D-4276 and 29CFR
1910.146. The use of appropriate respiratory protection is
advised when concentrations exceed any established exposure limits
(see Section 2 and 8). Wash thoroughly after handling. Do not
wear contaminated clothing or shoes. Use good personal hygiene
practice.
鈥淓mpty鈥? containers retain residue and may be dangerous. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose such
containers to heat, flame, sparks, or other sources of ignition.
They may explode and cause injury or death. Container should be
disposed in an environmentally safe manner and in accordance with
governmental regulations.
Before working on or in tanks which contain or have contained this
material, refer to OSHA Regulations, ANSI Z49.1 and other
governmental and industrial references pertaining to cleaning,
welding, or other contemplated operations.
Storage: Use and store this material in cool, dry, well-
ventilated areas away from heat and all sources of ignition. Post
area 鈥淣o Smoking or Open Flame.鈥? Solution is corrosive to copper,
copper alloys, lead, and zinc. Store to avoid contact with
incompatible materials such as ordinary combustibles, flammable
liquids, greases, and those materials, including other oxidizers,
that could react with the oxidizer or catalyze its decomposition
(see Section 10). Prohibit accumulation of combustible waste in
storage areas. Combustible construction materials that may be in
contact with oxidizers shall be protected with a compatible
coating to prevent impregnation of the combustible materials by
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 6 of 9
the oxidizers. Protect container(s) against physical damage.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls: If current ventilation practices are not adequate
to minimize exposure, additional ventilation or exhaust systems
may be required.
Personal Protective Equipment (PPE):
Respiratory: A NIOSH/MSHA approved air purifying respirator with a
N95 filter may be used under conditions where airborne
concentrations are expected to exceed exposure limits (see
Section 2). Protection provided by air purifying respirators
is limited (see manufacturer鈥檚 respirator selection guide).
Use a positive pressure air supplied respirator if there is
potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying
respirators may not provide adequate protection. A
respiratory protection program that meets OSHA鈥檚 29 CFR
1910.134 and ANSI Z88.2 requirements must be followed whenever
workplace conditions warrant a respirator鈥檚 use.
Skin: The use of gloves impermeable to the specific material
handled is advised to prevent skin contact, possible
irritation, absorption, and skin damage (see glove
manufacturer literature for information on permeability).
Depending on conditions of use, apron and/or arm covers may be
necessary.
Eye/Face: Approved eye protection to safeguard against potential
eye contact, irritation, or injury is recommended. Depending
on conditions of use, a face shield may be necessary.
Other Protective Equipment: A source of clean water should be
available in the work area for flushing eyes and skin.
Impervious clothing should be worn as needed.
9. PHYSICAL AND CHEMICAL PROPERTIES
Note: Unless otherwise stated, values are determined at 20掳C (68掳F) and
760 mm Hg (1 atm).
Flash Point: None
Flammable/Explosive Limits (%): LEL/UEL: No data
Autoignition Temperature: No data
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 7 of 9
Appearance: White solid in water bag
Physical State: solid/Liquid
Odor: None
pH: No data
Vapor Pressure (mm Hg): No data
Boiling Point: No data
Freezing/Melting Point: No data
Solubility in Water: 100%
Specific Gravity: approx 1.3
Evaporation Rate (nBuAc=1): No data
10. STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions of storage and
handling. Dry chemical is an oxidizer and may promote combustion
in other materials.
Conditions To Avoid: This material may be an oxidizer. Do not heat
above 250掳F. Do not let dry chemical or solution dry or
crystallize in contact with organic, reactive, or combustible
materials (see Sections 7).
Incompatible Materials: Avoid contact with reactive, combustible, or
organic materials, such as wood, grain, organic chemicals, acids,
corrosive liquids, sulfur, flammable liquids, chlorates,
permanganates, finely divided materials, charcoal, coke, cork, or
sawdust. Avoid contact with other oxidizers. Contact with
alkaline materials may liberate ammonia.
Hazardous Decomposition Products: Material will not burn, but if
involved in a fire, oxides of nitrogen may be generated. Exposure
to heat may liberate ammonia fumes.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
No definitive information available on carcinogenicity, mutagenicity,
target organs or developmental toxicity.
12. DISPOSAL CONSIDERATIONS
This material, if discarded as produced, may be a RCRA 鈥渃haracteristic鈥?
hazardous waste due to the characteristic(s) of ignitability (D001).
If the material is spilled to soil or water, characteristic testing of
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 8 of 9
the contaminated materials is recommended. To assure proper disposal,
consult with state and local regulations and disposal authorities.
13. TRANSPORT INFORMATION
Hazard Class or Division: Not classified as hazardous.
14. REGULATORY INFORMATION
This material contains the following chemicals subject to the reporting
requirements of SARA 313 and 40 CFR 372.
COMPONENT CAS NUMBER
Ammonia (includes anhydrous 7446-41-7
ammonia and aqueous ammonia from
water dissociable ammonium salts
and other sources; 10 percent of
total aqueous ammonia is reportable
under this listing)
Water dissociable nitrate None
compounds
Warning: This material contains the following chemicals which are known
to the State of California to cause cancer, birth defects or other
reproductive harm, and are subject to the requirements of California
Proposition 65 (CA Health & Safety Code Section 25249.5)
--None Known--
This material has not been identified as a carcinogen by NTP, IARC, or
OSHA.
EPA (CERCLA) Reportable Quantity: --None--
15. DOCUMENTARY INFORMATION
Issue Date: 07/23/04
Previous Issue Date: None
Product Code: ICE1069
16. DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
The information in this document is believed to be correct as of the
date issued. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY
PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
Product Name: Instant Cold Compress
Product Code: VARIOUS Page 9 of 9
IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THIS INFORMATION, THE
RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT,
THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. This
information and product are furnished on the condition that the person
receiving them shall make his own determination as to the suitability
of the product for his particular purpose and on the condition that he
assume the risk of his use thereof.
Issue Date: 07/23/04 Status: Final New
Revised Sections: New MSDS
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