MSDS
EN
**** MATERIAL SAFETY DATA SHEET ****
Glyoxal, 40 wt.% solution in water
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: Glyoxal, 40 wt.% solution in water
Catalog Numbers:
15622-0000, 15622-0010, 15622-0025, 15622-0050, 15622-5000
Synonyms:
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
|----------------|--------------------------------------|----------|-----------|-----------|---------------|
| 107-22-2 |Glyoxal | 40% | 203-474-9 | XN||
|----------------|--------------------------------------|----------|-----------|-----------|---------------|
| 7732-18-5 |Water | 60% | 231-791-2 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 36/38 43 20 68
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin. May cause sensitization by skin
contact. Harmful by inhalation.Possible risk of irreversible effects.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause sensitization by skin contact.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Possible risk of irreversible effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
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Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes.
Storage:
Store in a tightly closed container. Store in a dry area. Store at
around 20鈥.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: almost colorless
Odor: mild odor
pH: 2-3.5 (400 g/l aq.sol.)
Vapor Pressure: 20.2hPa @20 deg C
Viscosity: 8 mPa.s @20 deg C
Boiling Point: 104 deg C @760mmHg
Freezing/Melting Point: -14 deg C
Autoignition Temperature: 285 deg C ( 545.00 deg F)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
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Solubility in water: Miscible.
Specific Gravity/Density: 1.265
Molecular Formula: C2H2O2
Molecular Weight: 58.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107-22-2: MD2625000 MD2650000 MD2700000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 107-22-2: Dermal, guinea pig: LD50 = 6600 mg/kg; Draize test,
rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 100 uL/24H
Moderate; Draize test, rabbit, eye: 100 uL Mild; Draize test, rabbit,
skin: 500 uL/4H Mild; Draize test, rabbit, skin: 10 mg/24H;
Inhalation, rat: LC50 = 2410 mg/m3/4H; Oral, mouse: LD50 = 400 mg/kg;
Oral, mouse: LD50 = 1280 mg/kg; Oral, rabbit: LD50 = >3175 mg/kg;
Oral, rat: LD50 = 200 mg/kg; Oral, rat: LD50 = 200 mg/kg; Oral, rat:
LD50 = 4290 mg/kg; Oral, rat: LD50 = 2960 mg/kg; Skin, rabbit: LD50
= 10 mL/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rabbit: LD50 = 10
mL/kg; Skin, rat: LD50 = >2 gm/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Not available.
Carcinogenicity:
Glyoxal -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Leuciscus idus: LC50: >460 - <680 mg/l; 96H; DIN 38412 Part
15Daphnia: EC50: 404 mg/l; 48H; Dir. 79/831/EEClog Pow: -1,15
Other
Readily biodegradable.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
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RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20 Harmful by inhalation.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 107-22-2: 1
CAS# 7732-18-5: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 107-22-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 107-22-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 107-22-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/10/1996 Revision #3 Date: 12/09/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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