Prepared: 02/07/08
Supersedes: 11/21/02
ChemMasters
Product Name: Duraguard 401Part A
Material Safety Data Sheet
1. Chemical Product and Company Information
Product Name: Duraguard 401 Part A, Resin
Product Description: Duraguard 401 is a 3 component, low viscosity, solvent free, high molecular weight methacrylate
penetrating sealer and crack healer.
ChemMasters In Case of Emergency Contact:
300 Edwards Street CHEMTREC 800/424-9300
Madison, Ohio 44057
440-428-2105
2. Composition / Information on Ingredients
Hazardous Components CAS # Exposure Limits % by Wt
OSHA(PEL/TWA) ACGIH (TLV/TWA) OTHER
Methacrylate Monomer Not Available NE NE 鈥? 100
3. Hazards Identification
WARNING
Unstable (Reactive) Upon Depletion of Inhibitor
Cause eye irritation with possible corneal injury.
Overexposure may cause skin irritation or burns, central nervous system effects, liver damage and respiratory
sensitivity
Potential Health Hazards - Acute
Eye: Direct contact may cause irritation.
Skin: Direct contact may cause irritation and/or sensitization.
Inhalation: May cause irritation or respiratory tract.
Ingestion: Ingestion is not likely to cause injury.
Potential Health Effects - Chronic
None Known
Carcinogenicity: NTP IARC Monographs OSHA Regulated
No data available No data available No data available
4. First Aid Measures
Eye: Immediately flush with plenty of clean water for at least 15 minutes.
Skin: Remove contaminated clothing. Clean affected area(s) thoroughly with soap and water.
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get
medical attention.
Ingestion: Ingestion is not likely to cause injury. However, seek medical attention as a precaution.
SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST
1
Prepared: 02/07/08
Supersedes: 11/21/02
Product Name: Duraguard 401Part A
5. Fire Fighting Measures
Flash Point (method used): Not Flammable
Flammable Limits (% volume in air): Lower = NA Upper = NA
Auto Ignition Temperature: No data available
Extinguishing Media: Water may be ineffective in Fire Fighting as material in not soluble in water. Extinguish with water
fog, dry chemical, CO2 or foam.
Hazard Combustion Products: Acrid smoke-fumes/carbon monoxide/carbon dioxide and perhaps other toxic vapors
may be released during a fire involving this product.
Fire & Explosion Hazards: High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or
oxidizers may couse spontaneous polymerinzing reaction generating heat/pressure. Closed containers may rupture
or explode during runaway polymerization.
Fire Fighting Instructions: Do not enter confined fire space without full bunker gear including a positive pressure, NIOSH
approved, self-contained breathing apparatus. Cool containers exposed to fire with water.
6. Accidental Release Measures
Spill: Avoid personal contact. If spill is indoors, extinguish all ignition sources and ventilate area. Keep out of drains,
sewers or waterways. Take up with absorbentmaterial, place into non-leak containers and seal tightly for proper
disposal. Non-contaiminated product when properly inhibited is not a RCRA hazardous waste. However, when
contaiminated this product has the potential for internal heat generation.
7. Handling and Storage
Handling: Do NOT use localized heat sources such as band heaters to heat product. Do NOT use steam. If using
hot boxes or hot room, do not exceed 60o C or 140o F. Overheating may cause uncontrolled hazardous polymerization.
If it freezes, heat as indicated above and mix gently to redistribute the inhibitor. Material should be consumed in its
entirety after reheating as re-heats may affect product quality or result in product degradation.
Storage: Store containers tightly closed with adequate ventilation in a cool, dry area. Do not allow temperature to exceed
60o C or 140o F. Do not allow temperature to drop below 0o C or 32o F.
8. Exposure Controls / Personal Protection
Exposure Controls: Mechanical and local exhaust should be used for indoor use.
Personal Protection: Impervious gloves, chemical splash goggles, and protective clothing to minimize skin contact.
9. Physical and Chemical Properties
Appearance: Clear liquid
Odor: Methacrylate
Boiling Point: NA
Melting Point: Not applicable
Vapor Pressure (mm/Hg): No data available
Vapor Density (Air = 1): No data available
Solubility in Water: Negligible (<5%)
Specific Gravity (H20 = 1): 1.05
Evaporation Rate (n-Butyl Acetate = 1): <1
2
Prepared: 02/07/08
Supersedes: 11/21/02
Product Name: Duraguard 401Part A
10. Stability and Reactivity
Chemical Stability: Stable, contains inhibitor.
Conditions to Avoid: Heat, flame, contaminants.
Incompatibility (materials to avoid): Strong oxidizers, radiation and other initiators.
Hazardous Decomposition or By-products: Acrid fumes emitted upon decomposition. Incomplete combustion will
produce unknown toxic substances.
Hazardous Polymerization: Could occur under normal conditions. Store at room temperature.
11. Toxicological Informatio
Components Oral LD50 Dermal LD50 Inhalation LC50
(rat) (rabbit) (rat)
No Data Available --- 鈥? __
12. Ecological Information
Possible land, air and water pollutant. No exact data available.
13. Disposal Considerations
Dispose of in accordance with all federal, state, and local regulations. If uncertain of local requirements, contact the
proper environmental authorities for information on waste disposal in your area. Non-contaiminated product when
properly inhibited is not a RCRA hazardous waste. However, when contaiminated this product has the potential for
internal heat generation.
14. Transportation Information
For U S National, Air and International Shipments:
Shipping Description: Not Regulated
Emergency Response Guide Number: NA
Hazard Class: None
15. Regulatory Information
OSHA: This material is not hazardous by definition of Hazardous Communications Standard (29 CFR 1910.1200)
CERCLA Reportable Quantity: NA
SARA Title III:
Section 311/312 hazard categories: acute health
Section 313 reportable ingredients:
Components CAS # Maximum %
None
16. Other Information
MSDS Status: Reviewed 2/7/08
Industrial Abbreviation Legend on page 4 of this MSDS follows.
3
Prepared: 02/07/08
Supersedes: 11/21/02
Product Name: Duraguard 401Part A
Industrial Abbreviation Legend
mg/m3
ACGIH American Conference of Governmental Industrial milligrams per cubic meter
NIOSH National Institute for Occupational Safety and Health
Hygienists
NTP National Toxicology Program
CAA Clean Air Act (EPA)
CERCLA Comprehensive Environmental Response, OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
Compensation & Liability Act of 1980 (Superfund) (EPA)
ppm parts per million
CNS Central Nervous System
CWA Clean Water Act (EPA) RCRA Resource Conservation and Recovery Act (EPA)
SARA EPA鈥檚 Superfund Amendment and Reauthorization
DOT Department of Transportation
Act (EPA)
EPA Environmental Protection Agency
g/kg grams per kilogram STEL Short-Term Exposure Limit, ACGIH terminology
TLV Threshold Limit Value
IARC Internal Agency for Research on Cancer
TWA Time-Weighted Average
LC50 Lethal Concentration in which 50% of the test animals are
expected to die
LD50 Lethal Dose in which 50% of the test animals are
expected to die
THIS PRODUCT IS FORMULATED AND LABELED FOR
INDUSTRIAL AND COMMERCIAL APPLICATION ONLY
The information contained herein is given in good faith and based on data considered accurate. However, no warranty is
expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. The Spray-
Cure Company assumes no responsibility for personal injury or property damage to vendees, users or third parties caused
by the material. Such vendees or users assume all risks associated with the use of the material.
4
This is the last page of this MSDS.
|